• Article dans une revue

High pressures pathway toward boron-based nanostructured solids

Remi Grosjean, Yann Le Godec, Simon Delacroix, Guillaume Gouget, Patricia Beaunier, Ovidiu Ersen, Dris Ihiawakrim, Oleksandr O Kurakevych, Corinne Chanéac, David Portehault

Inorganic nanocomposites made of an inorganic matrix containing nanoparticle inclusions provide materials of advanced mechanical, magnetic, electrical properties and multifunctionality. The range of compounds that can be implemented in nanocomposites is still narrow and new preparation methods are…

Dalton Transactions, 2018, 47 (23), pp.7634-7639. ⟨10.1039/C8DT00932E⟩. ⟨hal-01883827⟩

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Defect-related multicolour emissions in ZnO tetrapods: from violet, over green to yellow

Miao Zhang, Frédéric Averseng, Francia Haque, Patrizia Borghetti, Jean-Marc Krafft, Benoît Baptiste, Guylène Costentin, Slavica Stankic

The nature of defects in ZnO smoke was studied at different stages of the materials' history by combining photoluminescence (PL) and electron paramagnetic resonance (EPR) spectroscopies. In contrast to studies previously reported on ZnO nanopowders, high vacuum conditions (P < 10-5 mbar)…

Nanoscale, 2019, 11 (11), pp.5102-5115. ⟨10.1039/C8NR09998G⟩. ⟨hal-02169364⟩

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Controlled Formation of Native Defects in Ultrapure ZnO for the Assignment of Green Emissions to Oxygen Vacancies

Fredeŕic Averseng, Miao Zhang, Frederic Averseng, Jean-Marc Krafft, Patrizia Borghetti, Guylène Costentin, Slavica Stankic

Ultrapure ZnO nanopowders were synthesized via vapor-phase based methods under oxygen deficient conditions. The type and relative proportions of intrinsic point defects were studied by photoluminescence (PL) and EPR spectroscopies performed under strictly controlled conditions. Besides coupled PL/…

Journal of Physical Chemistry C, In press, 124 (23), pp.12696-12704. ⟨10.1021/acs.jpcc.0c01078⟩. ⟨hal-02896623⟩

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Mesocellular silica foam-based Ni catalysts for dry reforming of CH4 (by CO2)

Oscar Daoura, Marie-Nour Kaydouh, Nissrine El-Hassan, Pascale Massiani, Franck Launay, Maya Boutros

Journal of CO2 Utilization, 2018, 24, pp.112-119. ⟨10.1016/j.jcou.2017.12.010⟩. ⟨hal-02414803⟩

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Molybdenum oxide catalysts for metathesis of higher 1-alkenes via supporting MoO2(acetylacetonate)2 and MoO2(glycolate)2 on SBA-15 mesoporous molecular sieves

Hynek Balcar, Diwa Mishra, E. Marceau, Xavier Carrier, Naděžda Žilková, Zdeněk Bastl

Applied Catalysis A : General, 2009, 359 (1-2), pp.129-135. ⟨10.1016/j.apcata.2009.02.037⟩. ⟨hal-03032165⟩

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Well-Defined Amphiphilic Block Copolymers and Nano-objects Formed in Situ via RAFT-Mediated Aqueous Emulsion Polymerization

Xuewei Zhang, Stephanie Boisse, Wenjing Zhang, Patricia Beaunier, Franck d'Agosto, Jutta Rieger, Bernadette Charleux

Macromolecules, 2011, 44 (11), pp.4149-4158. ⟨10.1021/ma2005926⟩. ⟨hal-01877415⟩

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Microporous polyacrylate matrix containing hydrogen bonded nanotubular assemblies

Farid Ouhib, Emmanuelle Bugnet, Andrei Nossov, Jean-Luc Bonardet, Laurent Bouteiller

We report the straightforward photo-polymn. of polyacrylate films contg. bis-urea based self-assembled nanotubes. The obtained materials are characterized by gas adsorption measurements, 129Xe NMR spectroscopy and WAXS. The presence of the bis-ureas is shown by butane adsorption (at 273 K and…

Polymer, 2010, 51 (15), pp.3360-3364. ⟨10.1016/j.polymer.2010.05.047⟩. ⟨hal-00604788⟩

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Thiol-Poly(Sodium Styrene Sulfonate) (PolyNaSS-SH) Gold Complexes: From a Chemical Design to a One-Step Synthesis of Hybrid Gold Nanoparticles and Their Interaction with Human Proteins

Ceĺine Falentin-Daudre, Mounia Aitouakli, Jean Sebastien Baumann, Nadia Bouchemal, Vincent Humblot, Veronique Migonney, Jolanda Spadavecchia

This study highlights recent advances in the synthesis of nanoconjugates based on gold (Au(III)) complex with a bioactive polymer bearing sulfonate groups called thiol-poly(sodium styrene sulfonate) (PolyNaSS-SH) with various molecular weights (5, 10, and 35 kDa). The three nanomaterials differ…

ACS Omega, 2020, pp.8137-8145. ⟨10.1021/acsomega.0c00376⟩. ⟨hal-02571960⟩

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Elaboration of Prussian Blue Analogue/Silica Nanocomposites: Towards Tailor-Made Nano-Scale Electronic Devices

Giulia Fornasieri, Merwe, Aouadi, Emilie Delahaye, Patricia Beaunier, D. Durand, Eric Rivière, Pierre-Antoine Albouy, François Brisset, Anne Bleuzen

The research of new molecular materials able to replace classical solid materials in electronics has attracted growing attention over the past decade. Among these compounds photoswitchable Prussian blue analogues (PBA) are particularly interesting for the elaboration of new optical memories.…

Materials, 2012, 5, pp.385-403. ⟨10.3390/ma5030385⟩. ⟨hal-00752239⟩

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Successive Strong Electrostatic Adsorptions of [RhCl6]3– on Tungstated-Ceria as an Original Approach to Preserve Rh Clusters From Sintering Under High-Temperature Reduction

Jeffrey Miller, Neil Schweitzer, Mimoun Aouine, Philippe Vernoux, Abdelmalik Boufar, Juliette Blanchard, Jean-Marc Krafft, Christophe Méthivier, Céline Sayag, Frédéric Ser, Mickaël Sicard, Cyril Thomas

Supported transition metal materials have been identified as ideal candidates for decades to catalyze various reactions of interest in the fields of hydrocarbon refining, energy and environmental catalysis. As the resources in transition metals on earth are known to be limited, it appears to be of…

Journal of Physical Chemistry C, 2021, 125 (45), pp.25094-25111. ⟨10.1021/acs.jpcc.1c07644⟩. ⟨hal-03449235⟩