Laboratoire de réactivité de surface

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  • Article dans une revue

Efficient transformation of cyclohexanone to ε-caprolactone in the oxygen-aldehyde system over single-site titanium BEA zeolite

Katarzyna Pamin, Jacek Gurgul, Grzegorz Mordarski, Yannick Millot, Jean-Philippe Nogier, Laetitia Valentin, Stanislaw Dzwigaj

TixSiBEA zeolites prepared by a two-step post-synthesis method are applied in the liquid-phase Baeyer-Villiger oxidation of cyclohexanone to ε-caprolactone in the oxygen-aldehyde system. Such method of ε-caprolactone synthesis offers the application of milder reaction conditions with the catalytic…

Microporous and Mesoporous Materials, 2021, 322, pp.111159. ⟨10.1016/j.micromeso.2021.111159⟩. ⟨hal-03993571⟩

  • Article dans une revue

Surface functionalization by covalent immobilization of an innovative carvacrol derivative to avoid fungal biofilm formation

Aïcha Gharbi, Thibaut Legigan, Vincent Humblot, Sébastien Papot, Jean-Marc Berjeaud

Carvacrol, an aromatic terpenic compound, known to be antimicrobial was grafted onto gold surfaces via two strategies based on newly-synthesized cross-linkers involving either an ester bond which can be cleaved by microbial esterases, or a covalent ether link. Surface functionalizations were…

AMB Express, 2015, 5 (1), pp.9. ⟨10.1186/s13568-014-0091-2⟩. ⟨hal-01143973⟩

  • Article dans une revue

Covalent Grafting of Organic–Inorganic Polyoxometalates Hybrids onto Mesoporous SBA-15: A Key Step for New Anchored Homogeneous Catalysts

Richard Villanneau, Asma Marzouk, Yan Wang, Aicha Ben Djamaa, Guillaume Laugel, Anna Proust, Franck Launay

Covalent grafting of the polyoxometalate (POM) hybrid [AsW9O33{P(O)(CH2CH2CO2H)}2]5- on mesoporous NH2-functionalized SBA-15 is the first example of anchored vacant POMs in which nucleophilic oxygen atoms are still available after incorporation into the supports. Such systems are interesting…

Inorganic Chemistry, 2013, 52 (6), pp.2958 - 2965. ⟨10.1021/ic302374v⟩. ⟨hal-01563887⟩

  • Article dans une revue

PdAg alloy nanoparticles encapsulated in N-doped microporous hollow carbon spheres for hydrogenation of CO2 to formate

Guoxiang Yang, Yasutaka Kuwahara, Kohsuke Mori, Catherine Louis, Hiromi Yamashita

Here, we report a general synthesis approach to produce PdAg nanoparticles (NPs) that are dispersed uniformly within N-doped microporous hollow carbon spheres (NMHCS) for hydrogenation of CO2 to formate. The optimized PdAg@NMHCS catalyst, which was obtained by using an optimized amount of…

Applied Catalysis B: Environmental, 2021, 283, pp.119628. ⟨10.1016/j.apcatb.2020.119628⟩. ⟨hal-03995568⟩

  • Article dans une revue

Structured hybrid nanoparticles via surface-initiated ATRP of methyl methacrylate from ordered mesoporous silica

F. Audouin, H. Bias, P. Pasetto, P. Beaunier, C. Boissiere, C. Sanchez, M. Save, B. Charleux

Structured hybrid nanoparticles were synthesized via surface-initiated atom transfer radical polymerization of MMA from ordered mesoporous silica (QMS) nanoparticles with various morphologies. The design of the QMS particles was adjusted to target either spherical core-shell or cylindrical…

Macromolecular Rapid Communications, 2008, 29 (11), pp.914-921. ⟨10.1002/marc.200800179⟩. ⟨hal-01563804⟩

  • Article dans une revue

Amphiphilic Polyoxometalates for the Controlled Synthesis of Hybrid Polystyrene Particles with Surface Reactivity

Jennifer Lesage de la haye, Jean-Michel Guigner, Eric Marceau, Laurent Ruhlmann, Bernold Hasenknopf, Emmanuel Lacôte, Jutta Rieger

Amphiphilic organo-polyoxometalates (POMs) used in the radical emulsion polymerization of styrene allowed the preparation in aqueous medium of stable 50-100 nm polystyrene-POM composite latexes. Thanks to the presence of a trithiocarbonate group in the POM amphiphile, POMs could be covalently…

Chemistry - A European Journal, 2015, 21 (7), pp.2948-53. ⟨10.1002/chem.201405708⟩. ⟨hal-01120607⟩

  • Article dans une revue

Microphysiological Glomerular Filtration Barriers: Current Insights, Innovations, and Future Applications

Manon Miran, Kieu Ngo, David Buob, Hanna Debiec, Pierre Ronco, Guillaume Perry

Chronic kidney disease (CKD) affects over 850 million individuals worldwide, often progressing to stages requiring dialysis or kidney transplants. Central to kidney function is the glomerular filtration barrier (GFB), which selectively filters waste while retaining essential proteins. Traditional…

Advanced Biology, In press, ⟨10.1002/adbi.202500108⟩. ⟨hal-05148948⟩

  • Article dans une revue

The Mosaic Structure of Zeolite Crystals

Zhengxing Qin, Georgian Melinte, Jean-Pierre Gilson, Maguy Jaber, Krassimir Bozhilov, Philippe Boullay, Svetlana Mintova, Ovidiu Ersen, Valentin Valtchev

Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride…

Angewandte Chemie International Edition, 2016, 55 (48), pp.15049-15052. ⟨10.1002/anie.201608417⟩. ⟨hal-02410439⟩

  • Article dans une revue

Porosity Design of Shaped Zeolites for Improved Catalyst Lifetime in the Methanol-to-Hydrocarbons Reaction

Rogéria Bingre, Renna Li, Qiang Wang, Patrick Nguyen, Thomas Onfroy, Benoit Louis

Additional porosity, such as meso-and macropores, was introduced in zeolite extrudates with the intention intuit of improving the effective diffusivity of the catalysts. The samples were characterized in depth by nitrogen adsorption-desorption, mercury intrusion porosimetry, ammonia temperature…

Catalysts, 2019, 9 (6), pp.545. ⟨10.3390/catal9060545⟩. ⟨hal-02271909⟩

  • Article dans une revue

An expeditious synthesis of early transition metal carbide nanoparticles on graphitic carbons

Debora Ressnig, Simona Moldovan, Ovidiu Ersen, Patricia Beaunier, David Portehault, Clément Sanchez, Sophie Carenco

An expeditious synthesis of metal carbide nanoparticles onto various carbon supports is demonstrated. The procedure is versatile and readily yields TiC, VC, Mo2C and W2C nanoparticles on different types of carbons. The reaction is initiated at room temperature and proceeds within seconds. This…

Chemical Communications, 2016, 52 (61), pp.9546-9549. ⟨10.1039/c6cc04157d⟩. ⟨hal-01346258v2⟩