• Article dans une revue

EPR Characterization and Reactivity of Surface-Localized Inorganic Radicals and Radical Ions

Mario Chiesa, Elio Giamello, Michel Che

A review. The role of surface inorg. radicals and radical ions formed at the interface between a solid and a gas phase was discussed. The formation of such species is relevant to field such as electrochem., heterogeneous catalysts, photocatalysis and corrosion. The characterization of these…

Chemical Reviews, 2010, 110 (3), pp.1320-1347. ⟨10.1021/cr800366v⟩. ⟨hal-00604710⟩

• Article dans une revue

Successive Strong Electrostatic Adsorptions of [RhCl6]3– on Tungstated-Ceria as an Original Approach to Preserve Rh Clusters From Sintering Under High-Temperature Reduction

Jeffrey Miller, Neil Schweitzer, Mimoun Aouine, Philippe Vernoux, Abdelmalik Boufar, Juliette Blanchard, Jean-Marc Krafft, Christophe Méthivier, Céline Sayag, Frédéric Ser, Mickaël Sicard, Cyril Thomas

Supported transition metal materials have been identified as ideal candidates for decades to catalyze various reactions of interest in the fields of hydrocarbon refining, energy and environmental catalysis. As the resources in transition metals on earth are known to be limited, it appears to be of…

Journal of Physical Chemistry C, 2021, 125 (45), pp.25094-25111. ⟨10.1021/acs.jpcc.1c07644⟩. ⟨hal-03449235⟩

• Article dans une revue

Selective Oxidation of Methane to Formaldehyde Catalyzed by Phosphates: Kinetic Description by Bond Strengths and Specific Total Acidities

Vasilij Gomonaj, Hervé Toulhoat

A kinetic model predicts the experimental activity and selectivity patterns obtained in oxidation of methane for divided unsupported orthophosphates (M II 3(PO4)2, M III PO4,) and pyrophosphates (M II 2P2O7, M IV P2O7) catalysts spanning extended ranges of M-O bond strength (calculated from first…

ACS Catalysis, 2018, 8 (9), pp.8263-8272. ⟨10.1021/acscatal.8b02629⟩. ⟨hal-01955648⟩

• Article dans une revue

Vibrating single probe and stationary bi-probes to measure local electrochemical impedance spectroscopy.

Hisasi Takenouti, G. Galicia, Michel Keddam, Vincent Vivier

The electrochemical impedance spectroscopy is widely used to investigate the electrode kinetics. This method is recognized as a powerful method to discriminate one reaction model to another and also to evaluate the reaction rate of elementary steps. However, when the electrode kinetics is markedly…

Bulgarian Chemical Communications, 2006, 38 (3), pp.165-175. ⟨hal-04172938⟩

• Article dans une revue

Nanostructured and spiky gold in biomolecule detection: improving binding efficiencies and enhancing optical signals

E. E. Bedford, S. Boujday, C.-M. Pradier, F. X. Gu

Nanostructured gold can improve the ability to detect biomolecules. Whether planar nanostructured surfaces or nanostructured particles are used, similar principles governing the enhancement apply. The two main benefits of nanostructured gold are improved geometry and enhancement of optical…

RSC Advances, 2015, 5 (21), pp.16461-16475. ⟨10.1039/c4ra13544j⟩. ⟨hal-01133167⟩

• Article dans une revue

Corrosion and protection of high leaded tin bronze covered with patina in NaHCO3 + Na2SO4 solution simulating acid rain in urban environment

Kamal Rahmouni, Suzanne Joiret, Luc Robbiola, A. Srhiri, Hisasi Takenouti, Vincent Vivier

An experimental procedure for obtaining reproducible patina on high leaded tin bronze, B66 (Cu-8Sn-14Pb in wt %) has been devised, followed by its isolation from the substrate and examination of the electrochemical behaviour in a solution of 0.2 g.L - 1 Na 2 SO 4 + 0.2 g.L - 1 NaHCO 3 acidified to…

Bulgarian Chemical Communications, 2005, 37 (1), pp.26-34. ⟨hal-04189329⟩

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Smartphone spectrometer for colorimetric biosensing

Yi Wang, Xiaohu Liu, Peng Chen, Nhung Thi Tran, Jinling Zhang, Wei Sheng Chia, Souhir Boujday, Bo Liedberg

We report on a smartphone spectrometer for colorimetric biosensing applications. The spectrometer relies on a sample cell with an integrated grating substrate, and the smartphone's built-in light-emitting diode flash and camera. The feasibility of the smartphone spectrometer is demonstrated…

Analyst, 2016, 141 (11), pp.3233 - 3238. ⟨10.1039/C5AN02508G⟩. ⟨hal-01547878⟩

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Catalytic Pyrolysis of Plastics over Maghemite-Impregnated Mesocellular Foam using Induction Heating

Luing Wong Syie, Sabino Armenise, B. Nyakuma Bemgba, Soon Ng Pang, Hau Lee Chia, Anna Bogush, Franck Launay, Evgeny Rebrov, Marta Munoz

Pyrolysis is a key technology that converts unrecyclable end-of-life plastics into value-added products. Nevertheless, the high energy consumption during plastic pyrolysis limits the economic feasibility of a scaled-up process. Development of an energy-efficient plastic pyrolysis process is…

Chemical Engineering Transactions, 2022, 97, pp.25. ⟨10.3303/CET2297005⟩. ⟨hal-04030193⟩

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Sustainable production of acrolein: effects of reaction variables, modifiers doping and ZrO2 origin on the performance of WO3/ZrO2 catalyst for the gas-phase dehydration of glycerol

Song-Hai Chai, Li-Zhi Tao, Bo Yan, Jacques C. Vedrine, Bo-Qing Xu

Zirconia-supported tungsten oxide (WO3/ZrO2 or WZ) is known as an efficient catalyst for selective acrolein (AC) production from gas-phase dehydration of glycerol (GL). Two catalysts (WZ-CP and WZ-AN) were prepared herein using, respectively, a ZrO(OH)2 hydrogel (ZrO(OH)2-CP) and its derived…

RSC Advances, 2014, 4 (9), pp.4619-4630. ⟨10.1039/C3RA46511J⟩. ⟨hal-01079293⟩

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Dephosphatation under UV light of water by Ti-PILC with activation by secondary species (La, Se, and Rb)

Siham Barama, Anne Davidson, Akila Barama, Hamza Boukhlouf, Sandra Casale, Christophe Calers, Dalil Brouri, Cyril Domingos, Amar Djadoun

Comptes Rendus. Chimie, 2017, 20 (1), pp.7 - 19. ⟨10.1016/j.crci.2016.05.017⟩. ⟨hal-01547166⟩