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Zn-Cu Alloy Nanofoams as Efficient Catalysts for the Reduction of CO 2 to Syngas Mixtures with a Potential-Independent H 2 /CO Ratio

Sarah Lamaison, David Wakerley, David Montero, Gwenaëlle Rousse, Dario Taverna, Domitille Giaume, Dimitri Mercier, Juliette Blanchard, Huan Ngoc Tran, Marc Fontecave, Marc Mougel

Alloying strategies are commonly used to design electrocatalysts that take on properties of their constituent elements. Herein, we explore the use of such a strategy to develop Zn-Cu alloyed electrodes with unique hierarchical porosity and tunable selectivity for CO2 vs. H + reduction. By varying…

ChemSusChem, 2019, 12 (2), pp.511-517. ⟨10.1002/cssc.201802287⟩. ⟨hal-02182388⟩

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Catalytic behavior of nickel loaded on acid-activated and pillared clay in total gas-phase oxidation of ethanol

Nadjat Lahoues-Chakour, Siham Barama, Akila Barama, Brahim Djellouli, Cyril Domingos, Anne Davidson

Layered and acid-activated clays, used as catalytic support, were synthesized from natural Algerian montmorillonite. All supports were prepared by (1) pillaring with aquo/hydroxo/oxo Al clusters, in particular Al13 that contains only octahedral Al-species, (2) an acidic H2SO4 treatment, and (3)…

Journal of Nanoparticle Research, 2018, 20 (11), pp.294. ⟨10.1007/s11051-018-4385-1⟩. ⟨hal-02022621⟩

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Stable Carboxylate-Terminated Gold Surfaces Produced by Spontaneous Grafting of an Alkyltin Compound

Mayreli Ortiz, Ahmed Debela, Christophe Méthivier, Serge Thorimbert, Bernold Hasenknopf, Ciara O'Sullivan

Chemistry - A European Journal, 2018, 24 (43), pp.11177 - 11184. ⟨10.1002/chem.201801854⟩. ⟨hal-01878679⟩

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Well-Defined Amphiphilic Block Copolymers and Nano-objects Formed in Situ via RAFT-Mediated Aqueous Emulsion Polymerization

Xuewei Zhang, Stephanie Boisse, Wenjing Zhang, Patricia Beaunier, Franck d'Agosto, Jutta Rieger, Bernadette Charleux

Macromolecules, 2011, 44 (11), pp.4149-4158. ⟨10.1021/ma2005926⟩. ⟨hal-01877415⟩

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Surface Segregation of Pd from TiO2-Supported AuPd Nanoalloys under CO Oxidation Conditions Observed In situ by ETEM and DRIFTS

Laurent Delannoy, Suzanne Giorgio, Jean-Gabriel Mattei, Claude R. Henry, Nadia El Kolli, Christophe M Éthivier, Catherine Louis

A TiO2-supported AuPd bimetallic catalyst with an Au/Pd atomic ratio of 8 was prepared by deposition-precipitation with urea, and its activity in CO oxidation at room temperature was compared to the one of a monometallic Au/TiO2 catalyst. X-ray photoelectron spectroscopy (XPS) and diffuse…

ChemCatChem, 2013, pp.1-11. ⟨10.1002/cctc.201200618⟩. ⟨hal-00836230⟩

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In situ observation of atomic redistribution in alloying gold-silver nanorods

Jessi E S van Der Hoeven, Tom a J Welling, Tiago a G da Silva, Jeroen E van den Reijen, Camille La Fontaine, Xavier Carrier, Catherine Louis, Alfons van Blaaderen, Petra E de Jongh

The catalytic performance and optical properties of bimetallic nanoparticles critically depend on the atomic distribution of the two metals in the nanoparticles. However, at elevated temperatures, during light induced heating or during catalysis atomic redistribution can occur. Measuring such metal…

ACS Nano, 2018, 12 (8), pp.8467-8476. ⟨10.1021/acsnano.8b03978⟩. ⟨hal-03157963⟩

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High activity of mononuclear copper present in the framework of CuSiBEA zeolites in the selective catalytic reduction of NO with NH3

Rafal Baran, Teresa Grzybek, Thomas Onfroy, Stanislaw Dzwigaj

CuxSiBEA zeolites (with x = 1–7.5 Cu wt %) prepared by a two-step postsynthesis method which consists in the first step of dealumination of parent BEA zeolite to obtain aluminum-free SiBEA support and then in the second step, of contacting the obtained material with an aqueous solution of copper…

Microporous and Mesoporous Materials, 2016, 226, pp.104-109. ⟨10.1016/j.micromeso.2015.11.065⟩. ⟨hal-01263831⟩

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Improved Experimental Setup to Reach a Broad Frequency Domain in Local Electrochemical Impedance Spectroscopy Measurements

Maurilio Pereira Gomes, Samantha Michelle Gateman, Isolda Costa, Oumaïma Gharbi, Kieu Ngo, Jesualdo Luiz Rossi, Mireille Turmine, Vincent Vivier

We report a new experimental setup enabling local electrochemical impedance spectroscopy (LEIS) measurements over a wide frequency range, including the low frequency domain. First, an improved signal treatment was performed using a potential shifter to minimize the DC component of the measured…

Measurement - Journal of the International Measurement Confederation (IMEKO), 2022, 200, pp.111504. ⟨10.1016/j.measurement.2022.111504⟩. ⟨hal-03719357⟩

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Influence of acid–base properties of Mg-based catalysts on transesterification: role of magnesium silicate hydrate formation

Damien Cornu, Longfei Lin, Maya Mounir Daou, Maguy Jaber, Jean-Marc Krafft, Virginie Herledan, Guillaume Laugel, Yannick Millot, Hélène Lauron-Pernot

The transesterification reaction assisted through heterogeneous basic catalysis was thoroughly studied because of its importance in transforming biomass, as for biodiesel production or lactone opening. As catalysts with the strongest basic properties are not always the most efficient ones, a series…

Catalysis science and Technology, 2017, 7 (8), pp.1701-1712. ⟨10.1039/C6CY02604D⟩. ⟨hal-01547299⟩

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Elaboration, activity and stability of silica-based nitroaromatic sensors

D. Mercier, Franck Pereira, Christophe Méthivier, Pierre Montméat, Lionel Hairault, Claire-Marie Pradier

Functionalized silica-based thin films, modified with hydrophobic groups, were synthesized and used as sensors for nitroaromatic compound (NAC) specific detection. Their performance and behavior, in terms of stability, ageing and regeneration, have been fully characterized by combining chemical…

Physical Chemistry Chemical Physics, 2013, 15, pp.12911--12919. ⟨10.1039/C3CP43406K⟩. ⟨hal-00918578⟩