• Article dans une revue

Scanning Electrochemical Microscopy for Investigating Gas Bubble/Liquid Interfaces

Claude Gabrielli, François Huet, Michel Keddam, Philippe Rousseau, Vincent Vivier

Scanning electrochemical microscopy was used to characterize air bubble/electrolyte interfaces for bubbles of diameter in the millimeter range. Contrary to rigid insulated substrate/liquid interfaces, the approach of the tip of the microelectrode was shown to lead to a deformation of the bubble…

Electrochemical and Solid-State Letters, 2003, 6 (10), pp.E23. ⟨10.1149/1.1604971⟩. ⟨hal-04219330⟩

• Article dans une revue

Corrosion propagation monitoring using electrochemical noise measurements on carbon steel in hydrogenocarbonated solution containing chloride ions

Chloé Comas, François Huet, Kieu Ngo, Marion Fregonese, Hassane Idrissi, Bernard Normand

The propagation of localized corrosion on API 5 L X65 carbon steel in hydrogenocarbonated solution containing chloride ions was monitored during long immersion times by electrochemical noise (EN) measurements in ZRA mode. Monitoring corrosion propagation from the EN amplitude is possible but…

Corrosion Science, 2021, 193, pp.109885. ⟨10.1016/j.corsci.2021.109885⟩. ⟨hal-03387864⟩

• Article dans une revue

Critical assessment of solvent effects on absorption and fluorescence of 3HF in acetonitrile in the QM/PCM framework: A synergic computational and experimental study

Daniele Loco, Stefano Protti, Benedetta Mennucci, Alberto Mezzetti

Absorption and fluorescence properties of 3-hydroxyflavone (3HF) dissolved in the polar aprotic solvent acetonitrile have been investigated by electronic spectroscopies, associated to mixed quantum mechanical (QM)/classical calculations, where the effect of the solvent is included at the classical…

Journal of Molecular Structure, 2019, 1182, pp.283-291. ⟨10.1016/j.molstruc.2018.12.085⟩. ⟨hal-02178337⟩

• Article dans une revue

Mesoporous nickel-alumina catalysts derived from MIL-53(Al) metal-organic framework: A new promising path for synthesizing CO2 methanation catalysts

Leila Karam, Maria C Bacariza, José M Lopes, Carlos Henriques, Julien Reboul, Nissrine El Hassan, Pascale Massiani

A new synthesis route for the preparation of highly efficient and stable porous Ni-based alumina catalysts for CO2 methanation is presented. It is based on the use of MIL-53(Al), an Al-containing metal-organic framework (MOF) with high surface area, as sacrificial support. A series of Ni-Al2O3…

Journal of CO2 Utilization, 2021, 51, pp.101651. ⟨10.1016/j.jcou.2021.101651⟩. ⟨hal-03455763⟩

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The state of BEA zeolite supported nickel catalysts in CO2 methanation reaction

Wojciech Gac, Witold Zawadzki, Grzegorz Słowik, Marcin Kuśmierz, Stanislaw Dzwigaj

Two model nickel catalysts for CO2 methanation reaction were prepared by the impregnation method using unmodified and dealuminated BEA-type zeolite supports, denoted NiHAlBEA and NiSiBEA. Transmission electron microscopy (TEM) and X-ray diffraction studies evidenced formation of metallic nickel…

Applied Surface Science, 2021, 564, pp.150421. ⟨10.1016/j.apsusc.2021.150421⟩. ⟨hal-03360250⟩

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Ultrafast time-resolved quantum cascade laser diagnostic for enlightening the role of surface formate species in the photocatalytic oxidation of methanol

Josefine Schnee, Marco Daturi, Mohamad El-Roz

In the present work, a new quantum cascade laser (QCL)-assisted operando FT-IR setup was used to get direct insight into the relationship between the overall catalytic performance of TiO2 photocatalysts in the gas phase photooxidation of methanol at 25 °C, and the kinetics of intermediate surface…

Catalysis Science & Technology, 2020, 10 (16), pp.5618-5627. ⟨10.1039/D0CY00865F⟩. ⟨hal-03013711⟩

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A new look on the corrosion mechanism of magnesium: An EIS investigation at different pH

Abdelmoheiman Zakaria Benbouzid, Maurilio Pereira Gomes, Isolda Costa, Oumaïma Gharbi, Nadine Pébère, Jesualdo Luiz Rossi, Mai T.T. Tran, Bernard Tribollet, Mireille Turmine, Vincent Vivier

This study investigates the electrochemical impedance diagrams obtained for a Mg electrode in a sodium sulphate solution at different pHs. A comprehensive model, independent of the pH range, with the presence of two adsorbed intermediates accounting for the anodic dissolution and the cathodic…

Corrosion Science, 2022, 205, pp.110463. ⟨10.1016/j.corsci.2022.110463⟩. ⟨hal-03719396⟩

• Article dans une revue

Experimental observation of ohmic impedance

Chen You, Arthur Dizon, Ming Gao, Vincent Vivier, Mark Orazem

Electrochimica Acta, 2022, 413, pp.140177. ⟨10.1016/j.electacta.2022.140177⟩. ⟨hal-03868701⟩

• Article dans une revue

Aqueous nickel(II) hydroxycarbonate instead of nickel(0) colloids as precursors of stable Ni-silica based catalysts for the dry reforming of methane

Oscar Daoura, Ghenwa El Chawich, Maya Boutros, Nissrine El Hassan, Pascale Massiani, Ovidiu Ersen, Walid Baaziz, Franck Launay

Nickel(II) hydroxycarbonate colloids were synthesized in water by the reaction of nickel(II) with carbonate in the presence of hexadecyltrimethylammonium bromide. Then, they were dispersed onto SBA-15 affording, after calcination and reduction, a supported 3 wt% nickel(0) catalyst for the dry…

Catalysis Communications, 2020, 138, pp.105953. ⟨10.1016/j.catcom.2020.105953⟩. ⟨hal-02991878⟩

• Thèse

Comprehension of cellulose depolymerisation mechanisms induced by iron ions, Compréhension des mécanismes de dépolymérisation de la cellulose induits par les ions fer

Alice Gimat

Degradation of paper by iron gall inks (IGI) is a challenging issue for written heritage conservation. These inks consist of a mixture of iron(II) sulphate, tannins and gum Arabic, and are therefore acidic and iron-rich. Hence, paper degradation by IGI is often attributed to a combination of acid…, La dégradation du papier par les encres ferrogalliques (EFG) est un défi pour la conservation du patrimoine écrit. Ces encres, composées d'un mélange de sulfate de fer (II), de tannins et de gomme Arabique, sont acides et riches en fer. Par conséquent, les mécanismes de dégradation des…

Material chemistry. Université Pierre et Marie Curie - Paris VI, 2016. English. ⟨NNT : 2016PA066579⟩. ⟨tel-01654429⟩