• Article dans une revue

Effect of SAM chain length and binding functions on protein adsorption: β-Lactoglobulin and apo-transferrin on gold.

Erin E. Bedford, Vincent Humblot, Frank X. Gu, Claire-Marie Pradier

Controlled immobilization of proteins is crucial in many applications, including biosensors. Allergen biosensing, for example, requires molecular recognition of suitably immobilized proteins by specific antibodies and sensitive measurement of this interaction. Self-assembled monolayers (SAMs),…

Colloids and Surfaces B: Biointerfaces, 2014, 116, pp.489-96. ⟨10.1016/j.colsurfb.2014.01.031⟩. ⟨hal-00982250⟩

• Thèse

Confinement effect of Nickel in mesoporous silica-based catalysts for syngas production by reforming of methane with CO2, Effet de confinement du nickel dans des catalyseurs à base de silice mésoporeuse pour la production de gaz de synthèse par reformage du méthane avec le CO2

Marie-Nour Kaydouh

Although economically and environmentally advantageous, the methane dry reforming process using supported nickel based catalysts still faces problems of active phase (a transition metal) sintering and of carbon deposition, which result in catalytic activity loss. This thesis is focused on the study…, Malgré ses avantages économiques et environnementaux, le procédé de reformage à sec du méthane sur des catalyseurs au nickel supporté se heurte encore à des problèmes de frittage de la phase active (un métal de transition) et de dépôt de carbone, ce qui entraîne une diminution de l'activité…

Analytical chemistry. Université Pierre et Marie Curie - Paris VI; Université de Balamand (Tripoli, Liban), 2016. English. ⟨NNT : 2016PA066425⟩. ⟨tel-01628885⟩

• Article dans une revue

Molecular Understanding of the Bulk Composition of Crystalline Nonstoichiometric Hydroxyapatites: Application to the Rationalization of Structure-Reactivity Relationships

Manel Ben Osman, Jean Marc Krafft, Yannick Millot, Frederic Averseng, Tetsuya Yoshioka, Jun Kubo, Guylène Costentin

Crystalline hydroxyapatite samples (HAps) have been prepared by using the co-precipitation method under various pH conditions, leading to nonstoichiometric solids (1.65 < Ca/P < 1.77). The aim of this study was to rationalize the sensitivity of the catalytic activity of HAps to their bulk…

European Journal of Inorganic Chemistry, 2016, 2016 (17), pp.2709 - 2720. ⟨10.1002/ejic.201600244⟩. ⟨hal-01378491⟩

• Article dans une revue

Introduction of Co into the Vacant T-Atom Sites of SiBEA Zeolite as Isolated Mononuclear Co Species

Rafal Baran, Thomas Onfroy, Sandra Casale, Stanislaw Dzwigaj

A CoSiBEA zeolite was obtained by a postsynthesis method which consisted of a treatment of tetraethylammonium BEA zeolite with nitric acid in the first step and introduction of Co ions into the vacant T atom sites of the SiBEA zeolite by reaction of aqueous Co(NO3)2 solution with silanol groups.…

Journal of Physical Chemistry C, 2014, 118 (35), pp.20445-20451. ⟨10.1021/jp506375v⟩. ⟨hal-01077988⟩

• Communication dans un congrès

Au-Cu Nanoparticules supported on Ti02: an efficient catalyst for selective hydrogenation of 1,3-butadiene

Laurent Delannoy, Catherine R Louis, Trimurthulu Gode, P.S. Reddy, B.M. Reddy, J. Nelayah, Ricolleau C.

2nd International Symposium on Intermetallic Compounds in Methanol Steam Reforming, Jun 2012, Munich, Germany. ⟨hal-01547421⟩

• Article dans une revue

Ordered Nanostructures on a Hydroxylated Aluminum Surface through the Self-Assembly of Fatty Acids.

Irma Liascukiene, Nesrine Aissaoui, Svajus J. Asadauskas, Jessem Landoulsi, Jean-François Lambert

We investigate the mechanism of self-assembly of fatty acids (FA) and methyl oleate on an Al oxy-hydroxide surface with a view to deciphering the role and nature of interfacial processes (adsorption, chemical binding, molecular organization, etc.). For this purpose, we focus on parameters related…

Langmuir, 2012, 28, pp.5116-5124. ⟨10.1021/la2051542⟩. ⟨hal-00688636⟩

• Article dans une revue

Chromium Oxide Species Supported on Silica: A Representative Periodic DFT Model

Hazar Guesmi, Frederik Tielens

The Cr/SiO2 system is investigated using periodic DFT. The model represents the amorphous character of the silica surface and allows the investigation of the effect of hydration on the Cr(VI) monomers. First, the geometry and energetics are discussed and compared with experimental data. The phase…

Journal of Physical Chemistry C, 2011, 116, pp.994-1001. ⟨10.1021/jp209680r⟩. ⟨hal-00690824⟩

• Article dans une revue

Hexacyano Ferrate (III) Reduction by Electron Transfer Induced by Plasmonic Catalysis on Gold Nanoparticles

Iyad Sarhid, Isabelle Lampre, Diana Dragoe, Patricia Beaunier, Bruno Palpant, Hynd Remita

Materials, 2019, 12 (18), pp.3012. ⟨10.3390/ma12183012⟩. ⟨hal-02316679⟩

• Article dans une revue

Chemical Modifications of Au/SiO2 Template Substrates for Patterned Biofunctional Surfaces

Elisabeth Briand, Vincent Humblot, Jessem Landoulsi, Sarunas Petronis, Claire-Marie Pradier, Bengt Kasemo, Sofia Svedhem

The aim of this work was to create patterned surfaces for localized and specific biochemical recognition. For this purpose, we have developed a protocol for orthogonal and material-selective surface modifications of microfabricated patterned surfaces composed of SiO2 areas (100 mu m diameter)…

Langmuir, 2011, 27 (2), pp.678-685. ⟨10.1021/la101858y⟩. ⟨hal-00602936⟩

• Article dans une revue

Halide-free CO 2 cycloaddition onto styrene oxide catalysed by first row transition-metal derivatives of polyoxotungstates

Jingjing Ren, Franck Launay, Richard Villanneau, Anna Proust

Quaternary ammonium salts of metal derivatives of polyoxometalates [XW11O39M(H2O)]n- (X = P, Si; M = Cr, Mn, Co, Ni, Zn) were successfully tested instead of quaternary ammonium halides as catalysts in the cycloaddition of CO2 to styrene oxide. Remarkably, they gave very satisfactory yields of…

Chemical Communications, 2024, ⟨10.1039/D4CC00522H⟩. ⟨hal-04545491⟩