Laboratoire de réactivité de surface

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  • Article dans une revue

Optimized immobilization of gold nanoparticles on planar surfaces through alkyldithiols and their use to build 3D biosensors

Anne-Laure Morel, Rose-Marie Volmant, Christophe Methivier, Jean-Marc Krafft, Souhir Boujday, Claire-Marie Pradier

This paper describes a controlled way to immobilize gold nanoparticles on planar gold surfaces and the use of the resulting 3D platform to build up a 3D biosensor. The surface was first functionalized by grafting hexanedithiol, this molecule has 2 thiol end groups, which enables its chemical…

Colloids and Surfaces B: Biointerfaces, 2010, 81 (1), pp.304-312. ⟨10.1016/j.colsurfb.2010.07.021⟩. ⟨hal-00604782⟩

  • Article dans une revue

N-Methylephedrium Salts as Chiral Surfactants for Asymmetric Hydrogenation in Neat Water with Rhodium(0) Nanocatalysts

Elodie Guyonnet Bile, Audrey Denicourt-Nowicki, Rita Sassine, Patricia Beaunier, Franck Launay, Alain Roucoux

Synthesis of a water-sol. family of optically active N-methylephedrium salts NMeEph12X I [X = Br, HCO3, (S)-lactate] that can be used as efficient protective agents of metallic nanoparticles in neat water was described. The resulting materials were evaluated in the asym. hydrogenation of…

ChemSusChem, 2010, 3 (11), pp.1276-1279. ⟨10.1002/cssc.201000206⟩. ⟨hal-00604720⟩

  • Article dans une revue

Surface Segregation of Pd from TiO2-Supported AuPd Nanoalloys under CO Oxidation Conditions Observed In situ by ETEM and DRIFTS

Laurent Delannoy, Suzanne Giorgio, Jean-Gabriel Mattei, Claude R. Henry, Nadia El Kolli, Christophe M Éthivier, Catherine Louis

A TiO2-supported AuPd bimetallic catalyst with an Au/Pd atomic ratio of 8 was prepared by deposition-precipitation with urea, and its activity in CO oxidation at room temperature was compared to the one of a monometallic Au/TiO2 catalyst. X-ray photoelectron spectroscopy (XPS) and diffuse…

ChemCatChem, 2013, pp.1-11. ⟨10.1002/cctc.201200618⟩. ⟨hal-00836230⟩

  • Article dans une revue

Origins of the deactivation process in the conversion of methylbutynol on zinc oxide monitored by operando DRIFTS

C. Drouilly, J.M. Krafft, F. Averseng, H. Lauron-Pernot, Delphine Bazer-Bachi, Céline Chizallet, V. Lecocq, G. Costentin

conversion reaction. The formation of acetone and acetylene is indicative of the basic properties of the zinc oxide surface. This basic catalyst, whose conversion level depends on the nature of the pre-treatment, was found to deactivate versus time on stream. Poisoning the basic sites by CO2 pre-…

Catalysis Today, 2012, 205, pp.67-75. ⟨10.1016/j.cattod.2012.08.011⟩. ⟨hal-00809404⟩

  • Article dans une revue

Surface Science Approach to the Solid-Liquid Interface: Surface-Dependent Precipitation of Ni(OH)2 on a-Al2O3 Surfaces

Asma Tougerti, Isabelle Llorens, Francesco d'Acapito, Emiliano Fonda, Jean-Louis Hazemann, Yves Joly, Dominique Thiaudi Ère, Michel Che, Xavier Carrier

A molecular-scale understanding of the adsorption of metal ions on oxide surfaces is of fundamental importance for various scientific areas where the oxide/water interface plays a central role, such as corrosion science, preparation of heterogeneous catalysts, transport of contaminants in the…

Angewandte Chemie International Edition, 2012, 51, pp.7697-7701. ⟨10.1002/anie.201201349⟩. ⟨hal-00749941⟩

  • Article dans une revue

Elaboration of a reusable immunosensor for the detection of staphylococcal enterotoxin A (SEA) in milk with a quartz crystal microbalance

Michèle Salmain, Mahsa Ghasemi, Souhir Boujday, Claire-Marie Pradier

An immunosensor with quartz crystal microbalance (QCM) detection operating in flow-through mode was set up for assaying staphylococcal enterotoxin A (SEA) in model buffer medium and in milk. This biosensor is label-free and operates in the direct format. Each step of construction of the sensing…

Sensors and Actuators B: Chemical, 2012, 173, pp.148-156. ⟨10.1016/j.snb.2012.06.052⟩. ⟨hal-00744497⟩

  • Article dans une revue

Self-Assembling of Redox-Active Atrazine Poly(ethylenimine) Conjugates – Interfacial Electrochemical and Spectroscopic Characterization

Zhaohui Chen, Michèle Salmain, Claire-Marie Pradier, Nathalie Fischer-Durand, Alain Pailleret, Féthi Bedioui, Sandrine Zanna

Thin films of polymers tethered with both atrazine haptens and ferrocenyl (Fc) probes were formed on polycrystalline gold electrodes by taking advantage of the facile formation of self-assembled monolayers (SAMs) of thiolates. These films were characterized by polarization modulation Fourier…

Electroanalysis, 2006, 18 (7), pp.684-694. ⟨10.1002/elan.200503451⟩. ⟨inserm-00194708⟩

  • Article dans une revue

Adsorption of functionalised thiols on gold surfaces: how to build a sensitive and selective sensor for a nitroaromatic compound?

F. Thery-Merland, Christophe Méthivier, Eric Pasquinet, Lionel Hairault, Claire-Marie Pradier

Adsorption of thiols of varying structures bearing amine, acid or aromatic functionalities was characterised by Polarisation Modulation Infrared Absorption Spectroscopy (PM-IRRAS). The so functionalised surfaces were then submitted to atmospheres containing traces of 2,4-…

Sensors and Actuators B: Chemical, 2006, 114, pp.223-228. ⟨10.1016/j.snb.2005.04.040⟩. ⟨hal-00111676⟩

  • Article dans une revue

Improved activity and stability in CO oxidation of bimetallic Au-Cu/TiO2 catalysts prepared by deposition-precipitation with urea

A. Sandoval, Catherine Louis, Rodolfo Zanello

Au-Cu bimetallic catalysts supported on TiO2 were prepared for the first time by sequential deposition-precipitation with the urea method, copper first then gold. Au-Cu catalysts with four different Au:Cu atomic ratios were synthesized (1:0.4 to 1:1.2). This method allowed quantitative deposition…

Applied Catalysis B: Environmental, 2013, 140-141, pp.363-377. ⟨10.1016/j.apcatb.2013.04.039⟩. ⟨hal-00911705⟩

  • Article dans une revue

On the origin of the optimum loading of Ag on Al2O3 in the C3H6-SCR of NOx

Tesnim Chaieb, Laurent Delannoy, Catherine Louis, Cyril Thomas

Ag/Al2O3 catalysts synthesized by the common impregnation technique with various Ag loadings were characterized by the NOx-Temperature-Programmed Desorption (TPD) method and their catalytic performances were evaluated in the selective catalytic reduction of NOx by propene (C3H6-SCR). It was found…

Applied Catalysis B: Environmental, 2013, 142-143, pp.780-784. ⟨10.1016/j.apcatb.2013.06.010⟩. ⟨hal-00907584⟩