Laboratoire de réactivité de surface

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  • Article dans une revue

Hollow Gold Nanoshells for Sensitive 2D Plasmonic Sensors

Daoming Sun, Ferdaous Ben Romdhane, Axel Wilson, Michèle Salmain, Souhir Boujday

The interaction of incident light with noble metal nanoparticles engenders a fascinating phenomenon known as localized surface plasmon resonance (LSPR). This results in the presence of single or multiple intense absorption bands in the visible to near-infrared spectral range whose position is…

ACS Applied Nano Materials, 2024, 7 (5), pp.5093-5102. ⟨10.1021/acsanm.3c05872⟩. ⟨hal-04477602⟩

  • Article dans une revue

Surface‐Dependent Activation of Model α‐Al2O3‐Supported P‐Doped Hydrotreating Catalysts Prepared by Spin Coating

Ricardo Garcia de Castro, Jérémy Bertrand, Baptiste Rigaud, Elodie Devers, Mathieu Digne, Anne‐félicie Lamic-Humblot, Gerhard Pirngruber, Xavier Carrier

Requirements for improved catalytic formulations is continuously driving research in hydrotreating (HDT) catalysis for biomass upgrading and heteroatom removal for cleaner fuels. The present work proposes a surface-science approach for the understanding of the genesis of the active (sulfide) phase…

Chemistry - A European Journal, 2020, 26 (64), pp.14623-14638. ⟨10.1002/chem.202001882⟩. ⟨hal-04025167⟩

  • Article dans une revue

Aqueous-Phase Preparation of Model HDS Catalysts on Planar Alumina Substrates: Support Effect on Mo Adsorption and Sulfidation

Cédric Bara, Lucie Plais, Kim Larmier, Elodie Devers, Mathieu Digne, Anne-Félicie Lamic-Humblot, Gerhard D. Pirngruber, Xavier Carrier

The role of the oxide support on the structure of the MoS2 active phase (size, morphology, orientation, sulfidation ratio, etc.) remains an open question in hydrotreating catalysis and biomass processing with important industrial implications for the design of improved catalytic formulations. The…

Journal of the American Chemical Society, 2015, 137 (50), pp.15915-15928. ⟨10.1021/jacs.5b10975⟩. ⟨hal-01263787⟩

  • Article dans une revue

Transformations of γ-alumina in aqueous suspensions. 1. Alumina chemical weathering studied as a function of pH

Xavier Carrier, Eric Marceau, Jean-François Lambert, Michel Che

Hydration of γ-Al2O3 is often reported to occur via the superficial transformation of the alumina surface into alumina hydroxide-like layers. However, very little evidence has been given so far to support this hypothesis. It is demonstrated here by X-ray diffraction, TEM, electron diffraction and…

Journal of Colloid and Interface Science, 2007, 308, pp.429-437. ⟨10.1016/j.jcis.2006.12.074⟩. ⟨hal-00133775⟩

  • Article dans une revue

A new glance at ruthenium sorption mechanism on hydroxy, carbonate, and fluor apatites: Analytical and structural studies

K. Tõnsuaadu, M. Gruselle, F. Villain, R. Thouvenot, M. Peld, V. Mikli, R. Traksmaa, Patrick Gredin, Xavier Carrier, L. Salles

The sorption mechanism of Ru3+ ions on hydroxy (HAp), carbonate (CO3HAp), and fluor apatites (FAp) has been studied in detail. Ru apatites were obtained by reaction of the apatites with RuCl3 in aqueous solution. The structure and composition of the ruthenium-modified apatites were studied by…

Journal of Colloid and Interface Science, 2006, 304, pp.283-291. ⟨hal-00160825⟩

  • Article dans une revue

Carbonates thermal decomposition kinetics and their implications in using Rock-Eval ® analysis for carbonates identification and quantification

François Baudin, Nicolas Bouton, Adrien Wattripont, Xavier Carrier

In 2014, Pillot et al. [Identification and quantification of carbonate species using Rock-Eval pyrolysis, Oil Gas Sci. Technol. – Rev. IFP 69, 341–349. https://doi.org/10.2516/ogst/2012036] proposed to use the Rock- Eval® method as a reliable tool to identify and quantify carbonates in solid…

Science and Technology for Energy Transition, 2023, ⟨10.2516/ogst/2012036]⟩. ⟨hal-04390156⟩

  • Article dans une revue

Characterization of mesoporous alumina prepared by surface alumination of SBA-15

Manuel Baca, Emmanuel de La Rochefoucauld, Emmanuelle Ambroise, Jean-Marc Krafft, Redouane Hajjar, Pascal P. Man, Xavier Carrier, Juliette Blanchard

Mesoporous aluminas of controlled pore sizes were synthesized by multiple grafting of Al isopropoxide in organic solvents on mesoporous silica SBA-15. These materials were characterized by N2 physisorption, TEM, XRD, 27Al NMR and their surface chemical properties were probed by DRIFT, cumene…

Microporous and Mesoporous Materials, 2008, 110, pp.232-241. ⟨hal-00260914⟩

  • Article dans une revue

Insight into the structure and localization of the titania overlayer in TiO2-coated SBA-15 materials

Fu-Xiang Zhang, Xavier Carrier, Jean-Marc Krafft, Yu-Ji Yoshimura, Juliette Blanchard

Titania-coated SBA-15 materials (Ti-SBA-n with n = 1-4) were synthesized by successive grafting of titanium isopropoxide in iso-propanol. The investigation of the nature and localization of the TiO2 overlayer allowed us to conclude that there was formation of very small (UV-visible, EXAFS, XANES),…

New Journal of Chemistry, 2010, 34 (3), pp.508-516. ⟨10.1039/B9NJ00439D⟩. ⟨hal-00604815⟩

  • Article dans une revue

Production of Laccase by Recombinant Yarrowia lipolytica from Molasses: Bioprocess Development Using Statistical Modeling and Increase Productivity in Shake-Flask and Bioreactor Cultures

Farshad Darvishi, Marzieh Moradi, Catherine Madzak, Claude Jolivalt

Laccases are used in numerous applications, from green degradation of various xenobiotic compounds, waste detoxification, textile dye bleaching, and delignification of lignocellulose materials to biofuel production. In this study, the recombinant Yarrowia lipolytica YL4 strain carrying the white-…

Applied Biochemistry and Biotechnology, 2017, 181 (3), ⟨10.1007/s12010-016-2280-8⟩. ⟨hal-01531721⟩

  • Article dans une revue

Comparison of molybdenum carbide and tungsten carbide for the hydrodesulfurization of dibenzothiophene

Agnieszka Szymanska-Kolasa, Marek Lewandowski, Celine Sayag, G. Djéga-Mariadassou

The molybdenum and tungsten carbides (Mo2C and W2C) were synthesized, characterized and tested in hydrodesulfurization (HDS) of dibenzothiophene (DBT). The phase purity of these catalysts was established by X-ray diffraction (XRD), and the surface properties were determined by N2 BET specific…

Catalysis Today, 2006, 119, pp.7-12. ⟨10.1016/j.cattod.2006.08.021⟩. ⟨hal-00128084⟩