Laboratoire de réactivité de surface

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  • Article dans une revue

Selective catalytic reduction of NO on single site FeSiBEA zeolite catalyst: Influence of the C1 and C2 reducing agents on the catalytic properties

Janusz Janas, Wojciech Rojek, Tetsuya Shishido, Stanislaw Dzwigaj

FeSiBEA zeolite with 0.8 Fe wt% is prepared in acidic condition (pH 2.5) by a two-step postsynthesis method which allows to incorporate iron into framework of zeolite as mononuclear distorted tetrahedral Fe(III) species, as evidenced by XRD, diffuse reflectance UV-vis and X-ray absorption…

Applied Catalysis B: Environmental, 2012, 123-124, pp.134-140. ⟨10.1016/j.apcatb.2012.04.026⟩. ⟨hal-00744653⟩

  • Article dans une revue

Methanol oxidation on VSiBEA zeolites: Influence of V content on the catalytic properties

Marciej Tredja, Maria Ziolek, Yannick Millot, Karolina Chalupka, Michel Che, Stanislaw Dziwag

This study deals with the influence of V content on the catalytic properties of VxSiBEA zeolites in the oxidation of methanol. The samples are prepared following a postsynthesis method reported earlier (S. Dzwigaj, M.J. Peltre, P. Massiani, A. Davidson, M. Che, T. Sen, S. Sivasanker, Chem. Commun…

Journal of Catalysis, 2011, 281 (1), pp.169-176. ⟨10.1016/j.jcat.2011.04.013⟩. ⟨hal-00663368⟩

  • Article dans une revue

Transformations of γ-alumina in aqueous suspensions. 1. Alumina chemical weathering studied as a function of pH

Xavier Carrier, Eric Marceau, Jean-François Lambert, Michel Che

Hydration of γ-Al2O3 is often reported to occur via the superficial transformation of the alumina surface into alumina hydroxide-like layers. However, very little evidence has been given so far to support this hypothesis. It is demonstrated here by X-ray diffraction, TEM, electron diffraction and…

Journal of Colloid and Interface Science, 2007, 308, pp.429-437. ⟨10.1016/j.jcis.2006.12.074⟩. ⟨hal-00133775⟩

  • Article dans une revue

On the kinetics of CO oxidation by O2 over RhI(CO)2 catalytic species anchored to a zeolitic support

Céline Fontaine-Gautrelet, Cyril Thomas, Jean-Marc Krafft, Gérald Djéga-Mariadassou

The reactivity of RhI(CO)2 towards CO oxidation was studied on a model Rh(0.7 wt%)/HY material. The kinetic results show that RhI(CO)2 exhibit a fairly low activity. It is therefore suggested that the catalytic species responsible for the enhanced activity of Rh/Ce0.68Zr0.32O2 [Manuel et al., J.…

Topics in Catalysis, 2007, 42-43, pp.357-361. ⟨10.1007/s11244-007-0205-z⟩. ⟨hal-00157007⟩

  • Article dans une revue

ADSORPTION ON STAINLESS STEEL SURFACES OF BIOSURFACTANTS PRODUCED BY GRAM-NEGATIVE AND GRAM-POSITIVE BACTERIA : CONSEQUENCE ON THE BIOADHESIVE BEHAVIOR OF PATHOGENIC STRAINS.

Thierry Meylheuc, Christophe Méthivier, Margareth Renault, Jean-Marie Herry, Claire-Marie Pradier, Marie-Noëlle Bellon-Fontaine

The ability of adsorbed biosurfactants (Pf and Lb) obtained from gram negative bacterium (Pseudomonas fluorescens) or gram positive bacterium (Lactobacillus helveticus) to inhibit adhesion of four listerial strains to stainless steel was investigated. These metallic surfaces were characterized…

Colloids and Surfaces B: Biointerfaces, 2006, 52 (2), pp.146-155. ⟨10.1016/j.colsurfb.2006.04.016⟩. ⟨hal-00111667⟩

  • Article dans une revue

Effect of water on cobalt speciation during solid-state synthesis of Co2+/ZSM5 catalysts: quantitative study by TPR and XAS

Eric Marceau, Michel Che, Françoise Villain, Younès Ben Taarit

The effect of water on cobalt speciation in the synthesis of Co2+/ZSM5 catalysts is quantitatively studied by the combined use of macroscopic and local characterization techniques, TPR and X-ray absorption spectroscopies, respectively. The addition of a small quantity of water to cobalt acetate and…

Microporous and Mesoporous Materials, 2006, 93, pp.62-70. ⟨10.1016/j.micromeso.2006.02.004⟩. ⟨hal-00109394⟩

  • Article dans une revue

Comparison of molybdenum carbide and tungsten carbide for the hydrodesulfurization of dibenzothiophene

Agnieszka Szymanska-Kolasa, Marek Lewandowski, Celine Sayag, G. Djéga-Mariadassou

The molybdenum and tungsten carbides (Mo2C and W2C) were synthesized, characterized and tested in hydrodesulfurization (HDS) of dibenzothiophene (DBT). The phase purity of these catalysts was established by X-ray diffraction (XRD), and the surface properties were determined by N2 BET specific…

Catalysis Today, 2006, 119, pp.7-12. ⟨10.1016/j.cattod.2006.08.021⟩. ⟨hal-00128084⟩

  • Article dans une revue

On the clarification of the IR stretching vibration assignment of adsorbed N2 on Rh0 and Rhd+ surface atoms of supported Rh crystallites

Céline Fontaine-Gautrelet, Jean-Marc Krafft, Gérald Djéga-Mariadassou, Cyril Thomas

The low temperature adsorption of N2 on Rh/SiO2 samples of various particle-size distributions was followed by FTIR. The addition of O2 pulses on Rh0 surfaces saturated with chemisorbed N2 allowed us to reassign stretching frequencies attributed originally to N2-Rh0 to N2-RhΔ+. The formation of the…

Journal of Physical Chemistry B, 2006, 110, pp.10075-10081. ⟨10.1021/jp061077y⟩. ⟨hal-00079961⟩

  • Article dans une revue

Critical assessment of solvent effects on absorption and fluorescence of 3HF in acetonitrile in the QM/PCM framework: A synergic computational and experimental study

Daniele Loco, Stefano Protti, Benedetta Mennucci, Alberto Mezzetti

Absorption and fluorescence properties of 3-hydroxyflavone (3HF) dissolved in the polar aprotic solvent acetonitrile have been investigated by electronic spectroscopies, associated to mixed quantum mechanical (QM)/classical calculations, where the effect of the solvent is included at the classical…

Journal of Molecular Structure, 2019, 1182, pp.283-291. ⟨10.1016/j.molstruc.2018.12.085⟩. ⟨hal-02178337⟩

  • Article dans une revue

PEDOT nanostructures synthesized in hexagonal mesophases

Srabanti Ghosh, Hynd Remita, Laurence Ramos, Alexandre Dazzi, Ariane Deniset-Besseau, Patricia Beaunier, Fabrice Goubard, Pierre-Henri Aubert, François Brisset, Samy Remita

We describe a single step preparation of nanostructures of poly(3,4-ethylenedioxythiophene), PEDOT, in the hydrophobic domains of cationic surfactant-based hexagonal mesophases via chemical oxidative polymerization of EDOT monomers using FeCl3 as an oxidizing agent. After polymerization, the…

New Journal of Chemistry, 2014, 38 (3), pp.1106-1115. ⟨10.1039/C3NJ01349A⟩. ⟨hal-01117164⟩