Laboratoire de réactivité de surface

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  • Communication dans un congrès

Laboratory simulation to support the search for organic molecules at the surface of Mars

Olivier Poch, Cyril Szopa, Patrice Coll, Maguy Jaber, Thomas Georgelin, Jean-Francois Lambert, Fabien Stalport

The search for organic carbon at the surface of Mars, as clues of past habitability or remnants of life, is a major science goal of Mars’ exploration. Understanding the chemical evolution of organic molecules under current Martian environmental conditions is essential to support the analyses…

40th COSPAR Scientific Assembly, Aug 2014, Moscow, Russia. pp.Abstract B0.2-25-14. ⟨insu-01148653⟩

  • HDR

Petit Voyage vers la surface : Structure et réactivité de solides inorganiques, A small trip to the surface: structure and reactivity of inorganic solids

Lorenzo Stievano

Dans ma carrière, j'ai eu la chance et le privilège de m'attaquer à des problématiques scientifiques très variées, qui peuvent être ressemblées par le concept fédérateur de l'application de méthodes d'analyses physico-chimiques pour la compréhension de la structure et de la…

Catalyse. Université Pierre et Marie Curie - Paris VI, 2005. ⟨tel-00092493⟩

  • Article dans une revue

Sulfur Deactivation of NOx Storage Catalysts: A Multiscale Modeling Approach.

Nikola Rankovic, Céline Chizallet, Andre Nicolle, David Berthout, Patrick da Costa

Lean NOx Trap (LNT) catalysts, a promising solution for reducing the noxious nitrogen oxide emissions from the lean burn and Diesel engines, are technologically limited by the presence of sulfur in the exhaust gas stream. Sulfur stemming from both fuels and lubricating oils is oxidized during the…

Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles, 2013, 68 (6), pp.995-1005. ⟨10.2516/ogst/2013123⟩. ⟨hal-00934035⟩

  • Article dans une revue

High activity of mononuclear copper present in the framework of CuSiBEA zeolites in the selective catalytic reduction of NO with NH3

Rafal Baran, Teresa Grzybek, Thomas Onfroy, Stanislaw Dzwigaj

CuxSiBEA zeolites (with x = 1–7.5 Cu wt %) prepared by a two-step postsynthesis method which consists in the first step of dealumination of parent BEA zeolite to obtain aluminum-free SiBEA support and then in the second step, of contacting the obtained material with an aqueous solution of copper…

Microporous and Mesoporous Materials, 2016, 226, pp.104-109. ⟨10.1016/j.micromeso.2015.11.065⟩. ⟨hal-01263831⟩

  • Article dans une revue

Characterizations and performances of Ni/diatomite catalysts for dry reforming of methane

Karam Jabbour, Nissrine El Hassan, Anne Davidson, Pascale Massiani, Sandra Casale

Monometallic 5 wt% Ni containing catalysts were prepared by a two-solvent (cyclohexane/water) deposition method using cheap and widely available natural diatomites (Ni/AW2 and Ni/MN3) as supports. The fresh samples were characterized by SEM, EDX microanalysis, N2 adsorption–desorption isotherms,…

Journal Chemical Engineering, 2015, 264, pp.351-358. ⟨10.1016/j.cej.2014.11.109⟩. ⟨hal-01118933⟩

  • Article dans une revue

Superior Stability of Au/SiO 2 Compared to Au/TiO 2 Catalysts for the Selective Hydrogenation of Butadiene

Nazila Masoud, Laurent Delannoy, Herrick Schaink, Ad van Der Eerden, Jan Willem de Rijk, Tiago A. G. Silva, Dipanjan Banerjee, Johannes D. Meeldijk, Krijn P. de Jong, Catherine Louis, Petra E. de Jongh

Supported gold nanoparticles are highly selective catalysts for a range of both liquid-phase and gas-phase hydrogenation reactions. However, little is known about their stability during gas-phase catalysis and the influence of the support thereon. We report on the activity, selectivity, and…

ACS Catalysis, 2017, 7 (9), pp.5594 - 5603. ⟨10.1021/acscatal.7b01424⟩. ⟨hal-01651990⟩

  • Article dans une revue

What Do Tantalum Framework Sites Look Like in Zeolites? A Combined Theoretical and Experimental Investigation

Frederik Tielens, Tetsuya Shishido, Stanislaw Dzwigaj

Ab initio periodic DFT calculations on the structural and energy properties of different model tantalum framework sites in tantalum-substituted socialite cavities are presented and related to experimental FTIR measurements on Ta-containing SiBEA zeolites. The tantalum framework sites are…

Journal of Physical Chemistry C, 2010, 114 (21), pp.9923-9930. ⟨10.1021/jp102181m⟩. ⟨hal-00604808⟩

  • Article dans une revue

EPR Characterization and Reactivity of Surface-Localized Inorganic Radicals and Radical Ions

Mario Chiesa, Elio Giamello, Michel Che

A review. The role of surface inorg. radicals and radical ions formed at the interface between a solid and a gas phase was discussed. The formation of such species is relevant to field such as electrochem., heterogeneous catalysts, photocatalysis and corrosion. The characterization of these…

Chemical Reviews, 2010, 110 (3), pp.1320-1347. ⟨10.1021/cr800366v⟩. ⟨hal-00604710⟩

  • Article dans une revue

Sustainable production of acrolein: effects of reaction variables, modifiers doping and ZrO2 origin on the performance of WO3/ZrO2 catalyst for the gas-phase dehydration of glycerol

Song-Hai Chai, Li-Zhi Tao, Bo Yan, Jacques C. Vedrine, Bo-Qing Xu

Zirconia-supported tungsten oxide (WO3/ZrO2 or WZ) is known as an efficient catalyst for selective acrolein (AC) production from gas-phase dehydration of glycerol (GL). Two catalysts (WZ-CP and WZ-AN) were prepared herein using, respectively, a ZrO(OH)2 hydrogel (ZrO(OH)2-CP) and its derived…

RSC Advances, 2014, 4 (9), pp.4619-4630. ⟨10.1039/C3RA46511J⟩. ⟨hal-01079293⟩

  • Article dans une revue

Prebiotic chemistry

J.F. Lambert, M. Sodupe, P. Ugliengo

Without doubt, one of the most fascinating questions ever asked is ''What is life?'', immediately followed by ''How and where did life arise?''. Both questions are by no means exclusively related to chemistry and biology. Indeed, it was soon realized that…

Chemical Society Reviews, 2012, 41, pp.5373-5374. ⟨10.1039/c2cs90061k⟩. ⟨hal-00809265⟩