• Article dans une revue

Porous nickel-alumina derived from metal-organic framework (MIL-53): a new approach to achieve active and stable catalysts in methane dry reforming

Leila Karam, Julien Reboul, Sandra Casale, Pascale Massiani, Nissrine El Hassan

An Al‐containing MIL‐53 metal‐organic framework with very high surface area (SBET=1130 m2.g−1, N2 sorption) was used as sacrificial template to prepare a nickel‐alumina‐based catalyst (Ni0AlMIL) highly active and stable in the reaction of dry reforming of methane (DRM). The procedure consisted in…

ChemCatChem, 2020, 12 (1), pp.373-385. ⟨10.1002/cctc.201901278⟩. ⟨hal-03053800⟩

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Plasmonic Ru/hydrogen molybdenum bronzes with tunable oxygen vacancies for light-driven reduction of p -nitrophenol

Haibo Yin, Yasutaka Kuwahara, Kohsuke Mori, Michel Che, Hiromi Yamashita

Plasmonic Ru/H x MoO 3−y hybrids enable significant plasmon-enhanced catalysis for reduction of p -nitrophenol under visible light irradiation.

Journal of Materials Chemistry A, 2019, 7 (8), pp.3783-3789. ⟨10.1039/C8TA11604K⟩. ⟨hal-04022363⟩

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Calibrated Co3O4 nanoparticles patterned in SBA-15 3 silicas: Accessibility and activity for CO oxidation

Irène Lopes, Anne Davidson, Cyril Thomas

The catalytic performances in CO oxidation of Co3 O4 nanoparticles patterned in the porosity of SBA-15 silicas are investigated. 10 Accessibility limitations of the reactants to the catalytic sites are clearly revealed,when the Co3O4 nanoparticles are embedded in the 11 SBA-15 pores.Despite these…

Catalysis Communications, 2007, 8, pp.2105-2109. ⟨hal-00181045⟩

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Sustainable production of acrolein: effects of reaction variables, modifiers doping and ZrO2 origin on the performance of WO3/ZrO2 catalyst for the gas-phase dehydration of glycerol

Song-Hai Chai, Li-Zhi Tao, Bo Yan, Jacques C. Vedrine, Bo-Qing Xu

Zirconia-supported tungsten oxide (WO3/ZrO2 or WZ) is known as an efficient catalyst for selective acrolein (AC) production from gas-phase dehydration of glycerol (GL). Two catalysts (WZ-CP and WZ-AN) were prepared herein using, respectively, a ZrO(OH)2 hydrogel (ZrO(OH)2-CP) and its derived…

RSC Advances, 2014, 4 (9), pp.4619-4630. ⟨10.1039/C3RA46511J⟩. ⟨hal-01079293⟩

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Selective uptake of alkaline earth metals by cyanobacteria forming intracellular carbonates

Nithavong Cam, Karim Benzerara, Thomas Georgelin, Maguy Jaber, Jean-Francois Lambert, Melanie Poinsot, Feriel Skouri-Panet, Laure Cordier

The uptakes of Ca, Sr and Ba by two cyanobacterial strains, Cyanothece sp. PCC7425 and Gloeomargarita lithophora, both forming intracellular carbonates, were investigated in laboratory cultures. In the culture medium BG 11 amended with 250 μM of Ca and 50 or 250 μM of Sr and Ba, G. lithophora…

Environmental Science and Technology, 2016, 50 (21), pp.11654-11662. ⟨10.1021/acs.est.6b02872⟩. ⟨hal-01383264⟩

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The antibacterial activity of Magainin I immobilized onto mixed thiols Self-Assembled Monolayers

Vincent Humblot, Jean-Fabrice Yala, Pascal Thebault, Kada Boukerma, Arnaud Héquet, Jean-Marc Berjeaud, Claire-Marie Pradier

An antibacterial peptide, Magainin I, was covalently bound to a mixed 11-mercaptoundecanoïc acid (MUA) and 6-mercaptohexanol (C6OH) (ratio 1:3) Self-Assembled Monolayer (SAM) on gold surfaces. Each step of the surface functionalization was characterized by Polarization Modulation Reflection…

Biomaterials, 2009, 30 (21), pp.3503-3512. ⟨10.1016/j.biomaterials.2009.03.025⟩. ⟨hal-04435299⟩

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Cobalt Based Catalysts Supported on Two Kinds of Beta Zeolite for Application in Fischer-Tropsch Synthesis

Renata Sadek, Karolina Chalupka, Pawel Mierczynski, Jacek Rynkowski, Jacek Gurgul, Stanislaw Dzwigaj

Co-containing Beta zeolite catalysts prepared by a wet impregnation and two-step postsynthesis method were investigated. The activity of the catalysts was examined in Fischer-Tropsch synthesis (FTS), performed at 30 atm and 260 °C. The physicochemical properties of all systems were investigated by…

Catalysts, 2019, 9 (6), pp.497. ⟨10.3390/catal9060497⟩. ⟨hal-02271879⟩

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Bimetallic Au-Ag/TiO2 catalyst prepared by deposition-precipitation: High activity and stability in CO oxidation

A. Sandoval, A. Aguilar, C. Louis, Agnes Traverse, Rodolfo Zanella

Au-Ag bimetallic catalysts supported on TiO2 were prepared by sequential deposition-precipitation method, silver first and then gold. Au-Ag catalysts with different Au/Ag atomic ratios were synthesized. XANES and H2 TPR results show that gold is more easily reduced in bimetallic catalysts than in…

Journal of Catalysis, 2011, 281, pp.40-49. ⟨10.1016/j.cat.2011.04.003⟩. ⟨hal-00666778⟩

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Selective terminal function modification of SAMs driven by low-energy electrons (0-15 eV)

J. Houplin, L. Amiaud, Vincent Humblot, I. Martin, E. Matar, R. Azria, Claire-Marie Pradier, A. Lafosse

Physical Chemistry Chemical Physics, 2013, 15, pp.7220-7227. ⟨10.1039/C3CP43750G⟩. ⟨hal-00915978⟩

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Emergence of Order in Origin-of-Life Scenarios on Mineral Surfaces: Polyglycine Chains on Silica

Ola El Samrout, Marco Fabbiani, Gloria Berlier, Jean-François Lambert, Gianmario Martra

The polymerization of amino acids (AAs) to peptides on oxide surfaces has attracted interest owing to its high importance in biotechnology, prebiotic chemistry, and origin of life theories. However, its mechanism is still poorly understood. We tried to elucidate the reactivity of glycine (Gly) from…

Langmuir, 2022, 38 (50), pp.15516-15525. ⟨10.1021/acs.langmuir.2c02106⟩. ⟨hal-04025462⟩