• Article dans une revue

Origins of the deactivation process in the conversion of methylbutynol on zinc oxide monitored by operando DRIFTS

C. Drouilly, J.M. Krafft, F. Averseng, H. Lauron-Pernot, Delphine Bazer-Bachi, Céline Chizallet, V. Lecocq, G. Costentin

conversion reaction. The formation of acetone and acetylene is indicative of the basic properties of the zinc oxide surface. This basic catalyst, whose conversion level depends on the nature of the pre-treatment, was found to deactivate versus time on stream. Poisoning the basic sites by CO2 pre-…

Catalysis Today, 2012, 205, pp.67-75. ⟨10.1016/j.cattod.2012.08.011⟩. ⟨hal-00809404⟩

• Article dans une revue

Mesocellular silica foam-based Ni catalysts for dry reforming of CH4 (by CO2)

Oscar Daoura, Marie-Nour Kaydouh, Nissrine El-Hassan, Pascale Massiani, Franck Launay, Maya Boutros

Nickel-containing mesocellular silica foam (MCF) catalysts were prepared for dry reforming of methane (DRM). Different methods were used for the synthesis of the MCFs supports in order to enhance their surface areas and pore volumes. The incorporation of nickel was done by three different methods:…

Journal of CO2 Utilization, 2018, 24, pp.112-119. ⟨10.1016/j.jcou.2017.12.010⟩. ⟨hal-02414803⟩

• HDR

Petit Voyage vers la surface : Structure et réactivité de solides inorganiques, A small trip to the surface: structure and reactivity of inorganic solids

Lorenzo Stievano

Dans ma carrière, j'ai eu la chance et le privilège de m'attaquer à des problématiques scientifiques très variées, qui peuvent être ressemblées par le concept fédérateur de l'application de méthodes d'analyses physico-chimiques pour la compréhension de la structure et de la…

Catalyse. Université Pierre et Marie Curie - Paris VI, 2005. ⟨tel-00092493⟩

• Article dans une revue

L’impact des concepts de Pierre-Gilles de Gennes sur l’innovation en France dans le domaine des matériaux

Charles de Novion, Hervé Toulhoat, Didier Roux, Patrick Maestro, Gustavo Luengo, Fabien Leonforte, Nawel Baghdadli, Pluton Pullumbi, Jean-Michel Vacherand, Yannick Peysson, Benjamin Herzhaft, Étienne Guyon, Françoise Brochard-Wiart, Madeleine Veyssié

Reflets de la Physique, 2018, 56, pp.10-19. ⟨10.1051/refdp/201856010⟩. ⟨hal-04015492⟩

• Article dans une revue

Real-time monitoring of the uniform corrosion rate of aluminum using picosecond acoustic method

Cyrine Lamloum, Oumaïma Gharbi, Laurent Belliard, Vincent Vivier, Kieu Ngo

This paper introduces a novel operando measurement technique to monitor the degradation rate of aluminum (a thin layer of Al deposited on a sapphire substrate), first in a commercial aluminum etching solution, and then in a sodium chloride solution using a pumpprobe spectroscopy technique. By…

Measurement - Journal of the International Measurement Confederation (IMEKO), 2025, 253, pp.117696. ⟨10.1016/j.measurement.2025.117696⟩. ⟨hal-05372918⟩

• Article dans une revue

Controlled Formation of Native Defects in Ultrapure ZnO for the Assignment of Green Emissions to Oxygen Vacancies

Fredeŕic Averseng, Miao Zhang, Frederic Averseng, Jean-Marc Krafft, Patrizia Borghetti, Guylène Costentin, Slavica Stankic

Ultrapure ZnO nanopowders were synthesized via vapor-phase based methods under oxygen deficient conditions. The type and relative proportions of intrinsic point defects were studied by photoluminescence (PL) and EPR spectroscopies performed under strictly controlled conditions. Besides coupled PL/…

Journal of Physical Chemistry C, In press, 124 (23), pp.12696-12704. ⟨10.1021/acs.jpcc.0c01078⟩. ⟨hal-02896623⟩

• Article dans une revue

Surface-induced assembly of sophorolipids

Jessie Peyre, Ahmed Hamraoui, Marco Faustini, Vincent Humblot, Niki Baccile

The surface self-assembly properties of acidic sophorolipids, a bolaform microbial glycolipids with pH-responsive properties in solution, were studied based on the chemical nature of the support and pH of the solution. Sophorolipids generally form micelles in water but formation of morphologies…

Physical Chemistry Chemical Physics, 2017, 19, pp.15227-15238. ⟨10.1039/C7CP01339F⟩. ⟨hal-01534555⟩

• Thèse

Photocatalyseurs nanocomposites UCNP@SiO2@ZnO, activés par rayonnement proche infrarouge, pour la dépollution des eaux usées, Nanocomposites photocatalysts UCNP@SiO2@ZnO, active under near-infrared light, for wastewater treatment

David Hu

Les photocatalyseurs tels que l’oxyde de zinc (ZnO) peuvent minéraliser les polluants organiques toxiques et persistants dans les eaux usées. Ils ne sont cependant pas efficients dans les eaux très contaminées, suite à la nécessité d’une activation par une lumière UV qui n’y pénètre que faiblement…, Photocatalysts such as zinc oxide (ZnO) can mineralize toxic and persistent organic pollutants present in wastewaters. Unfortunately, these photocatalysts loose part of their effectiveness because they need to be activated by UV light, which has a limited penetration depth in highly contaminated…

Matériaux. Sorbonne Université, 2021. Français. ⟨NNT : 2021SORUS017⟩. ⟨tel-04063743⟩

• Article dans une revue

Elucidation of the IR of Cu and Mn substituted intraframework SiBEA zeolites

Etienne Hessou, Michael Badawi, Laetitia Valentin, Guy Atohoun, Stanislaw Dzwigaj, Monica Calatayud, Frederik Tielens

Copper and manganese modified zeolites play key roles in selective oxidation catalytic reactions. Combining Density Functional Perturbation Theory (DFPT) implemented in VASP, and infrared spectroscopy experiments, we have studied and elucidated the incorporation of Cu 2+ and Mn 2+ in the framework…

Topics in Catalysis, 2022, ⟨10.1007/s11244-022-01601-w⟩. ⟨hal-03650572⟩

• Article dans une revue

Cyanobacterial formation of intracellular Ca-carbonates in undersaturated solutions

Nithavong Cam, Karim Benzerara, Thomas Georgelin, Maguy Jaber, Jean-François Lambert, Mélanie Poinsot, Fériel Skouri-Panet, David Moreira, Purificacion Lopez-Garcia, Emmanuelle Raimbault, Laure Cordier, Didier Jezequel

Cyanobacteria have long been thought to induce the formation of Ca-carbonates as secondary by-products of their metabolic activity, by shifting the chemical composition of their extracellular environment to conditions favoring mineral precipitation. Some cyanobacterial species forming Ca-carbonates…

Geobiology, 2018, 16 (1), pp.49-61. ⟨10.1111/gbi.12261⟩. ⟨hal-01655173⟩