• Article dans une revue

Evidence for an H2 promoting effect in the selective catalytic reduction of NO(x) by propene on Au/Al2O3.

Tesnim Chaieb, Laurent Delannoy, Sandra Casale, Catherine Louis, Cyril Thomas

This work provides the first experimental evidence of an H2 effect in C3H6-SCR over an Au/Al2O3 catalyst. This effect could only be observed when the number of Au catalytic sites was decreased. The N2 turnover rate estimated for the first time for the Au catalytic sites for H2–C3H6-SCR was found to…

Bulgarian Chemical Communications, 2015, 51 (4), pp.796-9. ⟨10.1039/c4cc07349e⟩. ⟨hal-01121184⟩

• Article dans une revue

Selectivities in Adsorption and Peptidic Condensation in the (Arginine and Glutamic Acid)/Montmorillonite Clay System

Maguy Jaber, Thomas Georgelin, Houssein Bazzi, France Costa-Torro, Jean-François Lambert, Gérard Bolbach, Gilles Clodic

The present study examines the selective adsorption and polymerization of two amino acids, glutamic acid (Glu) and arginine (Arg), on a cationic clay mineral, montmorillonite (Mt). Two experimental procedures were used: selective adsorption and wet impregnation. In the first case, an adsorption…

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 2014, 118 (44), pp.25447-25455. ⟨10.1021/jp507335e⟩. ⟨hal-01121644⟩

• Article dans une revue

Solvent effects on the vibrational spectrum of 3-hydroxyflavone

Ari Paavo Seitsonen, Abdenacer Idrissi, Stefano Protti, Alberto Mezzetti

3-hydroxyflavone (3HF) is a widely studied molecule that acts as a simplified prototype of biological, more complex flavonoids. Its solvation mechanism is still under investigation. Here we report a joint experimental and simulation study of the vibrational properties of 3HF in gas phase and in…

Journal of Molecular Liquids, 2019, 275, pp.723-728. ⟨10.1016/j.molliq.2018.11.020⟩. ⟨hal-02404703⟩

• Article dans une revue

Plasmonic Properties of Gold Nanostructures on Gold Film

Médéric Lequeux, David Mele, Priyamvada Venugopalan, Raymond Gillibert, Souhir Boujday, Wolfgang Knoll, Jakub Dostalek, Marc Lamy de La Chapelle

This paper reports on a systematic study of the plasmonic properties of periodic arrays of gold cylindrical nanoparticles in contact with a gold thin film. Depending on the gold film thickness, it observes several plasmon bands. Using a simple analytical model, it is able to assign all these modes…

Plasmonics, 2020, 15 (6), pp.1653-1660. ⟨10.1007/s11468-020-01185-9⟩. ⟨hal-03044556⟩

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A New Nanocomposite: L-DOPA/Laponite

Maguy Jaber, Jean-Francois Lambert

A simple procedure is reported to obtain original nanocomposite materials combining the smectite Laponite and melanin-like polymers. Aq. polymn. of L-DOPA is considerably accelerated in the presence of suspended Laponite particles, and its mechanism is significantly modified with respect to…

Journal of Physical Chemistry Letters, 2010, 1 (1), pp.85-88. ⟨10.1021/jz900020m⟩. ⟨hal-00604726⟩

• Communication dans un congrès

Preparation of SiO2-supported Ni-Fe nanoparticles exhibiting a Fe gradient for the hydrogenation of sugars in water

Francois Robert, Achraf Sadier, Catherine Amiens, Karine Philippot, Robert Wojcieszak, E. Marceau

13th International Symposium on the Preparation of Heterogeneous Catalysts (PREPA13), Jul 2023, Louvain-la-Neuve, Belgium. ⟨hal-04523325⟩

• Communication dans un congrès

Silica-supported iron-nickel nanoparticles for the hydrogenation of xylose

Francois Robert, Pierre Lecante, V. Collière, Achraf Sadier, Robert Wojcieszak, Jean Sébastien Girardon, Valérie Briois, E. Marceau, Catherine Amiens, Karine Philippot

SCF'23, Jun 2023, Nantes, France. ⟨hal-04523384⟩

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Toward new proton exchange batteries based on ionic liquid electrolyte: Metal hydride electrode / electrolyte coupling

Nesrine Chaabene, J. Zhang, Mireille Turmine, E. Kurchavova, Vincent Vivier, F. Cuevas, M. Mateos, M. Latroche, J. Monnier

The voltage of an alkaline electrolyte-based battery is limited by the narrow electrochemical stability window of water. As an alternative to water, protic ionic liquid (IL)-based electrolytes have shown excellent conducting properties as well as a wide electrochemical stability window, and can…

Journal of Power Sources, 2023, 574, pp.233176. ⟨10.1016/j.jpowsour.2023.233176⟩. ⟨hal-04129101⟩

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What Do the Niobium Framework Sites Look Like in Redox Zeolites? A Combined Theoretical and Experimental Investigation

Frederik Tielens, Tetsuya Shishido, Stanislaw Dzwigaj

Ab initio periodic DFT calculations oil the structural and energy properties of different model niobium framework sites ill niobium-substituted zeolites containing sodalite cavities are presented and related to experimental FTIR measurements oil Nb containing SiBEA zeolite. The niobium framework…

Journal of Physical Chemistry C, 2010, 114 (7), pp.3140-3147. ⟨10.1021/jp910956j⟩. ⟨hal-00604809⟩

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Quantitative Investigation of MgO Bronsted Basicity: DFT, IR, and Calorimetry Study of Methanol Adsorption

Hugo Petitjean, Konstantin Tarasov, Francoise Delbecq, Philippe Sautet, Jean-Marc Krafft, Philippe Bazin, Maria Cristina Paganini, Elio Giamello, Michel Che, Helene Lauron-Pernot, Guylene Costentin

The adsorption geometries, energies, and vibrational frequencies of methanol on MgO defective surfaces have been calcd. by periodic DFT simulations. The results are very comparable with those obtained with water and are also in very good accordance with microcalorimetry and IR expts. At low…

Journal of Physical Chemistry C, 2010, 114 (7), pp.3008-3016. ⟨10.1021/jp909354p⟩. ⟨hal-00604791⟩