• Poster de conférence

Fate of Organic Molecules in the Mars Regolith Under UV Radiation Deduced from the MOMIE Laboratory Experiment

Cyril Szopa, Patrice Coll, Fabien Stalport, Olivier Poch, Maguy Jaber, Jean-François Lambert, Laura Rouquette, Jérôme Lasne

Among bioindicators or biosigna- tures, organic molecules present on Mars could be re- trieved in the regolith near the surface due to erosion of rocks and gardening of the soil from meteorites bom- bardment through the Mars history. Once their, the organic molecules are submitted to the harsh…

• Article dans une revue

Equilibrium and dynamics of single-peptide binding to aluminum oxides: Emphasizing the role of local surface charge and hydrophobicity

Joanne Lê-Chesnais, Christophe Méthivier, Daniela Rodriguez, Christophe Humbert, Jean-François Lambert, Jessem Landoulsi

Understanding the interactions between biomolecules and mineral surfaces is a fundamental challenge at the crossroads of colloid science, surface chemistry, and molecular biophysics. While peptides and amino acids are known to bind a variety of metal oxides, our understanding remains limited…

Applied Surface Sciences Advances, 2025, 29, pp.100840. ⟨10.1016/j.apsadv.2025.100840⟩. ⟨hal-05266519⟩

• Article dans une revue

From 8-hydroxy-5-sulfoquinoline to new related fluorogenic ligands for complexation of aluminium(III) and gallium(III)

Franck Launay, Valérie Alain-Rizzo, Émilie Destandau, Nathalie Ramos, Ēlisabeth Bardez, Paul Baret, Jean-Louis Pierre

The hexadentate tripodal ligand O-TRENSOX (already known as a siderophore), incorporating three 8-hydroxy-5- sulfoquinoline (8-HQS) subunits, was investigated as a potential Ñuorogenic ligand of Al(III) and Ga(III). For the sake of comparison, every chelation study was also carried out with n-BUSOX…

New Journal of Chemistry, 2001, 25 (10), pp.1269-1280. ⟨10.1039/B103406P⟩. ⟨hal-05184790⟩

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Type IV Collagen surface functionalization for in vitro cell culture models

Manon Miran, Nicolas Rodriguez, Sophie Cribier, Souhir Boujday, Frederic Pincet, Kieu Ngo, Guillaume Perry

The Bioelectricity Cluster 2025, Apr 2025, Oxford, United Kingdom. ⟨hal-05162925⟩

• Article dans une revue

Covalent Grafting of Organic–Inorganic Polyoxometalates Hybrids onto Mesoporous SBA-15: A Key Step for New Anchored Homogeneous Catalysts

Richard Villanneau, Asma Marzouk, Yan Wang, Aicha Ben Djamaa, Guillaume Laugel, Anna Proust, Franck Launay

Covalent grafting of the polyoxometalate (POM) hybrid [AsW9O33{P(O)(CH2CH2CO2H)}2]5- on mesoporous NH2-functionalized SBA-15 is the first example of anchored vacant POMs in which nucleophilic oxygen atoms are still available after incorporation into the supports. Such systems are interesting…

Inorganic Chemistry, 2013, 52 (6), pp.2958 - 2965. ⟨10.1021/ic302374v⟩. ⟨hal-01563887⟩

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Loop-stabilized BAB triblock copolymer morphologies by PISA in water

Pauline Biais, Patricia Beaunier, François Stoffelbach, Jutta Rieger

A straightforward strategy to synthesize in water, loop-stabilized particles via PISA is developed. These particular structures can in theory be obtained through the synthesis of amphiphilic BAB triblock copolymers, starting from a hydrophilic middle block A, which is chain extended in an aqueous…

Polymer Chemistry, 2018, 9 (35), pp.4483-4491. ⟨10.1039/C8PY00914G⟩. ⟨hal-02374121⟩

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Multifunctional Supramolecular Gels with Strong Mechanical Properties Formed by Self-Assembly of Polyoxometalate-Based Coordination Polymers

Lorenzo Casimiro, Florence Volatron, Grégoire Boivin, Benjamin Abécassis, Sandra Alves, Dalil Brouri, David Montero, Jean-Michel Guigner, Lise-Marie Chamoreau, Geoffrey Gontard, David Portehault, Yanling Li, Rodrigue Lescouëzec, Anna Proust, Guylaine Ducouret, Albert Solé-Daura, Patrick Davidson, Théo Merland, Guillaume Izzet

<div><p>Metallogels built in a bottom-up approach by metal coordination and supramolecular interactions have important potential for the elaboration of smart materials. In this context, we present here the formation of supramolecular coordination polymers driven by the complexation of…

JACS Au, 2024, ⟨10.1021/jacsau.4c00981⟩. ⟨hal-04823350⟩

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Hydrothermally stable Pd/SiO2@Zr Core@Shell catalysts for diesel oxidation applications

Chih-Han Liu, Junjie Chen, Todd Toops, Jae-Soon Choi, Cyril Thomas, Michael Lance, Eleni Kyriakidou

Hydrothermally stable diesel oxidation catalysts (DOCs) with improved low-temperature activity are desired for the abatement of emissions from diesel vehicles. Herein, novel palladium(Pd)/SiO2(core)@Zr(shell) structured DOCs were developed. SiO2 was completely covered by an 8.4 nm thickness Zr-…

Chemical Engineering Journal, 2021, 425, pp.130637. ⟨10.1016/j.cej.2021.130637⟩. ⟨hal-03343231⟩

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Metal-free platforms for molecular thin films as high-performance supercapacitors

Ritu Gupta, Ankur Malik, Kusum Kumari, Saurabh Kumar Singh, Vincent Vivier, Prakash Chandra Mondal

Oligomeric thin films of anthracene, pyrene, and naphthalene are electrochemically prepared on graphite rods for understanding enhanced supercapacitor explained through proton-coupled electron-transfer and electrical double-layer mechanism.

Chemical Science, 2024, 15 (23), pp.8775-8785. ⟨10.1039/D4SC00611A⟩. ⟨hal-04775537⟩

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Chromium Oxide Species Supported on Silica: A Representative Periodic DFT Model

Hazar Guesmi, Frederik Tielens

The Cr/SiO2 system is investigated using periodic DFT. The model represents the amorphous character of the silica surface and allows the investigation of the effect of hydration on the Cr(VI) monomers. First, the geometry and energetics are discussed and compared with experimental data. The phase…

Journal of Physical Chemistry C, 2011, 116, pp.994-1001. ⟨10.1021/jp209680r⟩. ⟨hal-00690824⟩