Laboratoire de réactivité de surface

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  • Article dans une revue

Ionic liquid route for the corrosion inhibition of Al alloys: the effect of butylammonium nitrate on the corrosion of AA2024-T6

Abdelmoheiman Zakaria Benbouzid, Oumaïma Gharbi, Najet Sidi-Yakoub, Mai T T Tran, Mireille Turmine, Vincent Vivier

In this work, the effect of an ammonium nitrate ionic liquid on the corrosion susceptibility of an Al-Cu-Mg alloy was investigated. The effect of the nitrate anion and the ammonium cation on the anodic and cathodic kinetics were studied separately using potentiodynamic polarisation testing,…

Corrosion Communications, 2023, 9, pp.57 - 64. ⟨10.1016/j.corcom.2022.11.001⟩. ⟨hal-04274869v2⟩

  • Article dans une revue

Miniaturized Pathogen Detection System Using Magnetic Nanoparticles and Microfluidics Technology

Benjamin Garlan, Amine Rabehi, Kieu Ngo, Sophie Neveu, Reza Askari Moghadam, Hamid Kokabi

Rapid detection of a biological agent is essential to anticipate a threat to the protection of biodiversity and ecosystems. Our goal is to miniaturize a magnetic pathogen detection system in order to fabricate an efficient and portable system. The detection device is based on flat, multilayer coils…

Micromachines, 2024, 15 (10), pp.1272. ⟨10.3390/mi15101272⟩. ⟨hal-04758036⟩

  • Article dans une revue

Peptide Interactions with Metal and Oxide Surfaces

Anne Vallee, Vincent Humblot, Claire-Marie Pradier

Increasing interest in bio-interfaces for medical, diagnostic, or biotechnology applications has highlighted the critical scientific challenge behind both the understanding and control of protein-solid surface interactions. In this context, this Account focuses on the molecular-level…

Accounts of Chemical Research, 2010, 43 (10), pp.1297-1306. ⟨10.1021/ar100017n⟩. ⟨hal-00604811⟩

  • Communication dans un congrès

Formation and fate of alpha-dicarbonyl compounds in honey and Maillard model systems

Varoujan A. Yaylayan, Eric Marceau, Fong L. Chu

Reactive alpha-dicarbonyl compds. can originate from various sources contg. reducing sugars. They are responsible for the formation of many important Maillard reaction products generated in food. Some alpha-dicarbonyl compds. are assocd. with toxicity and immunosuppressive effects while others with…

Abstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, 2010, San Francisco, CA, United States, United States. pp.AGFD-95. ⟨hal-00604814⟩

  • Article dans une revue

What Do the Niobium Framework Sites Look Like in Redox Zeolites? A Combined Theoretical and Experimental Investigation

Frederik Tielens, Tetsuya Shishido, Stanislaw Dzwigaj

Ab initio periodic DFT calculations oil the structural and energy properties of different model niobium framework sites ill niobium-substituted zeolites containing sodalite cavities are presented and related to experimental FTIR measurements oil Nb containing SiBEA zeolite. The niobium framework…

Journal of Physical Chemistry C, 2010, 114 (7), pp.3140-3147. ⟨10.1021/jp910956j⟩. ⟨hal-00604809⟩

  • Article dans une revue

A New Nanocomposite: L-DOPA/Laponite

Maguy Jaber, Jean-Francois Lambert

A simple procedure is reported to obtain original nanocomposite materials combining the smectite Laponite and melanin-like polymers. Aq. polymn. of L-DOPA is considerably accelerated in the presence of suspended Laponite particles, and its mechanism is significantly modified with respect to…

Journal of Physical Chemistry Letters, 2010, 1 (1), pp.85-88. ⟨10.1021/jz900020m⟩. ⟨hal-00604726⟩

  • Article dans une revue

Different Kinds of Tetrahedral V Species in Vanadium-Containing Zeolites Evidenced by Diffuse Reflectance UV-vis, Raman, and Periodic Density Functional Theory

Anna E. Lewandowska, Miguel A. Banares, Frederik Tielens, Michel Che, Stanislaw Dzwigaj

The combined use of DR-UV-vis and Raman spectroscopies allows one to evidence three kinds of tetrahedral V-V with different structure in V(x)SiBEA zeolite. In all cases, vanadium species possess distorted tetrahedral configuration. At very low vanadium content (0.05 wt %), the majority of…

Journal of Physical Chemistry C, 2010, 114 (46), pp.19771-19776. ⟨10.1021/jp107589d⟩. ⟨hal-00604774⟩

  • Article dans une revue

Influence of Magnesium Substitution on the Basic Properties of Hydroxyapatites

Sarah Diallo-Garcia, Danielle Laurencin, Jean-Marc Krafft, Sandra Casale, Mark E. Smith, Hélène Pernot, Guylène Costentin

Magnesium-substituted hydroxyapatites (HAP) have been prepared to evaluate the influence of cationic substitution on the surface basic properties of HAP. Despite successful introduction of some of the magnesium cations into the HAP structure (as evidenced by XRD, infrared, and Raman), no influence of…

Journal of Physical Chemistry C, 2011, 115, pp.24317-24327. ⟨10.1021/jp209316k⟩. ⟨hal-00653862⟩

  • Article dans une revue

Anchoring of Pt(II) Pyridyl Complex to Mesoporous Silica Materials: Enhanced Photoluminescence Emission at Room Temperature and Photooxidation Activity using Molecular Oxygen

Kohsuke Mori, Kentaro Watanabe, Masayoshi Kawashima, Michel Che, Hiromi Yamashita

Chloro(2,2':6',2''-terpyridine)platinum(II) ([Pt(tpy)Cl]Cl) complex was successfully anchored to a series of (3-aminopropyl)trimethoxysilane-modified mesoporous silica materials (MCM-41, SBA-15, and MCM-48). Pt LIII-edge x-ray absorption fine structure (XAFS) measurements reveal…

Journal of Physical Chemistry C, 2011, 115 (4), pp.1044-1050. ⟨10.1021/jp105577f⟩. ⟨hal-00602944⟩

  • Article dans une revue

Organo-NOx formation-decomposition as the origin of the changes in the low temperature NO-TPD profile in the presence of n-decane on Ag/γ-Al2O3

Kinga Malinger, Juliette Blanchard, Rachel P. Doherty, Cyril Thomas

The NOx desorption profiles obtained in O2-He and n-C10-O2-He were compared on γ-Al2O3 and Ag/γ-Al2O3. On Ag/γ-Al2O3, the low-temperature NOx desorption profiles obtained in n-C10-O2-He were significantly different from those obtained in O2-He. In particular, at 190-220 °C excess release of NO,…

Catalysis Communications, 2014, 46, pp.81-85. ⟨10.1016/j.catcom.2013.11.017⟩. ⟨hal-00982268⟩