Laboratoire de réactivité de surface

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  • Article dans une revue

Mesoporous materials from zeolite seeds as supports for nickel tungsten sulfide active phases Part 1. Characterization and catalytic properties in hydrocracking reactions

Shuangqin Zeng, Juliette Blanchard, Michèle Breysse, Dadong Li, Hong Nie, Yahua Shib, Xintian Su

MCM-41 aluminosilicate mesostructures (Si/Al = 18) with hexagonal long-range order were assembled from protozeolitic nanoclusters (zeolite seeds) that normally nucleate the crystn. of b-zeolite (BEA). Depending on the duration of the thermal treatment leading to the zeolite seeds, different acidic…

Applied Catalysis A : General, 2005, 294, pp.59-67. ⟨10.1016/j.apcata.2005.07.015⟩. ⟨hal-00080297⟩

  • Article dans une revue

Silver species reduction upon exposure of Ag/Al2O3 catalyst to gaseous ethanol: An in situ Quick-XANES study

Elie Sayah, Camille La Fontaine, Valérie Briois, Dalil Brouri, Pascale Massiani

The evolution of supported silver species of a pre-calcined Ag/Al2O3 catalyst was monitored upon thermal treatment under an air flow enriched with 3000 ppm of ethanol (EtOH) using transmission electron microscopy and UV-visible and X-ray absorption spectroscopies. A special focus is put on the…

Catalysis Today, 2012, 189, pp.55-59. ⟨10.1016/j.cattod.2012.03.055⟩. ⟨hal-00745963⟩

  • Article dans une revue

Influence of the preparation procedure on the nature and environment of vanadium in VSiBEA zeolite: XRD, DR UV-vis, NMR, EPR and TPR studies

Rafal Baran, Yannick Millot, Thomas Onfroy, Frédéric Averseng, Jean-Marc Krafft, Stanislaw Dzwigaj

Two series of VxSiBEA(I) and VxSiBEA(II) zeolites have been prepared by a two-steps postsynthesis method which consists, in the first step, in the dealumination of TEABEA zeolite by two different procedures to obtain SiBEA(I) and SiBEA(II) zeolites and then, in the second step, in contacting the…

Microporous and Mesoporous Materials, 2012, 161, pp.179-186. ⟨10.1016/j.micromeso.2012.05.023⟩. ⟨hal-00744705⟩

  • Article dans une revue

The influence of C1 and C2 organic reducing agents on catalytic properties of Co(II)-single site BEA zeolite in SCR of NO

Janusz Janas, Wojciech Rojek, Stanislaw Dzwigaj

CoSiBEA zeolite with 0.9 wt.% Co is prepared in acidic (pH = 2.5) condition by a two-step postsynthesis method which allows to incorporate cobalt into framework zeolite as isolated tetrahedral Co(II) species, as evidenced by XRD and diffuse reflectance UV-vis. As obtained Co(II)-single site zeolite…

Catalysis Today, 2012, 191, pp.32-37. ⟨10.1016/j.cattod.2012.03.004⟩. ⟨hal-00744302⟩

  • Article dans une revue

Chromium sites in zeolite framework: Chromyl or chromium hydroxyl groups?

Frederik Tielens, Mazharul M. Islam, Gabriella Skara, F. de Proft, Tetsuya Shishido, Stanislaw Dzwigaj

A combined experimental and ab initio periodic DFT calculation on the structure and stability of different chromium-substituted zeolite models are presented. Experimental investigation by XRD, FT-IR and UV-vis show the presence of chromium in SiBEA zeolite. The favorable chromium sites are…

Microporous and Mesoporous Materials, 2012, 159, pp.66-73. ⟨10.1016/j.micromeso.2012.02.046⟩. ⟨hal-00744253⟩

  • Article dans une revue

Solving the Long-Standing Cu(111) "8" Surface Oxide Puzzle

Romain Bernard, Jacek Goniakowski, Claudine Noguera, Alessandro Coati, Yves Garreau, Guilhem Simon, Axel Wilson, Lei Zhang, Ahmed Naitabdi, Geoffroy Prévot

<div><p>Due to the interesting properties of copper oxides, in particular for catalytic applications, ultrathin oxide layers formed by Cu oxidation have attracted sustained interest. Experimental observations of several surface phases, including the so-called "5-7", "8…

ACS Nano, 2026, ⟨10.1021/acsnano.6c11362⟩. ⟨hal-05731076⟩

  • Pré-publication, Document de travail

A common precursor to both prebiotic and biological pathways to RNA nucleotides

Andrea Pérez-Villa, Thomas Georgelin, Jean-François Lambert, Marie-Christine Maurel, François Guyot, A. Marco Saitta, Fabio Pietrucci

Understanding the mechanism of spontaneous formation of ribonucleotides under realistic prebiotic conditions is a key open issue of origins-of-life research. In cells, de novo and salvage nucleotide enzymatic synthesis combines 5-phospho-α-D-ribose-1-diphosphate (α-PRPP) and nucleobases.…

2023. ⟨hal-04015892⟩

  • Article dans une revue

Silk foams with metallic nanoparticles as scaffolds for soft tissue regeneration

Claire de Lartigue, Cristina Belda Marín, Vincent Fitzpatrick, Antonella Esposito, Sandra Casale, Jessem Landoulsi, Erwan Guénin, Christophe Egles

Tissue regeneration can be achieved by providing endogenous cells with a biomaterial scaffold that supports their adhesion and proliferation, as well as the synthesis and deposition of an extracellular matrix (ECM). In this work, silk fibroin protein foams were formed by lyophilization to generate…

International Journal of Molecular Sciences, 2024, 25 (22), pp.12377. ⟨10.3390/ijms252212377⟩. ⟨hal-04798722⟩

  • Poster de conférence

Chemical evolution of organic molecules under Mars-like UV radiation conditions simulated in the laboratory with the MOMIE setup

O. Poch, Patrice Coll, Cyril Szopa, F. Stalport, T. Georgelin, M. Jaber, J.F. Lambert

The search for organic carbon at the surface of Mars, as clues of past habitability or remnants of life, is a major science goal of Mars' exploration. Understanding the chemical evolution of organic molecules under current Martian environmental conditions is essential to support the past,…

Eighth International Conference on Mars, Jul 2014, Pasadena, United States. pp.abstract 1228, 2014. ⟨hal-01139973⟩

  • Article dans une revue

Cysteine-montmorillonite composites for heavy metal cation complexation: A combined experimental and theoretical study

Khaled El Adraa, Thomas Georgelin, Jean-François Lambert, Farouk Jaber, Frederik Tielens, Maguy Jaber

Green composites based on montmorillonite (Mt) and cysteine, were prepared for heavy metal removal. A comparison between the adsorption properties of the resulting hybrid inorganic-organic materials and the pure montmorillonite was carried out for the following heavy metal cations Cd2+, Hg2+, Pb2…

Chemical Engineering Journal, 2017, 314, pp.406 - 417. ⟨10.1016/j.cej.2016.11.160⟩. ⟨hal-01490419⟩