Laboratoire de réactivité de surface

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  • Article dans une revue

Static and dynamic electronic characterization of organic monolayers grafted on a silicon surface

Olivier Pluchery, Y. Zhang, R. Benbalagh, L. Caillard, J. J. Gallet, F. Bournel, A.-F. Lamic-Humblot, M. Salmeron, Y. J. Chabal, F. Rochet

Organic layers chemically grafted on silicon offer excellent interfaces that may open up the way for new organic–inorganic hybrid nanoelectronic devices. However, technological achievements rely on the precise electronic characterization of such organic layers. We have prepared ordered grafted…

Physical Chemistry Chemical Physics, 2016, 18 (5), pp.3675-3684. ⟨10.1039/C5CP05943G⟩. ⟨hal-01262800⟩

  • Article dans une revue

Critical assessment of solvent effects on absorption and fluorescence of 3HF in acetonitrile in the QM/PCM framework: A synergic computational and experimental study

Daniele Loco, Stefano Protti, Benedetta Mennucci, Alberto Mezzetti

Absorption and fluorescence properties of 3-hydroxyflavone (3HF) dissolved in the polar aprotic solvent acetonitrile have been investigated by electronic spectroscopies, associated to mixed quantum mechanical (QM)/classical calculations, where the effect of the solvent is included at the classical…

Journal of Molecular Structure, 2019, 1182, pp.283-291. ⟨10.1016/j.molstruc.2018.12.085⟩. ⟨hal-02178337⟩

  • Article dans une revue

Effect of Fe on the activity of Au/FeO x -TiO2 catalysts for CO oxidation

Mpfunzeni Raphulu, Thabang Ntho, Pumeza Gqogqa, John Moma, Lebohang Mokoena, Gary Pattrick, Mike Scurrell, Laurent Delannoy, Catherine Louis

A thorough characterisation of Au/TiO2 and Au/ FeOx-TiO2 catalysts was conducted in order to get a better understanding of the effect of Fe on the Au/TiO2 catalysts and link it to differences observed in their activities for CO oxidation. Several techniques including HRTEM, temperature-programmed…

Gold Bulletin : The journal of gold science, technology and applications , 2016, 49 (1-2), pp.9-20. ⟨10.1007/s13404-016-0178-4⟩. ⟨hal-01548378⟩

  • Thèse

Création de surfaces antibiofilms par greffage covalent de peptides et enzymes antibactériens sur les surfaces de cuivre et de titane, Creation of antibiofilm surfaces : covalent grafting of antimicrobial peptides and enzymes onto copper and titanium surfaces

Jessie Peyre

La contamination bactérienne et le développement de biofilms marins sont des problèmes récurrents, et terriblement coûteux sur les structures immergées des bâtiments de l'armée. L'emploi de composés bactéricides et nocifs pour l'écosystème est désormais interdit. Les travaux menés…, Bacterial contamination and formation of biofilms on immersed structures in seawater are frequent and at the origin of high cost maintenance treatments. The use of compounds biocidal, but also harmful for the ecosystem, is nowadays forbidden. The aim of this thesis work was to find new preventive…

Matériaux. Université Pierre et Marie Curie - Paris VI, 2012. Français. ⟨NNT : 2012PAO66535⟩. ⟨tel-00833434⟩

  • Article dans une revue

Ionic liquids/metal reactivity: on the origins of cation–anion synergy to form stable grafted molecules

Christophe Méthivier, Mireille Turmine, Vincent Vivier, Oumaïma Gharbi

<div><p>In this work, the reactivity between a Cu single crystal (110) and an alkylammonium ionic liquidthe ethylammonium nitrate (EAN) -was investigated by in situ X-ray photoelectron spectroscopy (XPS) and polarization modulation infrared reflectance absorbance spectroscopy (PM-IRRAS…

Applied Surface Science, 2026, ⟨10.1016/j.apsusc.2026.166518⟩. ⟨hal-05545902⟩

  • Article dans une revue

Structure, Orientation and Stability of Lysozyme Confined in layered Materials

Sébastien Balme, Régis Guégan, Jean-Marc Janot, Maguy Jaber, Mathilde Lepoitevin, Philippe Dejardin, Xavier Bourrat, Mikael Motelica-Heino

The confinement of lysozyme in 3 layered materials based on montmorillonite and lamellar double hydroxide exhibiting different surface charges was studied. The protein structure and orientation in these materials were determined by X-Ray diffraction, time resolved fluorescence and fluorescence…

The Royal Society of Chemistry, 2013, 9 (11), pp.3188-3196. ⟨10.1039/C3SM27880H⟩. ⟨insu-00779421v2⟩

  • Article dans une revue

A selective and stable Fe/TiO 2 catalyst for selective hydrogenation of butadiene in alkene-rich stream

Zhao Wang, Laura Santander de Soto, Christophe Méthivier, Sandra Casale, Catherine Louis, Laurent Delannoy

The Fe/TiO 2 catalyst shows high selectivity to alkenes at high butadiene conversion and good stability at 175 °C.

Chemical Communications, 2021, 57 (57), pp.7031-7034. ⟨10.1039/d1cc02366g⟩. ⟨hal-03987090⟩

  • Article dans une revue

Elaboration of antibiofilm surfaces functionalized with antifungal-cyclodextrin inclusion complexes.

Aïcha Gharbi, Vincent Humblot, Turpin Frédéric, Claire-Marie Pradier, Christine Imbert, Jean-Marc Berjeaud

To tackle the loss of activity of surfaces functionalized by coating and covalently bound molecules to materials, an intermediate system implying the noncovalent immobilization of active molecules in the inner cavity of grafted cyclodextrins (CDs) was investigated. The antifungal and antibiofilm…

FEMS Immunology and Medical Microbiology, 2012, pp.257-269. ⟨10.1111/j.1574-695X.2012.00932.x⟩. ⟨hal-00707695⟩

  • Article dans une revue

Application of Arrhenius law to DP and zero-span tensile strength measurements taken on iron gall ink impregnated papers: relevance of artificial ageing protocols

Véronique Rouchon, Oulfa Belhadj, Maroussia Duranton, Alice Gimat, Pascale Massiani

Iron gall inks (IGI) were largely used for writing until the nineteenth century. Under certain circumstances, they provoke a substantial degradation of their cellulosic support.It was shown in a previous works thatc ombination of oxygen and iron largely impacts cellulose chain breaking occurring in…

Applied physics. A, Materials science & processing, 2016, 122 (8), pp.773. ⟨10.1007/s00339-016-0307-1⟩. ⟨hal-01435154⟩

  • Communication dans un congrès

Unveiling the M−F/OH bonding and anionic ordering in Mg, Zn, Cu−based hydroxyfluorides for the design of basic catalysts

Helies Boumali, Matthew R. Suchomel, Étienne Durand, Thomas Onfroy, Guillaume Laugel, Hélène Pernot

Functional inorganic materials, mostly oxides but also fluorides, sulfides, or nitrides has led to the development of many modern technologies. The usual way to improve the chemical and physical properties of these materials was the cationic substitution in order to tune the chemical bonding. These…

15ème Journées Thématiques de l'Association Bordelaise de Cristallographie - JABC 2023, Association Bordelaise de Cristallographie, Jun 2023, Bordeaux, France. ⟨hal-04628119⟩