Laboratoire de réactivité de surface

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  • Article dans une revue

Ethanol Conversion into 1,3-Butadiene by Lebedev Method over MTaSiBEA Zeolites (M= Ag, Cu, Zn)

Pavlo I. Kyriienko, Olga V. Larina, Sergiy O. Soloviev, Svitlana M. Orlyk, Christophe Calers, Stanislaw Dzwigaj

Tantalum-containing SiBEA zeolite with isolated framework mononuclear Ta(V) doped with Ag, Cu and Zn were prepared and characterized by XRD, XPS, DR UV-VIS and FTIR (with pyridine, 2,6-di-tert-butylpyridine, pyrrole and deuterated chloroform). The conversion of ethanol as renewable raw material…

ACS Sustainable Chemistry & Engineering, 2017, ⟨10.1021/acssuschemeng.6b01728⟩. ⟨hal-01437547⟩

  • Article dans une revue

Experimental clues for detecting biosignatures on Mars

J.-C. Viennet, S. Bernard, Corentin Le Guillou, P. Jacquemot, E. Balan, L. Delbes, B. Rigaud, T. Georgelin, M. Jaber

Forthcoming exploration of Mars aims at identifying fossil biosignatures within ancient clay-rich formations. The subsurface of Mars has mostly acted as a giant freezer for the last 4 Gyr, thereby preserving potential remains of martian life. Yet, volcanism and impactors have periodically triggered…

Geochemical Perspectives Letters, 2019, Geochemical Perspectives Letters, 12, pp.28-33. ⟨10.7185/geochemlet.1931⟩. ⟨hal-02415460⟩

  • Article dans une revue

Identification of iron species in FeSiBEA by DR UV-vis, XPS and Mössbauer spectroscopy: Influence of Fe content

J. Gurgul, K. Łątka, I. Hnat, J. Rynkowski, S. Dzwigaj

The nature of iron in FeSiBEA zeolite was identified using DR UV-vis, XPS and Mössbauer spectroscopy. Various FexSiBEA zeolites (x = 3.8, 8.2 and 15 wt.%) were prepared by a two-step post synthesis method, which consisted in the creation of vacant T-atom sites by dealumination of tetraethylammonium…

Microporous and Mesoporous Materials, 2013, 168, pp.1-6. ⟨10.1016/j.micromeso.2012.09.015⟩. ⟨hal-00812092⟩

  • Article dans une revue

The remarkable effect of the preparation procedure on the catalytic activity of CoBEA zeolites in the Fischer-Tropsch Synthesis

Karolina A. Chalupka, Sandra Casale, Ewa Zurawicz, Jacek Rynkowski, Stanislaw Dzwigaj

This work deals with the investigation of the influence of the preparation procedure and Co content on the activity of CoBEA zeolite in Fischer – Tropsch synthesis. For this purpose the Co-containing zeolites were prepared by a conventional wet impregnation (CoxAlBEA series) and a two-step…

Microporous and Mesoporous Materials, 2015, 211, pp.9-18. ⟨10.1016/j.micromeso.2015.02.024⟩. ⟨hal-01130202⟩

  • Article dans une revue

Tuning the shape and size of hybrid gold nanoparticles by porphyrins using seed-mediated synthesis

Jolanda Spadavecchia, Sandra Casale, Jessem Landoulsi, Claire-Marie Pradier

We report the synthesis of hybrid gold nanostructures by means of seed/growth approach, using porphyrin molecules (protoporphyrin IX) in addition to cetyltetraammonium bromide (CTAB) as surfactants and/or shape-modulating agents. The combination of CTAB and porphyrin yields stable complexes that…

Chemical Physics Letters, 2014, 609, pp.134-141. ⟨10.1016/j.cplett.2014.06.008⟩. ⟨hal-01078002⟩

  • Article dans une revue

Catalytic activity of HAlBEA and NixHAlBEA zeolites in hydrogen-assisted dehydrochlorination of 1,2-dichloroethane into vinyl chloride monomer

Rafal Baran, Anna Srebowata, I.I. Kaminska, D. Łomot, Stanislaw Dzwigaj

HAlBEA zeolite is prepared by calcination of parent TEABEA zeolite at 823 K for 3 h in air following ionic exchange with NH4NO3 solution. NixHAlBEA zeolites are prepared by impregnation of HAlBEA with an aqueous solution of Ni(NO3)2, following a drying at 333 K to obtain NixHAlBEA. The calcination…

Microporous and Mesoporous Materials, 2013, 180, pp.209-218. ⟨10.1016/j.micromeso.2013.06.037⟩. ⟨hal-00910991⟩

  • Article dans une revue

Corrosion propagation monitoring using electrochemical noise measurements on carbon steel in hydrogenocarbonated solution containing chloride ions

Chloé Comas, François Huet, Kieu Ngo, Marion Fregonese, Hassane Idrissi, Bernard Normand

The propagation of localized corrosion on API 5 L X65 carbon steel in hydrogenocarbonated solution containing chloride ions was monitored during long immersion times by electrochemical noise (EN) measurements in ZRA mode. Monitoring corrosion propagation from the EN amplitude is possible but…

Corrosion Science, 2021, 193, pp.109885. ⟨10.1016/j.corsci.2021.109885⟩. ⟨hal-03387864⟩

  • Article dans une revue

The Synthesis of Different Series of Cobalt BEA Zeolite Catalysts by Post-Synthesis Methods and Their Characterization

Renata Sadek, Karolina Chalupka-Spiewak, Jean-Marc Krafft, Yannick Millot, Laetitia Valentin, Sandra Casale, Jacek Gurgul, Stanislaw Dzwigaj

Three series of zeolite catalysts Co all-silica and Co Al-containing zeolites beta were prepared for use in the selective oxidative dehydrogenation of propane to propylene. Two series of zeolite catalysts Co all-silica were prepared by a two-step postsynthesis method at pH = 2.5 and pH = 3.0-9.0,…

Catalysts, 2022, 12 (12), pp.1644. ⟨10.3390/catal12121644⟩. ⟨hal-04030832⟩

  • Article dans une revue

Methane dry reforming over hydrotalcite-derived Ni–Mg–Al mixed oxides: the influence of Ni content on catalytic activity, selectivity and stability

Radosław Dębek, Monika Motak, Dorota Duraczyska, Franck Launay, Maria Elena Galvez, Teresa Grzybek, Patrick da Costa

Ni-containing hydrotalcite-derived catalysts were prepared using different Ni loadings (from ca. 4 to 60 wt%) at the same MII/MIII ratio equal to 3. The influence of the Ni content on the physico-chemical features of these catalysts was studied, as well as the influence of this parameter on their…

Catalysis Science & Technology, 2016, 6 (17), pp.6705 - 6715. ⟨10.1039/C6CY00906A⟩. ⟨hal-01547978⟩

  • Article dans une revue

Real-time colorimetric hydration sensor for sport activities

Yubin Zhou, Htet Han, Hnin Pwint Phyuson Naw, Alice Venecia Lammy, Chee Hong Goh, Souhir Boujday, Terry W.J. Steele

Dehydration and over-hydration are a serious health concern in endurance sport activities, especially in tropical climates. Current methods for detection are inconvenient and not widely applied. Point-of-care hydration monitoring during a sport event is an ideal preventative therapy, as it allows…

Materials & Design, 2016, 90, pp.1181 - 1185. ⟨10.1016/j.matdes.2015.06.078⟩. ⟨hal-01548066⟩