• Article dans une revue

Selective Oxidation of Methane to Formaldehyde Catalyzed by Phosphates: Kinetic Description by Bond Strengths and Specific Total Acidities

Vasilij Gomonaj, Hervé Toulhoat

A kinetic model predicts the experimental activity and selectivity patterns obtained in oxidation of methane for divided unsupported orthophosphates (M II 3(PO4)2, M III PO4,) and pyrophosphates (M II 2P2O7, M IV P2O7) catalysts spanning extended ranges of M-O bond strength (calculated from first…

ACS Catalysis, 2018, 8 (9), pp.8263-8272. ⟨10.1021/acscatal.8b02629⟩. ⟨hal-01955648⟩

• Article dans une revue

A soft-chemistry assisted strong metal–support interaction on a designed plasmonic core–shell photocatalyst for enhanced photocatalytic hydrogen production

Getaneh Diress Gesesse, Cong Wang, Bor Kae Chang, Shih-Hsuan Tai, Patricia Beaunier, Robert Wojcieszak, Hynd Remita, Christophe Colbeau-Justin, Mohamed Nawfal Ghazzal

Nanoscale, 2020, ⟨10.1039/C9NR09891G⟩. ⟨hal-02521511⟩

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Fe3+-doped ordered mesoporous γ-Fe2O3/SiO2 microspheres as a highly efficient magnetically separable heterogeneous Fenton catalyst

Nassira Ferroudj, Patricia Beaunier, Anne Davidson, Sébastien Abramson

Here, several γ-Fe 2 O 3 /SiO 2 nanocomposite microspheres were synthesized, characterized and tested as magnetically separable heterogeneous catalysts in an advanced oxidation process. A strong relation between the structure and the activity of these materials was evidenced. Two parameters,…

Microporous and Mesoporous Materials, 2021, 326, pp.111373. ⟨10.1016/j.micromeso.2021.111373⟩. ⟨hal-03524378⟩

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Emergence of Order in Origin-of-Life Scenarios on Mineral Surfaces: Polyglycine Chains on Silica

Ola El Samrout, Marco Fabbiani, Gloria Berlier, Jean-François Lambert, Gianmario Martra

The polymerization of amino acids (AAs) to peptides on oxide surfaces has attracted interest owing to its high importance in biotechnology, prebiotic chemistry, and origin of life theories. However, its mechanism is still poorly understood. We tried to elucidate the reactivity of glycine (Gly) from…

Langmuir, 2022, 38 (50), pp.15516-15525. ⟨10.1021/acs.langmuir.2c02106⟩. ⟨hal-04025462⟩

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Ni-Silica-based Catalysts for CH4 Reforming by CO2 with Enhanced Stability: Recent Designs and the Impacts of Ni Confinement, Promoters, and Core-Shell Structures

Oscar Daoura, Maya Boutros, Franck Launay

CO2 reforming of CH4, also referred to as the Dry Reforming of Methane (DRM), is considered an excellent method to produce H2 and CO (syngas), which are known to be used for the production of higher alkanes and oxygenates. Despite nickel’s moderate toxicity, Ni-based heterogeneous catalysts are…

Journal of Energy and Power Technology, 2021, 3 (1), ⟨10.21926/jept.2101007⟩. ⟨hal-04025299⟩

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Controlled Formation of Native Defects in Ultrapure ZnO for the Assignment of Green Emissions to Oxygen Vacancies

Fredeŕic Averseng, Miao Zhang, Frederic Averseng, Jean-Marc Krafft, Patrizia Borghetti, Guylène Costentin, Slavica Stankic

Ultrapure ZnO nanopowders were synthesized via vapor-phase based methods under oxygen deficient conditions. The type and relative proportions of intrinsic point defects were studied by photoluminescence (PL) and EPR spectroscopies performed under strictly controlled conditions. Besides coupled PL/…

Journal of Physical Chemistry C, In press, 124 (23), pp.12696-12704. ⟨10.1021/acs.jpcc.0c01078⟩. ⟨hal-02896623⟩

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Highly Promoted Photocatalytic Hydrogen Generation by Multiple Electron Transfer Pathways

Xiaojiao Yuan, Cong Wang, Diana Dragoe, Patricia Beaunier, Christophe Colbeau-Justin, Hynd Remita

Applied Catalysis B: Environmental, 2021, 281, pp.119457. ⟨10.1016/j.apcatb.2020.119457⟩. ⟨hal-03092690⟩

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Revealing Size Dependent Structural Transitions in Supported Gold Nanoparticles in Hydrogen at Atmospheric Pressure

Abdallah Nassereddine, Qing Wang, David Loffreda, Christian Ricolleau, Damien Alloyeau, Catherine Louis, Laurent Delannoy, Jaysen Nelayah, Hazar Guesmi

The enhancement of the catalytic activity of gold nanoparticles with their decreasing size is often attributed to the increasing proportion of low-coordinated surface sites. This correlation is based on the paradigmatic picture of working gold nanoparticles as perfect crystal forms having complete…

Small, 2021, pp.2104571. ⟨10.1002/smll.202104571⟩. ⟨hal-03367920⟩

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Co–Ru Nanoalloy Catalysts for the Acceptorless Dehydrogenation of Alcohols

Brandon Azeredo, Tayssir Ben Ghzaiel, Ning Huang, Kamila Kaźmierczak, Wenjie Shen, Guillaume Wang, Delphine Schaming, Patricia Beaunier, Philippe Decorse, Noémie Perret, Jennifer Peron, Marion Giraud, Carine Michel, Lorette Sicard, Jean-Yves Piquemal

The synthesis of Co–Ru bimetallic nanoparticles was performed by co-reduction of Co(II) and Ru(III) salts in octan-1-ol, acting both as a solvent and a mild reducing agent. The metal composition was varied in the entire range, from pure Co to pure Ru. Although Co and Ru are miscible in the bulk,…

ACS Applied Nano Materials, 2022, 5 (4), pp.5733-5744. ⟨10.1021/acsanm.2c00764⟩. ⟨hal-03821692⟩

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Cyto- and bio-compatibility assessment of plasma-treated polyvinylidene fluoride scaffolds for cardiac tissue engineering

Maria Kitsara, Gaëlle Revet, Jean-Sébastien Vartanian-Grimaldi, Alexandre Simon, Mathilde Minguy, Antoine Miche, Vincent Humblot, Thierry Dufour, Onnik Agbulut

As part of applications dealing with cardiovascular tissue engineering, drop-cast polyvinylidene fluoride (PVDF) scaffolds have been treated by cold plasma to enhance their adherence to cardiac cells. The scaffolds were treated in a dielectric barrier device where cold plasma was generated in a…

Frontiers in Bioengineering and Biotechnology, 2022, 10, pp.1008436. ⟨10.3389/fbioe.2022.1008436⟩. ⟨hal-03889499v2⟩