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  • Article dans une revue

Proton irradiation: a key to the challenge of N-glycosidic bond formation in a prebiotic context

Raffaele Saladino, Bruno M. Bizzarri, Lorenzo Botta, Jiří Šponer, Judit E. Šponer, Thomas Georgelin, Maguy Jaber, Baptiste Rigaud, Michail Kapralov, Gennady N. Timoshenko, Alexei Rozanov, Eugene Krasavin, Anna Maria Timperio, Ernesto Di Mauro

Scientific Reports, 2017, 7 (1), ⟨10.1038/s41598-017-15392-8⟩. ⟨hal-01651973⟩

  • Article dans une revue

Stabilization of ribofuranose by a mineral surface

Thomas Georgelin, Maguy Jaber, Frederic Fournier, Guillaume Laurent, France Costa-Torro, Marie-Christine Maurel, Jean-François Lambert

The existence of the ribose moiety in biomolecules poses two problems for prebiotic chemistry. First, the exclusive presence of the furanose isomer in RNA has to be accounted for since furanose is a minor form in solution and does not exist in crystals. Second, all D-ribose polymorphs are unstable…

Carbohydrate Research, 2015, 402, pp.241-244. ⟨10.1016/j.carres.2014.07.018⟩. ⟨hal-01275035⟩

  • Article dans une revue

Selective uptake of alkaline earth metals by cyanobacteria forming intracellular carbonates

Nithavong Cam, Karim Benzerara, Thomas Georgelin, Maguy Jaber, Jean-Francois Lambert, Melanie Poinsot, Feriel Skouri-Panet, Laure Cordier

The uptakes of Ca, Sr and Ba by two cyanobacterial strains, Cyanothece sp. PCC7425 and Gloeomargarita lithophora, both forming intracellular carbonates, were investigated in laboratory cultures. In the culture medium BG 11 amended with 250 μM of Ca and 50 or 250 μM of Sr and Ba, G. lithophora…

Environmental Science and Technology, 2016, 50 (21), pp.11654-11662. ⟨10.1021/acs.est.6b02872⟩. ⟨hal-01383264⟩

  • Article dans une revue

Fischer carbene mediated covalent grafting of a peptide nucleic acid on gold surfaces and IR optical detection of DNA hybridization with a transition metalcarbonyl label

Pratima Srivastava, Mahsa Ghasemi, Namrata Ray, Amitabha Sarkar, Jana Kocabova, Stepanka Lachmanova, Magdalena Hromadova, Souhir Boujday, Silvia Cauteruccio, Emanuela Licandro, Pramod Thakare, Céline Fosse, Michèle Salmain

Amine-reactive surfaces comprising N-hydroxysuccinimide ester groups as well as much more unusual Fischer alkoxymetallocarbene groups were generated on gold-coated surfaces via self-assembled monolayers of carboxy- and azido-terminated thiolates, respectively. These functions were further used to…

Applied Surface Science, 2016, 385, pp.47-55. ⟨10.1016/j.apsusc.2016.05.058⟩. ⟨hal-01325035⟩

  • Article dans une revue

Investigation of ionic surfactant-selective electrodes by EIS

Claude Gabrielli, Patrick Hemery, Pierre Letellier, Michele Masure, Hubert Perrot, Marie-Isabelle Rahmi, Mireille Turmine

A model of ionic surfactant-selective electrodes with mobile ionic sites is proposed. The steady-state concentrations of the active species are calculated. The electrochemical impedance of the membrane immersed between electrolytic solutions is given. This model is in good agreement with the…

Electrochimica Acta, 2002, 47 (13-14), pp.2117-2126. ⟨10.1016/S0013-4686(02)00083-X⟩. ⟨hal-04219890⟩