• Article dans une revue

Detailed kinetic modeling study of NOx oxidation and storage and their interactions over Pt/Ba/Al2O3 monolith catalysts

Nikola Rankovic, Andre Nicolle, Patrick da Costa

The concept of nitrogen oxide storage-redn. (NSR) is a promising aftertreatment technol. for reducing NOx emissions from lean-burn engine exhaust. The present work focuses on the first two steps of the overall NSR mechanism, namely, NO to NO2 oxidn. and NOx storage. The governing storage mechanisms…

Journal of Physical Chemistry C, 2010, 114 (15), pp.7102-7111. ⟨10.1021/jp100192u⟩. ⟨hal-00604794⟩

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Ag–Ni bimetallic SiBEA zeolite as an efficient catalyst of hydrodechlorination of 1,2-dichloroethane towards ethylene

A Śrębowata, I Zielińska, R Baran, G Słowik, S Dzwigaj

Dealuminated form of BEA zeolite with Si/Al ratio of 1500 was used for the synthesis of Ag2.0SiBEA, Ni2.0SiBEA and Ag2.0Ni2.0SiBEA by two-step postsynthesis method. The calcination of zeolite samples led to the formation of well dispersed isolated mononuclear Ag(I) and Agnδ + clusters and a pseudo-…

Catalysis Communications, 2015, 69, pp.154-160. ⟨10.1016/j.catcom.2015.06.009⟩. ⟨hal-01171840⟩

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Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D framework at the nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting

Ram Kumar, Yang Song, Anissa Ghoridi, Philippe Boullay, Gwenaelle Rousse, Christel Gervais, Cristina Coelho Diogo, Houria Kabbour, Capucine Sassoye, Patricia Beaunier, Victor Castaing, Bruno Viana, Maria Luisa Ruiz Gonzalez, José Gonzalez Calbet, Christel Laberty-Robert, David Portehault

Mixed-anion compounds widen the chemical space of attainable materials compared to single anionic compounds, but the exploration of their structural diversity is limited by common synthetic paths. Especially, oxychlorides rely mainly on layered structures, which suffer from low stability during…

Angewandte Chemie, 2023, ⟨10.1002/ange.202303487⟩. ⟨hal-04070975⟩

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Recent studies on the preparation, activation and design of active phases and supports of hydrotreating catalysts

Michèle Breysse, C. Geantet, P. Afanasiev, Juliette Blanchard, M. Vrinat

Commercial hydrotreating catalysts are usually composed of a sulfide active phase, molybdenum or tungsten sulfide promoted by cobalt or nickel, supported on alumina. Due to very stringent environmental regulations, the research effort to enhance the properties of these catalysts is still very…

Catalysis Today, 2008, 130, pp.3-13. ⟨10.1016/j.cattod.2007.08.018⟩. ⟨hal-00283614⟩

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Salt concentration and pH-dependent adsorption of two polypeptides on planar and divided alumina surfaces; in situ IR investigations.

Claire-Marie Pradier, Vincent Humblot, Lorenzo Stievano, Christophe Méthivier, Jean-François Lambert

The adsorption of proteins is the first process to take place when a solid is immersed in a biological fluid; though not yet thoroughly understood at a molecular level, this process is also known to be strongly influenced by the presence of salt in solution or by pH changes. In the present work,…

Langmuir, 2007, 23, pp.2463-2471. ⟨10.1021/la062208p⟩. ⟨hal-00138685⟩

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Search for confinement effects in mesoporous supports: hydrogenation of o-xylene on Pt /MCM-41

Franck Letellier, Juliette Blanchard, Katia Fajerwerg, Catherine Louis, Michele Breysse, Denis Guillaume, Denis Uzio

The occurrence in meso-porous supports of a confinement effect related to the adsorption strength of a reaction intermediate on a metallic phase dispersed in the meso pores is examd., as well as its effect on the activity and selectivity. A model is proposed in order to det. the catalyst…

Catalysis Letters, 2006, 110, pp.115-124. ⟨10.1007/s10562-006-0093-z⟩. ⟨hal-00111995⟩

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Influence of the texturalproperties of porousaluminas on the reducibility of Ni/Al2O3 catalysts

Faiza Bentaleb, Eric Marceau

Temperature-programmed reduction (TPR) profiles recorded on calcined Ni/Al2O3 catalysts exhibiting the same Ni(II) surface density (3 Ni2+ nm−2) suggest that nickel speciation and reducibility are significantly influenced by the specific surface area and texturalproperties of aluminas, and by their…

Microporous and Mesoporous Materials, 2012, 156, pp.40-44. ⟨10.1016/j.micromeso.2012.02.018⟩. ⟨hal-00686937⟩

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Synergy between XANES spectroscopy and DFT to Elucidate the Amorphous Structure of Heterogeneous Catalysts: TiO2-Supported Molybdenium Oxide Catalysts

Asma Tougerti, Elise Berrier, Anne-Sophie Mamede, Camille La Fontaine, Valérie Briois, Yves Joly, Edmond Payen, Sylvain Cristol, J.F. Paul

Angewandte Chemie International Edition, 2013, 52, pp.6440. ⟨10.1002/ange.201300538⟩. ⟨hal-00855400⟩

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BEA zeolite modified with iron as effective catalyst for N2O decomposition and selective reduction of NO with ammonia

Pawel Boron, Lucjan Chmielarz, J. Gurgul, K. Łątka, Tetsuya Shishido, J.M. Krafft, Stanislaw Dzwigaj

BEA zeolite is modified by a two-steps postsynthesis method allowing incorporate iron atoms into the zeolite framework. Two series of the zeolite samples with aluminium (FexAlSiBEA) and without aluminium (FexSiBEA), containing various iron content (0.5-4.0 Fe wt.%) are obtained. For low Fe content…

Applied Catalysis B: Environmental, 2013, 138-139, pp.434-445. ⟨10.1016/j.apcatb.2013.03.022⟩. ⟨hal-00911026⟩

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Preparation of thin film gold based catalysts for oxidation reactions in liquid and gas phases

Anne-Félicie Lamic-Humblot, Philippe Barthe, Guillaume Guzman, Laurent Delannoy, Catherine Louis

This work deals with the preparation of gold on titania catalysts to make catalytic films in the less than 100 nm thickness area and its comparison with usual powder catalyst in catalytic oxidation reactions in gas and liquid phases. Titania was coated on glass plates with different thicknesses,…

Thin Solid Films, 2012, 527, pp.96-101. ⟨10.1016/j.tsf.2012.11.096⟩. ⟨hal-00906344⟩