• Article dans une revue

Discrimination of infrared fingerprints of bulk and surface POH and OH of hydroxyapatites

Sarah Diallo-Garcia, Manel Ben Osman, Jean-Marc Krafft, Souhir Boujday, Guylene Costentin

The identification of the nature of the surface acid base pairs present on hydroxyapatites surface is a key point to rationalize their catalytic properties. To investigate the possible involvement of acidic protonated phosphate (POH) and/or of basic OH emerging from the channels, the spectroscopic…

Catalysis Today, 2014, 226, pp.81-88. ⟨10.1016/j.cattod.2013.11.041⟩. ⟨hal-00982290⟩

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Cobalt Based Catalysts Supported on Two Kinds of Beta Zeolite for Application in Fischer-Tropsch Synthesis

Renata Sadek, Karolina Chalupka, Pawel Mierczynski, Jacek Rynkowski, Jacek Gurgul, Stanislaw Dzwigaj

Co-containing Beta zeolite catalysts prepared by a wet impregnation and two-step postsynthesis method were investigated. The activity of the catalysts was examined in Fischer-Tropsch synthesis (FTS), performed at 30 atm and 260 °C. The physicochemical properties of all systems were investigated by…

Catalysts, 2019, 9 (6), pp.497. ⟨10.3390/catal9060497⟩. ⟨hal-02271879⟩

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Transforming a Diamagnetic Ordered Mesoporous Silica Monolith into a Room Temperature Permanent Magnet through Multiscale Control of the Magnetic Properties

Virgile Trannoy, Laura Altenschmidt, Giulia Fornasieri, Amélie Bordage, Eric Rivière, Patricia Beaunier, Anne Bleuzen

ChemNanoMat, 2018, 4 (12), pp.1254-1261. ⟨10.1002/cnma.201800333⟩. ⟨hal-02353510⟩

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Bimetallic Au-Ag/TiO2 catalyst prepared by deposition-precipitation: High activity and stability in CO oxidation

A. Sandoval, A. Aguilar, C. Louis, Agnes Traverse, Rodolfo Zanella

Au-Ag bimetallic catalysts supported on TiO2 were prepared by sequential deposition-precipitation method, silver first and then gold. Au-Ag catalysts with different Au/Ag atomic ratios were synthesized. XANES and H2 TPR results show that gold is more easily reduced in bimetallic catalysts than in…

Journal of Catalysis, 2011, 281, pp.40-49. ⟨10.1016/j.cat.2011.04.003⟩. ⟨hal-00666778⟩

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In vitro synthesis of amorphous Mg-, Ca-, Sr- and Ba-carbonates: what do we learn about intracellular calcification by cyanobacteria?

Nithavong Cam, Thomas Georgelin, Maguy Jaber, Jean-François Lambert, Karim Benzerara

Some cyanobacteria, including Candidatus Gloeomargarita lithophora, which was isolated from Lake Alchichica (Mexico), can form intracellular carbonates. This contradicts the common paradigm that cyanobacterial calcification is always extracellular and suggests that calcification might be controlled…

Geochimica et Cosmochimica Acta, 2015, 161, pp.36-49. ⟨10.1016/j.gca.2015.04.003⟩. ⟨hal-01147190⟩

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High pressures pathway toward boron-based nanostructured solids

Remi Grosjean, Yann Le Godec, Simon Delacroix, Guillaume Gouget, Patricia Beaunier, Ovidiu Ersen, Dris Ihiawakrim, Oleksandr O Kurakevych, Corinne Chanéac, David Portehault

Inorganic nanocomposites made of an inorganic matrix containing nanoparticle inclusions provide materials of advanced mechanical, magnetic, electrical properties and multifunctionality. The range of compounds that can be implemented in nanocomposites is still narrow and new preparation methods are…

Dalton Transactions, 2018, 47 (23), pp.7634-7639. ⟨10.1039/C8DT00932E⟩. ⟨hal-01883827⟩

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Nanoporous Materials as New Engineered Catalysts for the Synthesis of Green Fuels

Ioana Fechete, Jacques Vedrine

This review summarizes the importance of nanoporous materials and their fascinating structural properties with respect to the catalytic and photocatalytic reduction of CO2 to methane, toward achieving a sustainable energy supply. The importance of catalysis as a bridge step for advanced energy…

Molecules, 2015, 20 (4), pp.5638-5666. ⟨10.3390/molecules20045638⟩. ⟨hal-01226491⟩

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Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si / Al lower limit

Marcelo Maciel Pereira, Elisa Gomes, Alessandra Vieira Silva, Ana Belen Pinar, Marc-Georg Willinger, Sangaraju Shanmugam, Céline Chizallet, Guillaume Laugel, Pit Losch, Benoit Louis

A family of Al-rich ZSM-5 zeolites with Si / Al = 8 ± 0.5 was prepared according to a biomass-mediated supramolecular approach. A combination of advanced characterisation techniques and periodic density functional theory (DFT) calculations unraveled the purity and stability of unexpected Al-…

Chemical Science, 2018, 9 (31), pp.6532 - 6539. ⟨10.1039/C8SC01675E⟩. ⟨hal-01882119v2⟩

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Elaboration of a reusable immunosensor for the detection of staphylococcal enterotoxin A (SEA) in milk with a quartz crystal microbalance

Michèle Salmain, Mahsa Ghasemi, Souhir Boujday, Claire-Marie Pradier

An immunosensor with quartz crystal microbalance (QCM) detection operating in flow-through mode was set up for assaying staphylococcal enterotoxin A (SEA) in model buffer medium and in milk. This biosensor is label-free and operates in the direct format. Each step of construction of the sensing…

Sensors and Actuators B: Chemical, 2012, 173, pp.148-156. ⟨10.1016/j.snb.2012.06.052⟩. ⟨hal-00744497⟩

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Surface Science Approach to the Solid-Liquid Interface: Surface-Dependent Precipitation of Ni(OH)2 on a-Al2O3 Surfaces

Asma Tougerti, Isabelle Llorens, Francesco d'Acapito, Emiliano Fonda, Jean-Louis Hazemann, Yves Joly, Dominique Thiaudi Ère, Michel Che, Xavier Carrier

A molecular-scale understanding of the adsorption of metal ions on oxide surfaces is of fundamental importance for various scientific areas where the oxide/water interface plays a central role, such as corrosion science, preparation of heterogeneous catalysts, transport of contaminants in the…

Angewandte Chemie International Edition, 2012, 51, pp.7697-7701. ⟨10.1002/anie.201201349⟩. ⟨hal-00749941⟩