• Article dans une revue

Permanently hydrophilic, piezoelectric PVDF nanofibrous scaffolds promoting unaided electromechanical stimulation on osteoblasts

Maria Kitsara, Andreu Blanquer, Gonzalo Murillo, Vincent Humblot, Sara de Bragança Vieira, Carme Nogués, Elena Ibáñez, Jaume Esteve, Leonardo Barrios

Biomimetic functional scaffolds for tissue engineering should fulfil specific requirements concerning structural, biochemical and electro-mechanical characteristics, depending on the tissue that they are designed to resemble. In bone tissue engineering, piezoelectric materials based on poly(…

Nanoscale, 2019, 11 (18), pp.8906-8917. ⟨10.1039/C8NR10384D⟩. ⟨hal-02351810⟩

• Article dans une revue

Non-Hydroxyl Radical Species Production during Dark Air Oxidation of Alluvial Soils

Elora Bourbon, Frédéric Averseng, Pierre Le Pape, Thierry Allard, Fulvia Baratelli, Fabrice Alliot, Alexandre Gélabert, Valentine Rollot, Elodie Guigon, Jessica Brest, Sylvie Nélieu, Guillaume Morin

Natural environments subjected to hydrologically-driven redox fluctuations are regarded as propitious to contaminant degradation since they favor cyclic oxygenation of Fe(II)-minerals that produces oxidizing reactive species, such as the hydroxyl radical, OH • . However, the identity of these…

ACS Earth and Space Chemistry, 2024, 8 (9), pp.1757-1770. ⟨10.1021/acsearthspacechem.4c00113⟩. ⟨hal-04744483⟩

• Article dans une revue

Efficient transformation of cyclohexanone to ε-caprolactone in the oxygen-aldehyde system over single-site titanium BEA zeolite

Katarzyna Pamin, Jacek Gurgul, Grzegorz Mordarski, Yannick Millot, Jean-Philippe Nogier, Laetitia Valentin, Stanislaw Dzwigaj

TixSiBEA zeolites prepared by a two-step post-synthesis method are applied in the liquid-phase Baeyer-Villiger oxidation of cyclohexanone to ε-caprolactone in the oxygen-aldehyde system. Such method of ε-caprolactone synthesis offers the application of milder reaction conditions with the catalytic…

Microporous and Mesoporous Materials, 2021, 322, pp.111159. ⟨10.1016/j.micromeso.2021.111159⟩. ⟨hal-03993571⟩

• Article dans une revue

Heterogeneous catalytic partial oxidation of lower alkanes (C 1 –C 6 ) on mixed metal oxides

Jacques Védrine

This review paper aims at analysing the state of the art for partial oxidation and oxidative dehydrogenation (ODH) reactions of lower alkanes C1–C6 into olefins and oxygenated products (aldehydes, anhydrides, carboxylic acids) on metal oxide catalysts with cations of variable oxidation state, such…

Journal of Energy Chemistry, 2016, 25 (6), pp.936-946. ⟨10.1016/j.jechem.2016.10.007⟩. ⟨hal-02188605⟩

• Article dans une revue

Optimization of Synthesis Conditions of Ni/SBA-15 Catalysts: Confined Nanoparticles and Improved Stability in Dry Reforming of Methane

Nissrine El Hassan, Marie-Nour Kaydouh, Nissrine El, Anne Davidson, Pascale Massiani

Despite its economic and environmental advantages, the dry reforming of methane using supported Ni-based catalysts remains challenging due to problems of metal particle sintering and carbon deposition, which lead to loss in catalytic activity. In this study, different silica supports, containing 5…

Catalysts, 2020, 11 (1), pp.44. ⟨10.3390/catal11010044⟩. ⟨hal-03146326⟩

• Poster de conférence

Influence des voies de préparation des oxydes mixtes NiMgAl sur leurs activités catalytiques en méthanation du CO2

Michel Obeid, Christophe Poupin, Samer Aouad, François Delattre, Madona Labaki, Josefine Schnee, Eric Gaigneaux, Edmond Abi-Aad

GECat 2024, May 2024, Hendaye, France. ⟨hal-04585096⟩

• Article dans une revue

Surface functionalization by covalent immobilization of an innovative carvacrol derivative to avoid fungal biofilm formation

Aïcha Gharbi, Thibaut Legigan, Vincent Humblot, Sébastien Papot, Jean-Marc Berjeaud

Carvacrol, an aromatic terpenic compound, known to be antimicrobial was grafted onto gold surfaces via two strategies based on newly-synthesized cross-linkers involving either an ester bond which can be cleaved by microbial esterases, or a covalent ether link. Surface functionalizations were…

AMB Express, 2015, 5 (1), pp.9. ⟨10.1186/s13568-014-0091-2⟩. ⟨hal-01143973⟩

• Article dans une revue

Ni/CeO2 Nanoparticles Promoted by Yttrium Doping as Catalysts for CO2 Methanation

Valeria La Parola, Chao Sun, Patricia Beaunier, Leonarda F Liotta, Patrick da Costa

Ni (5 wt.%) catalysts over yttrium modified CeO2 oxides synthesized by hydrothermal method were prepared. For comparison Ni was supported over pure CeO2 and Y2O3. Characterizations by N2 adsorption/desorption, XRD, XPS, TEM/HRTEM, H2-TPR, CO2-TPD and TGA were carried out. The catalytic performance…

ACS Applied Nano Materials, 2020, 3 (12), pp.12355-12368. ⟨10.1021/acsanm.0c02841⟩. ⟨hal-03146777⟩

• Communication dans un congrès

Soil organo-mineral associations fine structure : nanoscale MET-EELS imaging of Fe Si Al-organic matter coprecipitates

Nithavong Cam, Clement Levard, Emmanuel Doelsch, Jérôme Rose, Bertrand Devouard, Isabelle Basile-Doelsch

EGU General Assembly 2019, Apr 2019, Vienne, Austria. ⟨hal-03548680⟩

• Article dans une revue

Drastic Au(111) Surface Reconstruction upon Insulin Growth Factor Tripeptide Adsorption

Vincent Humblot, Anne Vallee, Ahmed Naitabdi, Frederik Tielens, Claire-Marie Pradier

Adsorption of biomolecules at metal surfaces often creates two-dimensional ordering of the adlayers. However, metal substrate reconstruction is less commonly observed, unless upon annealing of the molecule−surface system. Here, we report on the drastic room-temperature reconstruction of the Au(111…

Journal of the American Chemical Society, 2012, 134, pp.6579−6583. ⟨10.1021/ja302530q⟩. ⟨hal-00748253⟩