• Article dans une revue

Proton irradiation: a key to the challenge of N-glycosidic bond formation in a prebiotic context

Raffaele Saladino, Bruno M. Bizzarri, Lorenzo Botta, Jiří Šponer, Judit E. Šponer, Thomas Georgelin, Maguy Jaber, Baptiste Rigaud, Michail Kapralov, Gennady N. Timoshenko, Alexei Rozanov, Eugene Krasavin, Anna Maria Timperio, Ernesto Di Mauro

Scientific Reports, 2017, 7 (1), ⟨10.1038/s41598-017-15392-8⟩. ⟨hal-01651973⟩

• Article dans une revue

Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release

Changlong Wang, Jimena Tuninetti, Zhao Wang, Chen Zhang, Roberto Ciganda, Lionel Salmon, Sergio Moya, Jaime Ruiz, Didier Astruc

Non-noble metal nanoparticles are notoriously difficult to prepare and stabilize with appropriate,dispersion, which in ttirn severely limits their catalytic functions. Here, using zeolitic imidazolate framework (ZIF-8) as MOF template, catalytically remarkably- efficient, ligand-free first-row late…

Journal of the American Chemical Society, 2017, 139 (33), pp.11610-11615. ⟨10.1021/jacs.7b06859⟩. ⟨hal-01651999⟩

• Article dans une revue

NO2 disproportionation for the IR characterisation of basic zeolites

Olivier Marie, Nicolas Malicki, Catherine Pommier, Pascale Massiani, Ann Vos, Robert Schoonheydt, Paul Geerlings, Carlos Henriquese, Frédéric Thibault-Starzyk

NO2 disproportionation on alkaline zeolites is used to generate nitrosonium (NO+) and nitrate ions on the surface, and the infrared vibrations observed are very sensitive to the cation chemical hardness and to the basicity of zeolitic oxygen atoms.side pockets of acidic mordenite. We describe here…

Chemical Communications, 2005, pp.1049-1051. ⟨hal-00126967⟩

• Article dans une revue

Surface orientation dependent interaction of cobalt (II) precursors with alpha-alumina

Céline Chizallet, Christian Schlaup, Emiliano Fonda, Xavier Carrier

The performances of alumina-supported cobalt catalysts strongly depend on Co/alumina interactions, that are poorly understood. In the present work, α-alumina surfaces are used as models of polycrystalline support, to unravel their orientation dependent behavior by GI-EXAFS. The CoII/α-alumina…

Journal of Catalysis, 2021, 394, pp.157-166. ⟨10.1016/j.jcat.2020.10.025⟩. ⟨hal-03176305⟩

• Article dans une revue

EPR Characterization and Reactivity of Surface-Localized Inorganic Radicals and Radical Ions

Mario Chiesa, Elio Giamello, Michel Che

A review. The role of surface inorg. radicals and radical ions formed at the interface between a solid and a gas phase was discussed. The formation of such species is relevant to field such as electrochem., heterogeneous catalysts, photocatalysis and corrosion. The characterization of these…

Chemical Reviews, 2010, 110 (3), pp.1320-1347. ⟨10.1021/cr800366v⟩. ⟨hal-00604710⟩

• Article dans une revue

What Do Tantalum Framework Sites Look Like in Zeolites? A Combined Theoretical and Experimental Investigation

Frederik Tielens, Tetsuya Shishido, Stanislaw Dzwigaj

Ab initio periodic DFT calculations on the structural and energy properties of different model tantalum framework sites in tantalum-substituted socialite cavities are presented and related to experimental FTIR measurements on Ta-containing SiBEA zeolites. The tantalum framework sites are…

Journal of Physical Chemistry C, 2010, 114 (21), pp.9923-9930. ⟨10.1021/jp102181m⟩. ⟨hal-00604808⟩

• Article dans une revue

Assessing carbon or tungstates coverage of ZrO2 nanoparticles supported on MWCNT via NOx-TPD

Patrick Kelleher, Gary Haller, Sandra Casale, Christophe Méthivier, Cyril Thomas

Multi-walled carbon nanotubes (MWCNT) promoted by oxides, that are far from trivial to characterize, have emerged as promising candidates in several fields such as biosensors and catalysis. In this study the coverage of ZrO2 nanoparticles supported on MWCNT, by carbonaceous deposits or tungstates…

Nano-Structures & Nano-Objects, 2018, 16, pp.110-119. ⟨10.1016/j.nanoso.2018.05.003⟩. ⟨hal-01803349⟩

• Thèse

Photocatalyseurs nanocomposites UCNP@SiO2@ZnO, activés par rayonnement proche infrarouge, pour la dépollution des eaux usées, Nanocomposites photocatalysts UCNP@SiO2@ZnO, active under near-infrared light, for wastewater treatment

David Hu

Les photocatalyseurs tels que l’oxyde de zinc (ZnO) peuvent minéraliser les polluants organiques toxiques et persistants dans les eaux usées. Ils ne sont cependant pas efficients dans les eaux très contaminées, suite à la nécessité d’une activation par une lumière UV qui n’y pénètre que faiblement…, Photocatalysts such as zinc oxide (ZnO) can mineralize toxic and persistent organic pollutants present in wastewaters. Unfortunately, these photocatalysts loose part of their effectiveness because they need to be activated by UV light, which has a limited penetration depth in highly contaminated…

Matériaux. Sorbonne Université, 2021. Français. ⟨NNT : 2021SORUS017⟩. ⟨tel-04063743⟩

• Chapitre d'ouvrage

Synthesis of metal oxide catalysts

Xavier Carrier, Sébastien Royer, E. Marceau

This chapter gives an overview of the current preparation strategies for the synthesis of bulk and supported metal oxide catalysts, in order to give rational guides to understand the synthetic challenges associated with the preparation of these catalytic systems developed in the successive chapters…

Védrine, Jacques C. Metal Oxides in Heterogeneous Catalysis, Elsevier, pp.43-103, 2018, 978-0-12-811631-9. ⟨10.1016/b978-0-12-811631-9.00002-8⟩. ⟨hal-03575930⟩

• Article dans une revue

Compared activity and stability of three Ni-silica catalysts for methane bi- and dry reforming

Karam Jabbour, M.N. Kaydouh, N El Hassan, H El Zakhem, Sandra Casale, Anne Davidson, Pascale Massiani

A low weight % of Ni (5 wt %) and the two solvents technique of deposition are used to obtain well-dispersed Ni-species (either particles or species dispersed on the silica surface) and avoid the formation of large particles on three silicas SBA-15, Aerosil 300 and diatoms MN3. Stability tests at…

IEEE Transactions on NanoBioscience, 2015, pp.1-4. ⟨10.1109/MedGO.2015.7330318⟩. ⟨hal-01264119⟩