• Article dans une revue

Investigating nalidixic acid adsorption onto ferrihydrite and maghemite surfaces: molecular-level insights <i>via</i> continuous-flow ATR-FTIR spectroscopy

Ana C Schuh Frantz, Alberto Mezzetti, Ari Paavo Seitsonen, Sylvie Nelieu, Etienne Balan, Guillaume Morin, Xavier Carrier

Contaminants sequestration by iron oxides are of particular relevance in environmental chemistry and Fourier Transform Infrared (FTIR) Spectroscopy in Attenuated Total Reflectance (ATR) mode is used in this study to investigate the molecular-scale adsorption mechanism of the antibiotic nalidixic…

• Article dans une revue

Catalytic Pyrolysis of Plastics over Maghemite-Impregnated Mesocellular Foam using Induction Heating

Luing Wong Syie, Sabino Armenise, B. Nyakuma Bemgba, Soon Ng Pang, Hau Lee Chia, Anna Bogush, Franck Launay, Evgeny Rebrov, Marta Munoz

Pyrolysis is a key technology that converts unrecyclable end-of-life plastics into value-added products. Nevertheless, the high energy consumption during plastic pyrolysis limits the economic feasibility of a scaled-up process. Development of an energy-efficient plastic pyrolysis process is…

Chemical Engineering Transactions, 2022, 97, pp.25. ⟨10.3303/CET2297005⟩. ⟨hal-04030193⟩

• Article dans une revue

Boronic species as promising inhibitors of the Staphylococcus aureus NorA efflux pump: Study of 6-substituted pyridine-3-boronic acid derivatives

Fanny Fontaine, Arnaud Héquet, Anne-Sophie Voisin-Chiret, Alexandre Bouillon, Aurélien Lesnard, Thierry Cresteil, Claude Jolivalt, Sylvain Rault

In response to the extensive use of antibiotics, bacteria have evolved numerous mechanisms of defense against antimicrobial agents. Among them, extrusion of the antimicrobial agents outside the bacterial cell through efflux pumps is a major cause of concern. At first limited to one or few…

European Journal of Medicinal Chemistry, 2015, 95, pp.185-198. ⟨10.1016/j.ejmech.2015.02.056⟩. ⟨hal-01170424⟩

• Article dans une revue

Room-Temperature Synthesis of Iron-Doped Anatase TiO2 for Lithium-Ion Batteries and Photocatalysis

Christian Andriamiadamanana, C. Laberty-Robert, Moulay Tahar Sougrati, Sandra Casale, Carine Davoisne, Snehangshu Patra, Frédéric Sauvage

Iron-doped nanocrystalline particles of anatase TiO2 have been successfully synthesized using a complete room-temperature synthetic approach, leading to particles of high surface area (280 m2/g) and a narrowed band gap of 2.3 eV. These particles were introduced for photocatalysis under white light…

Inorganic Chemistry, 2014, pp.10129-10139. ⟨10.1021/ic501067p⟩. ⟨hal-01094375⟩

• Article dans une revue

l-Methionine adsorption on Cu(110), binding and geometry of the amino acid as a function of coverage

Christophe Méthivier, Vincent Humblot, Claire-Marie Pradier

The adsorption of l-methionine on Cu(110) has been characterized by combining in situ Polarization Modulation Infrared Reflection Absorption Spectroscopy (PM-IRRAS) and X-ray Photoelectron Spectroscopy (XPS). Both the chemical state of the molecule, and its anchoring points were determined at…

Applications of Surface Science, 2015, 632, pp.88-92. ⟨10.1016/j.susc.2014.09.007⟩. ⟨hal-01117667⟩

• Article dans une revue

Catalytic conversion of trichloroethylene on nickel containing beta zeolites into value added products

A. Śrębowata, R. Baran, D. Lisovytskiy, I.I. Kamińska, S. Dzwigaj

Nickel containing BEA zeolites, NiSiBEA and NiHAlBEA, with 2 wt% of Ni were prepared by a two-step postsynthesis method and conventional wet impregnation. The calcination of NiSiBEA and NiHAlBEA at 773 K for 3 h in air led to the formation of C-NiSiBEA and C-NiHAlBEA. After reduction at 873 K for 3…

Catalysis Communications, 2014, 57, pp.107-110. ⟨10.1016/j.catcom.2014.08.023⟩. ⟨hal-01117203⟩

• Article dans une revue

Discrimination of infrared fingerprints of bulk and surface POH and OH of hydroxyapatites

Sarah Diallo-Garcia, Manel Ben Osman, Jean-Marc Krafft, Souhir Boujday, Guylene Costentin

The identification of the nature of the surface acid base pairs present on hydroxyapatites surface is a key point to rationalize their catalytic properties. To investigate the possible involvement of acidic protonated phosphate (POH) and/or of basic OH emerging from the channels, the spectroscopic…

Catalysis Today, 2014, 226, pp.81-88. ⟨10.1016/j.cattod.2013.11.041⟩. ⟨hal-00982290⟩

• Article dans une revue

Interaction of ZnII porphyrin with TiO2 nanoparticles: from mechanism to synthesis of hybrid nanomaterials.

Jolanda Spadavecchia, Christophe Méthivier, Jessem Landoulsi, Claire-Marie Pradier

The mechanism of interaction of Zn porphyrin (ZnPP) with TiO2 surfaces is investigated with a view to optimizing the synthesis of hybrid nanomaterials. The strategy consists of studying the adsorption of ZnPP on TiO2 flat surfaces by taking advantage of complementary surface characterization…

ChemPhysChem, 2013, 14, pp.2462-2469. ⟨10.1002/cphc.201300193⟩. ⟨hal-00983739⟩

• Article dans une revue

EPR Characterization and Reactivity of Surface-Localized Inorganic Radicals and Radical Ions

Mario Chiesa, Elio Giamello, Michel Che

A review. The role of surface inorg. radicals and radical ions formed at the interface between a solid and a gas phase was discussed. The formation of such species is relevant to field such as electrochem., heterogeneous catalysts, photocatalysis and corrosion. The characterization of these…

Chemical Reviews, 2010, 110 (3), pp.1320-1347. ⟨10.1021/cr800366v⟩. ⟨hal-00604710⟩

• Article dans une revue

A simple thermodynamic approach to predict responses from polymer-coated quartz crystal microbalance sensors exposed to organic vapors.

P. Palmas, J. Klingenfus, A. Vedeau, E. Girard, P. Montméat, L. Hairault, C.M. Pradier, C. Methivier

As of lately, the demand for developing artificial sensors with improved capabilities for the detection of explosives, toxics or drugs has increased. Ideally, sensor devices should provide high sensitivity and give a response that is specific to a given target molecule without being influenced by…

Talanta, 2013, 115, pp.616-623. ⟨10.1016/j.talanta.2013.06.017⟩. ⟨hal-00958092⟩