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A fullerene helical peptide: synthesis, characterization and formation of self-assembled monolayers on gold surfaces

Houssein Nasrallah, Jad Rabah, Van Bui-Thi-Tuyet, Krystyna Baczko, Hélène Fensterbank, Flavien Bourdreux, Anne-Marie Goncalves, Valérie Declerck, Souhir Boujday, Vincent Humblot, Karen Wright, Anne Vallée, Emmanuel Allard

The synthesis of a C60-peptide using "clickable" fullerene and peptide derivatives is described. The peptide is composed of a repeating sequence of -aminoisobutyric acid (Aib) and two L-Alanine (Ala) residues, promoting the formation of a helical conformation, which has been confirmed by…

New Journal of Chemistry, 2018, 42 (24), pp.19423-19432. ⟨10.1039/c8nj04599b⟩. ⟨hal-02348881⟩