Laboratoire de réactivité de surface

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  • Article dans une revue

BSA adsorption on aliphatic and aromatic acid SAMs: Investigating the effect of residual surface charge and sublayer nature

Anne Vallée, Vincent Humblot, Rana Al Housseiny, Souhir Boujday, Claire-Marie Pradier

n this work, the influence of surface charge and layer rigidity on Bovin Serum Albumin (BSA) adsorption has been investigated. To this aim, Self Assembled Monolayers (SAMs) bearing terminal COOH or COO− groups were built on gold surfaces. The rigidity of the acid terminated SAMs was modified using…

Colloids and Surfaces B: Biointerfaces, 2013, 109, pp.136-142. ⟨10.1016/j.colsurfb.2013.03.014⟩. ⟨hal-00915941⟩

  • Article dans une revue

A combined EXAFS and DFT study of the Ni2+ environment in dehydrated Ni/NaX

Hazar Guesmi, Pascale Massiani

The location of the divalent nickel cation exchanged in low amount in dehydrated NaX is identified by a combination of experimental (XAS) and theoretical (DFT) approaches. The Ni-O and Ni-T distances as well as the coordination numbers evaluated from experiments are in good agreement with the…

Catalysis Today, 2011, 177, pp.25-30. ⟨10.1016/j.cattod.2011.04.047⟩. ⟨hal-00667400⟩

  • Article dans une revue

Biosensors elaborated on gold nanoparticles, a PM-IRRAS characterisation of the IgG binding efficiency.

Anne-Laure Morel, Souhir Boujday, Christophe Méthivier, Jean-Marc Krafft, Claire-Marie Pradier

This work is focused on studying the grafting of gold nanoparticles (Np) on a cystamine self-assembled monolayer on gold, in order to build sensitive immunosensors. The synthesis and deposition of gold nanoparticles, 13 and 55 nm sizes, were characterised by combining Polarisation Modulation…

Talanta, 2011, 85, pp.35-42. ⟨10.1016/j.talanta.2011.02.028⟩. ⟨hal-00668945⟩

  • Article dans une revue

The synergistic power of theory and experiment in the field of catalysis

Frederik Tielens, Monica Calatayud

Potential energy curves, equilibrium interatomic distances, term energies and harmonic vibration frequencies for the 16 lowest states of neutral carbon monoxide and the six lowest states of singly ionized carbon monoxide are calculated by density functional theory (DFT) and linear-response time-…

Catalysis Today, 2011, 177, pp.1-2. ⟨10.1016/j.cattod.2011.08.026⟩. ⟨hal-00669713⟩

  • Article dans une revue

Hydrogen and syngas production by methane dry reforming on SBA-15 supported nickel catalysts: On the effect of promotion by Ce0.75Zr0.25O2 mixed oxide

Abdulkader Albarazi, Patricia Beaunier, Patrick da Costa

In this work, the effects of doping Ni-based SBA-15 catalysts with Ceria-Zirconia mixed oxide (CZ) on the activity and stability of these catalysts during syngas production by methane dry reforming (MDR) were investigated and compared with the activity and stability of unmodified Ni/SBA-15. The…

International Journal of Hydrogen Energy, 2013, 38, pp.127-139. ⟨10.1016/j.ijhydene.2012.10.063⟩. ⟨hal-00913348⟩

  • Article dans une revue

Non-biological selectivity in amino acids polymerization on TiO2 nanoparticles

Maguy Jaber, Jolanda Spadavecchia, Houssein Bazzi, Thomas Georgelin, France Costa-Torro, Jean-François Lambert

For the first, time a strong selectivity is evidenced in inorganic peptide synthesis. When an equimolar mixture of Ala and Arg monomers is added to the synthesis medium of TiO2 nanoparticles from Ti(IV) isopropoxide in benzyl alcohol, the Ala-Arg dipeptide is observed by 13C NMR in the resulting…

Amino Acids, 2013, 45, pp.403-406. ⟨10.1007/s00726-013-1516-y⟩. ⟨hal-00957907⟩

  • Article dans une revue

Plasmonic Ru/hydrogen molybdenum bronzes with tunable oxygen vacancies for light-driven reduction of p -nitrophenol

Haibo Yin, Yasutaka Kuwahara, Kohsuke Mori, Michel Che, Hiromi Yamashita

Plasmonic Ru/H x MoO 3−y hybrids enable significant plasmon-enhanced catalysis for reduction of p -nitrophenol under visible light irradiation.

Journal of Materials Chemistry A, 2019, 7 (8), pp.3783-3789. ⟨10.1039/C8TA11604K⟩. ⟨hal-04022363⟩

  • Article dans une revue

Calibrated Co3O4 nanoparticles patterned in SBA-15 3 silicas: Accessibility and activity for CO oxidation

Irène Lopes, Anne Davidson, Cyril Thomas

The catalytic performances in CO oxidation of Co3 O4 nanoparticles patterned in the porosity of SBA-15 silicas are investigated. 10 Accessibility limitations of the reactants to the catalytic sites are clearly revealed,when the Co3O4 nanoparticles are embedded in the 11 SBA-15 pores.Despite these…

Catalysis Communications, 2007, 8, pp.2105-2109. ⟨hal-00181045⟩

  • Article dans une revue

Sustainable production of acrolein: effects of reaction variables, modifiers doping and ZrO2 origin on the performance of WO3/ZrO2 catalyst for the gas-phase dehydration of glycerol

Song-Hai Chai, Li-Zhi Tao, Bo Yan, Jacques C. Vedrine, Bo-Qing Xu

Zirconia-supported tungsten oxide (WO3/ZrO2 or WZ) is known as an efficient catalyst for selective acrolein (AC) production from gas-phase dehydration of glycerol (GL). Two catalysts (WZ-CP and WZ-AN) were prepared herein using, respectively, a ZrO(OH)2 hydrogel (ZrO(OH)2-CP) and its derived…

RSC Advances, 2014, 4 (9), pp.4619-4630. ⟨10.1039/C3RA46511J⟩. ⟨hal-01079293⟩

  • Article dans une revue

Selective uptake of alkaline earth metals by cyanobacteria forming intracellular carbonates

Nithavong Cam, Karim Benzerara, Thomas Georgelin, Maguy Jaber, Jean-Francois Lambert, Melanie Poinsot, Feriel Skouri-Panet, Laure Cordier

The uptakes of Ca, Sr and Ba by two cyanobacterial strains, Cyanothece sp. PCC7425 and Gloeomargarita lithophora, both forming intracellular carbonates, were investigated in laboratory cultures. In the culture medium BG 11 amended with 250 μM of Ca and 50 or 250 μM of Sr and Ba, G. lithophora…

Environmental Science and Technology, 2016, 50 (21), pp.11654-11662. ⟨10.1021/acs.est.6b02872⟩. ⟨hal-01383264⟩