Laboratoire de réactivité de surface

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  • Article dans une revue

Optimization of ammonium fluoride route to hierarchical ZSM-5 zeolites

T. Onfroy, Z. Qin, S. Casale, V. Valtchev

Preparation of hierarchical zeolites via a chemical etching is a hot topic as it strongly improves microporous material's diffusive properties and thus their catalytic activity. However, an issue that is often neglected is the softening the post-treatment condition. Herein we we report the…

Microporous and Mesoporous Materials, 2023, 362, pp.112760. ⟨10.1016/j.micromeso.2023.112760⟩. ⟨hal-04229106⟩

  • Article dans une revue

The state of BEA zeolite supported nickel catalysts in CO2 methanation reaction

Wojciech Gac, Witold Zawadzki, Grzegorz Słowik, Marcin Kuśmierz, Stanislaw Dzwigaj

Two model nickel catalysts for CO2 methanation reaction were prepared by the impregnation method using unmodified and dealuminated BEA-type zeolite supports, denoted NiHAlBEA and NiSiBEA. Transmission electron microscopy (TEM) and X-ray diffraction studies evidenced formation of metallic nickel…

Applied Surface Science, 2021, 564, pp.150421. ⟨10.1016/j.apsusc.2021.150421⟩. ⟨hal-03360250⟩

  • Article dans une revue

How the acido-basic properties of Mg silicates and clays govern the catalytic mechanism of transesterification reactions

Longfei Lin, Elisa Silva Gomes, François Payan, Maguy Jaber, Jean-Marc Krafft, Guillaume Laugel, Hélène Lauron-Pernot

Choosing acido-basic properties of magnesium silicates to tune the transesterification mechanism in the liquid phase.

Catalysis Science & Technology, 2019, 9 (21), pp.6072-6084. ⟨10.1039/C9CY01475F⟩. ⟨hal-03990037⟩

  • Article dans une revue

Effects of dealumination on the performance of Ni-containing BEA catalysts in bioethanol steam reforming

Wojciech Gac, Magdalena Greluk, Grzegorz Słowik, Yannick Millot, Laetitia Valentin, Stanislaw Dzwigaj

The effects of dealumination of BEA zeolite on the formation of nickel active sites and the performance of Ni-containing BEA zeolite catalysts in the steam reforming of ethanol have been studied. Ni-containing BEA zeolite catalysts were prepared by the impregnation of unmodified and dealuminated…

Applied Catalysis B: Environmental, 2018, 237, pp.94-109. ⟨10.1016/j.apcatb.2018.05.040⟩. ⟨hal-01909340⟩

  • Article dans une revue

On-line inductively coupled plasma-atomic emission spectroelectrochemistry: Real-time element-resolved electrochemistry

Borhan Bin Mohamad Sultan, Oumaïma Gharbi, Kevin Ogle, Junsoo Han

Electrochemical techniques are coupled with inductively coupled plasma (ICP) atomic emission spectrometry for in-line electrolyte analyses. In this way, direct measurement of the elemental dissolution rates in real-time or element-resolved electrochemistry can be carried out, complementary to…

Current Opinion in Electrochemistry, 2023, 41, pp.101350. ⟨10.1016/j.coelec.2023.101350⟩. ⟨hal-04211090⟩

  • Article dans une revue

Generation of pits on CoCrFeMnNi high entropy alloy: an electrochemical impedance study of a single event

Yaojun Hou, Oumaïma Gharbi, Kevin Ogle, Fan Sun, Mireille Turmine, Vincent Vivier

In this study, a single pit was successfully generated on the surface of a CoCrFeMnNi alloy using a home-made device consisting of an electrochemical work station coupled with a microflow-cell. The three-dimensional morphology of the single pit was observed by optical microscopy, revealing that the…

Electrochimica Acta, 2025, 526, pp.146193. ⟨10.1016/j.electacta.2025.146193⟩. ⟨hal-05041648⟩

  • Article dans une revue

Control of the anisotropic shape of cobalt nanorods in the liquid phase: from experiment to theory… and back

Kahina Aït Atmane, Carine Michel, Jean-Yves Piquemal, Philippe Sautet, Patricia Beaunier, Marion Giraud, Mickaël Sicard, Sophie Nowak, Rémi Losno, G. Viau

The polyol process is one of the few methods allowing the preparation of metal nanoparticles in solution. Hexagonal close packed monocrystalline Co nanorods are easily obtained in basic 1,2-butanediol at 448 K after a few minutes using a Co(II) dicarboxylate precursor. By using a combined…

Nanoscale, 2014, 6 (5), pp.2682-2692. ⟨10.1039/C3NR03686C⟩. ⟨hal-01131455⟩

  • Article dans une revue

Identification of iron species in FeSiBEA by DR UV-vis, XPS and Mössbauer spectroscopy: Influence of Fe content

J. Gurgul, K. Łątka, I. Hnat, J. Rynkowski, S. Dzwigaj

The nature of iron in FeSiBEA zeolite was identified using DR UV-vis, XPS and Mössbauer spectroscopy. Various FexSiBEA zeolites (x = 3.8, 8.2 and 15 wt.%) were prepared by a two-step post synthesis method, which consisted in the creation of vacant T-atom sites by dealumination of tetraethylammonium…

Microporous and Mesoporous Materials, 2013, 168, pp.1-6. ⟨10.1016/j.micromeso.2012.09.015⟩. ⟨hal-00812092⟩

  • Article dans une revue

Au-Ru/TiO2 prepared by deposition-precipitation with urea: Relevant synthesis parameters to obtain bimetallic particles

Lina Calzada, Catherine Louis, Chang Wan Han, Volkan Ortalan, Rodolfo Zanella

Although Au and Ru are not miscible in the bulk, the paper focusses on the attempts to prepare bimetallic Au-Ru/TiO2 catalysts by deposition-precipitation with urea (co-DPU and sequential DPU, Au then Ru and vice versa). Gold was found already reduced after the preparations of co-DPU and Ru then Au…

Applied Catalysis B: Environmental, 2020, 264, pp.118503. ⟨10.1016/j.apcatb.2019.118503⟩. ⟨hal-04025207⟩

  • Article dans une revue

Urea electro-oxidation byproducts impact on NiO/NiOOH anode performance studied by operando electrochemical impedance spectroscopy

Sophia Akkari, Vincent Vivier, Carlos M Sánchez-Sánchez

With significant quantities of urea (CO(NH2)2) being worldwide produced and its presence at high concentration in urine, simultaneous treatment of urea effluents and hydrogen production by paired electrolysis represents a very attractive approach in circular economy. Urea electro-oxidation on Ni-…

Electrochimica Acta, 2024, 474, pp.143526. ⟨10.1016/j.electacta.2023.143526⟩. ⟨hal-04298004⟩