• Article dans une revue

On the reactivity of NO/N2 mixtures with aluminum surfaces: a combined PM-IRRAS and QCM investigation

Aude Delebecque, Cyril Thomas, Claire-Marie Pradier, Christophe Methivier, Hervé Paoli, Martine Carré, Eric Coffre

Abstract. The interaction of NO, and the further reactivity of oxygen, with water-passivated aluminum surfaces are investigated for the first time by in situ Polarization Modulation Infrared Reflexion Absorption Spectroscopy (PM-IRRAS) coupled with Quartz Crystal Microbalance (QCM). Chemical and…

Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces, 2007, 602, pp.283-290. ⟨10.1016/j.susc.2007.10.035⟩. ⟨hal-00202695⟩

• Article dans une revue

Dispersion and hydrogenation activity of surfactant-stabilized Rh(0) nanoparticles prepared on different mesoporous supports

Maya Boutros, Guillaume Shirley, Thomas Onfroy, Franck Launay

Supported Rh(0) colloidal particles were prepared by the reduction of Rh(III) ions by sodium borohydride in the presence of N-N-dimethyl-N-cetyl-N-(2-hydroxyethyl) ammonium chloride (HEA16Cl), usually used as a stabilizing agent in solution. Tested supports were Na-Al-SBA-15, SBA-15 and CMK-3. In…

Applied Catalysis A : General, 2011, 394 (1-2), pp.158-165. ⟨10.1016/j.apcata.2010.12.035⟩. ⟨hal-00602935⟩

• Article dans une revue

Incorporation of Nb(V) into BEA zeolite investigated by XRD, NMR, IR, DR UV-vis, and XPS

Stanislaw Dzwigaj, Yannick Millot, Christophe Methivier, Michel Che

Nb(x)SiBEA (x = 1.0, 1.5 Nb wt%) zeolites are prepared by a two-step postsynthesis method involving first the creation of vacant T-atom sites associated with silanol groups by dealumination of BEA zeolite by nitric acid solution and then by impregnation of the resulting SiBEA zeolite with the…

Microporous and Mesoporous Materials, 2010, 130 (1-3), pp.162-166. ⟨10.1016/j.micromeso.2009.10.027⟩. ⟨hal-00604714⟩

• Article dans une revue

Enhancement of the Photoinduced Oxidation Activity of a Ruthenium(II) Complex Anchored on Silica-Coated Silver Nanoparticles by Localized Surface Plasmon Resonance

Kohsuke Mori, Masayoshi Kawashima, Michel Che, Hiromi Yamashita

Angewandte Chemie International Edition, 2010, 49 (46), pp.8598-8601. ⟨10.1002/anie.201004942⟩. ⟨hal-00604784⟩

• Article dans une revue

TiO2-supported Rh nanoparticles: From green catalyst preparation to application in arene hydrogenation in neat water

Claudie Hubert, Audrey Denicourt-Nowicki, Patricia Beaunier, Alain Roucoux

TiO2-supported Rh(0) nanoparticles were prepd. by an easy method under mild conditions in neat water. They proved to be highly active catalysts for arene hydrogenation in water with TOFs up to 33 333 h-1. [on SciFinder(R)]

Green Chemistry, 2010, 12 (7), pp.1167-1170. ⟨10.1039/C004079G⟩. ⟨hal-00604723⟩

• Article dans une revue

Formation of heteropolymolybdates during the preparation of Mo and NiMo HDS catalysts supported on SBA-15: Influence on the dispersion of the active phase and on the HDS activity

Alvaro Sampieri, Stephane Pronier, Sylvette Brunet, Xavier Carrier, Catherine Louis, Juliette Blanchard, Katia Fajerwerg, Michele Breysse

Mo and Ni-Mo sulfides in SBA-15 and Al-SBA-15 catalysts were prepd. by incipient wetness co-impregnation of molybdenum and nickel precursors (followed by thermal treatment under He at 823 K) and sulfidation under 10% H2S/H2 at 673 K. Only incipient wetness impregnation of Mo on pure silica SBA-15…

Microporous and Mesoporous Materials, 2010, 130 (1-3), pp.130-141. ⟨10.1016/j.micromeso.2009.10.024⟩. ⟨hal-00604795⟩

• Article dans une revue

From Al2O3-supported Ni(II)-ethylenediamine Complexes to CO Hydrogenation Catalysts: Importance of the Hydrogen Post-treatment Evidenced by XPS

Fabien Négrier, Eric Marceau, Michel Che, Jean-Marc Giraudon, Léon Gengembre, Axel Löfberg

Ni (7 wt%)/Al2O3 catalysts prepared by decomposition of Ni(II)-ethylenediamine complexes in inert atmosphere initially contain a mixture of metallic and oxidized nickel. X-ray photoelectron spectroscopy shows that after a hydrogen treatment at 500°C, the system contains more metallic nickel than…

Catalysis Letters, 2008, 124, pp.18..23. ⟨10.1007/s10562-008-9514-5⟩. ⟨hal-00308479⟩

• Communication dans un congrès

Kinetic modeling of carbon dioxide valorization with epoxides

Viviana Contreras Moreno, Alain Ledoux, Lionel Estel, Rabah Azzouz, Vincent Levacher, Laurent Bischoff, Salim Derrouiche

International Congress on Green Process Engineering (GPE, 5, 2016), Jun 2016, Mont-Tremblant, Canada. ⟨hal-02389135⟩

• Article dans une revue

Oxidative Dehydrogenation of Propane on Hydroxyapatite‐Supported Cobalt Catalysts

Corentin Reynaud, Cyril Thomas, Dalil Brouri, Josefine Schnee, Sandra Casale, Guylène Costentin

Hydroxyapatite (HAp)‐supported cobalt catalysts have been evaluated in the oxidative dehydrogenation of propane to propene (ODHP). The morphology of the HAp supports and the cobalt immobilization mechanisms strongly influence the surface accessibility of cobalt species and their dispersion. A…

ChemCatChem, 2025, 17 (10), pp.e202402100. ⟨10.1002/cctc.202402100⟩. ⟨hal-05370167⟩

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Monitoring of the Plasmon Resonance of Gold Nanoparticles in Au/TiO2 Catalyst under Oxidative and Reducing Atmospheres

Yves Borensztein, Laurent Delannoy, Anis Djedidi, Ruben G. Barrera, Catherine Louis

Diffuse optical reflectance of Au/TiO2 powder catalysts, prepared by the deposition-precipitation method, is measured in the UV-visible range in controlled atmosphere. An intense optical absorption observed around 550 nm is interpreted by the excitation of plasmon resonances in the 4 nm gold…

Journal of Physical Chemistry C, 2010, 114, pp.9008. ⟨10.1021/jp101248h⟩. ⟨hal-00490473⟩