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  • Article dans une revue

Nanoporous Materials as New Engineered Catalysts for the Synthesis of Green Fuels

Ioana Fechete, Jacques Vedrine

This review summarizes the importance of nanoporous materials and their fascinating structural properties with respect to the catalytic and photocatalytic reduction of CO2 to methane, toward achieving a sustainable energy supply. The importance of catalysis as a bridge step for advanced energy…

Molecules, 2015, 20 (4), pp.5638-5666. ⟨10.3390/molecules20045638⟩. ⟨hal-01226491⟩

  • Article dans une revue

Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si / Al lower limit

Marcelo Maciel Pereira, Elisa Gomes, Alessandra Vieira Silva, Ana Belen Pinar, Marc-Georg Willinger, Sangaraju Shanmugam, Céline Chizallet, Guillaume Laugel, Pit Losch, Benoit Louis

A family of Al-rich ZSM-5 zeolites with Si / Al = 8 ± 0.5 was prepared according to a biomass-mediated supramolecular approach. A combination of advanced characterisation techniques and periodic density functional theory (DFT) calculations unraveled the purity and stability of unexpected Al-…

Chemical Science, 2018, 9 (31), pp.6532 - 6539. ⟨10.1039/C8SC01675E⟩. ⟨hal-01882119v2⟩

  • Article dans une revue

High activity of mononuclear copper present in the framework of CuSiBEA zeolites in the selective catalytic reduction of NO with NH3

Rafal Baran, Teresa Grzybek, Thomas Onfroy, Stanislaw Dzwigaj

CuxSiBEA zeolites (with x = 1–7.5 Cu wt %) prepared by a two-step postsynthesis method which consists in the first step of dealumination of parent BEA zeolite to obtain aluminum-free SiBEA support and then in the second step, of contacting the obtained material with an aqueous solution of copper…

Microporous and Mesoporous Materials, 2016, 226, pp.104-109. ⟨10.1016/j.micromeso.2015.11.065⟩. ⟨hal-01263831⟩

  • Article dans une revue

Versatile and robust synthesis process for the fine control of the chemical composition and core-crystallinity of spherical core-shell Au@Ag nanoparticles

Suyeon Lee, Hervé Portalès, Michael Walls, Patricia Beaunier, Nicolas Goubet, Benoit Tremblay, Jérémie Margueritat, Lucien Saviot, Alexa Courty

Au nanoparticles (NPs) characterized by distinct surface chemistry (including dodecanethiol or oleylamine as capping agent), different sizes (~5 and ~10 nm) and crystallinities (polycrystalline or single crystalline), were chosen as seeds to demonstrate the versatility and robustness of our two-…

Nanotechnology, 2021, 32, pp.095604. ⟨10.1088/1361-6528/abc450⟩. ⟨hal-02994816⟩

  • Article dans une revue

On the preparation of multifunctional conversion coatings of FePO 4 /LiFePO 4

S. Valverde-Pérez, R. Figueroa, X.R. Nóvoa, D.S. Ramírez-Rico, Vincent Vivier

This research aims to take advantage of the properRes of phosphate coaRngs to overcome the problems inherent in using LiFePO4 as a powder. LiFePO4 coaRngs have been prepared on iron sheets using cyclic voltammetry in an aqueous soluRon of H3PO4 and LiOH. The voltammograms evolved from the iniRal…

Surface and Coatings Technology, 2024, 479, pp.130548. ⟨10.1016/j.surfcoat.2024.130548⟩. ⟨hal-04775533⟩

  • Article dans une revue

Heteropolytungstate-decorated core-shell magnetic nanoparticles: A covalent strategy for polyoxometalate-based hybrid nanomaterials

Ourania Makrygenni, Emilie Secret, Aude Michel, Dalil Brouri, Vincent Dupuis, Anna Proust, Jean-Michel Siaugue, Richard Villanneau

Amino-functionalized core-shell magnetic nanoparticles have been covalently grafted with Polyoxometalates (POMs). These multifunctional nanocomposites have been obtained through the coupling of heteropolytungstate-based hybrids bearing carboxylic acid functions with aminopropyl functions that…

Journal of Colloid and Interface Science, 2018, 514, pp.49-58. ⟨10.1016/j.jcis.2017.12.019⟩. ⟨hal-03511208v2⟩

  • Article dans une revue

Gold/Polyoxometalate Core/Shell Nanoparticles for Combined Chemotherapy–Photothermal Cancer Therapy

Somia Tomane, Claire Wilhelm, Souhir Boujday, Alexandre Fromain, Antoine Miche, Flavien Bourdreux, Anne Dolbecq, Pierre Mialane, Anne Vallée

We designed monodisperse and perfectly shaped core/shell AuNP@Mo4Zol2Mn nanohybrids consisting of gold nanoparticles (AuNPs) functionalized by an antitumoral polyoxometalate (POM) incorporating the biologically active zoledronate ligand. After incubation, the nanoparticles were readily confined in…

ACS Applied Nano Materials, 2021, 4 (3), pp.2339-2344. ⟨10.1021/acsanm.0c03187⟩. ⟨hal-03214106⟩

  • Article dans une revue

Hierarchical Self-Assembly of Polyoxometalate-Based Hybrids Driven by Metal Coordination and Electrostatic Interactions: From Discrete Supramolecular Species to Dense Monodisperse Nanoparticles

Guillaume Izzet, Benjamin Abécassis, Dalil Brouri, Madeleine Piot, Benjamin Matt, Stefano Artin Serapian, Carles Bo, Anna Proust

The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing remote terpyridine binding sites have been investigated. In a strongly dissociating solvent, a discrete metallomacrocycle, described as a molecular triangle, is formed and characterized by 2D diffusion…

Journal of the American Chemical Society, 2016, 138 (15), pp.5093 - 5099. ⟨10.1021/jacs.6b00972⟩. ⟨hal-01548125⟩

  • Article dans une revue

Interaction of ZnII porphyrin with TiO2 nanoparticles: from mechanism to synthesis of hybrid nanomaterials.

Jolanda Spadavecchia, Christophe Méthivier, Jessem Landoulsi, Claire-Marie Pradier

The mechanism of interaction of Zn porphyrin (ZnPP) with TiO2 surfaces is investigated with a view to optimizing the synthesis of hybrid nanomaterials. The strategy consists of studying the adsorption of ZnPP on TiO2 flat surfaces by taking advantage of complementary surface characterization…

ChemPhysChem, 2013, 14, pp.2462-2469. ⟨10.1002/cphc.201300193⟩. ⟨hal-00983739⟩

  • Article dans une revue

Thiol-Poly(Sodium Styrene Sulfonate) (PolyNaSS-SH) Gold Complexes: From a Chemical Design to a One-Step Synthesis of Hybrid Gold Nanoparticles and Their Interaction with Human Proteins

Ceĺine Falentin-Daudre, Mounia Aitouakli, Jean Sebastien Baumann, Nadia Bouchemal, Vincent Humblot, Veronique Migonney, Jolanda Spadavecchia

This study highlights recent advances in the synthesis of nanoconjugates based on gold (Au(III)) complex with a bioactive polymer bearing sulfonate groups called thiol-poly(sodium styrene sulfonate) (PolyNaSS-SH) with various molecular weights (5, 10, and 35 kDa). The three nanomaterials differ…

ACS Omega, 2020, pp.8137-8145. ⟨10.1021/acsomega.0c00376⟩. ⟨hal-02571960⟩