Laboratoire de réactivité de surface

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  • Article dans une revue

Covalent Grafting of Organic–Inorganic Polyoxometalates Hybrids onto Mesoporous SBA-15: A Key Step for New Anchored Homogeneous Catalysts

Richard Villanneau, Asma Marzouk, Yan Wang, Aicha Ben Djamaa, Guillaume Laugel, Anna Proust, Franck Launay

Covalent grafting of heteropolyanions hybrids B,α-[AsIIIW9O33{P(O)(CH2CH2CO2H)}2]5- on 3-aminopropyle functionalized SBA-15 has been achieved through the formation of peptide bonds. The covalent link has been confirmed by using IR and 13C CP MAS NMR spectroscopies. Electrostatic interactions…

Inorganic Chemistry, 2013, 52 (6), pp.2958-2965. ⟨10.1021/ic302374v⟩. ⟨hal-03991058⟩

  • Communication dans un congrès

Mesoporous alumina of controlled pore size obtained by surface alumination of pure silica SBA 15

Emmanuel de La Rochefoucauld, Xavier Carrier, Jean-Marc Krafft, Juliette Blanchard

Silica-alumina oxide supports were synthesized by surface alumination of mesoporous silica SBA-15 with Al isopropoxide in organic solvents. These materials were characterised by N2 adsorption-desorption isotherms, XRD, 27Al NMR and cumene cracking. The chemical nature of the surface was probed by…

Scientific Bases for the Preparation of Heterogeneous Catalysts, Proceedings of the 9th International Symposium, 2006, France. pp.13-20. ⟨hal-00096788⟩

  • Article dans une revue

Chemical Preparation of Supported Bimetallic Catalysts. Gold-Based Bimetallic, a Case Study

Catherine Louis

This review focuses on the chemical methods used to prepare supported bimetallic heterogeneous catalysts, i.e., bimetallic nanoparticles deposited on a support. The review is limited to the preparation of gold-based bimetallic catalysts and moreover to bimetallic nanoparticles supported on powder…

Catalysts, 2016, 6 (8), pp.110. ⟨10.3390/catal6080110⟩. ⟨hal-01375388⟩

  • Article dans une revue

Influence of organic additives on the properties of impregnationsolutions and on nickel oxide particle size for Ni/Al2O3catalysts

Faiza Bentaleb, Michel Che, Anne-Claire Dubreuil, Cécile Thomazeau, Eric Marceau

tThe introduction of organic additives, such as polyols, sugars or polyacids, in impregnation solutionshas been suggested to better control the size of nanoparticles on supported catalysts. The present paperfocuses on the roles played by three of these additives, sorbitol, glucose and citric acid,…

Catalysis Today, 2014, 235, pp.250-255. ⟨10.1016/j.cattod.2014.02.020⟩. ⟨hal-01065046⟩

  • Article dans une revue

Magnetic Fe 2 O 3 −Polystyrene/PPy Core/Shell Particles: Bioreactivity and Self-Assembly

Claire Mangeney, Meriem Fertani, Smain Bousalem, Ma Zhicai, Souad Ammar, Frédéric Herbst, Patricia Beaunier, Abdelhamid Elaissari, Mohamed Chehimi

This paper describes the synthesis of new magnetic, reactive polystyrene/polypyrrole core/shell latex particles. The core consists of a polystyrene microsphere containing gamma-Fe2O3 superparamagnetic nanoparticles (PSmag), and the shell is made of reactive N-carboxylic acid-functionalized…

Langmuir, 2007, 23 (22), pp.10940-10949. ⟨10.1021/la700492s⟩. ⟨hal-02093459⟩

  • Article dans une revue

Characterization and catalytic activity of Mn (salen) immobilized on silica by various strategies

Khalil Tesnime Abou, Chaaben Semy Ben, Boujday Souhir, Bergaoui Latifa

Different strategies were applied to prepare supported Mn(salen) on fumed silica and to explore the effect of the interaction nature between the active sites and the surface on the catalytic activity. Direct and multistep grafting methods were used: the silica surface was silylated and the metal…

IOSR Journal of Applied Chemistry, 2015, 8, pp.36-45. ⟨10.9790/5736-08113645⟩. ⟨hal-01133157⟩

  • Article dans une revue

An Anthropocene-Framed Transdisciplinary Dialog at the Chemistry-Energy Nexus

Mathieu S Prévot, Valeria Finelli, Xavier Carrier, Gabriele Deplano, Margherita Cavallo, Elsje Alessandra Quadrelli, Juliette Michel, Marie-Hélène Pietraru, Clément Camp, Giulia Forghieri, Anna Gagliardi, Sebastian Seidel, Antoine Missemer, Bertrand Reuillard, Barbara Centrella, Silvia Bordiga, María Grace Salamanca González, Vincent Artero, Keanu V. A. Birkelbach, Niklas von Wolff

At the energy-chemistry nexus, key molecules include carbon dioxide (CO2), hydrogen (H2), methane (CH4), and ammonia (NH3). The position of these four molecules and that of the more general family of synthetic macromolecular polymer blends (found in plastics) were cross-analyzed with the planetary…

Chemical Science, 2024, 15, pp.9054-9086. ⟨10.1039/d4sc00099d⟩. ⟨hal-04611454⟩

  • Communication dans un congrès

Effect of different substrates on heterologous production of a fungal laccase in a recombinant strain of Yarrowia lipolytica

Catherine Madzak, M Moradi, Farshad Darvishi, Claude Jolivalt

Effect of different substrates on heterologous production of a fungal laccase in a recombinant strain of Yarrowia lipolytica. 16. International and Iranian Congress of Microbiology

16. International and Iranian Congress of Microbiology, Aug 2015, Téhéran, Iran. ⟨hal-01535367⟩

  • Article dans une revue

Adsorption of a chiral modifier on an oxide surface: Chemical nature of tartaric acid on rutile TiO2 (110)

E. Meriggio, R. Lazzari, S. Chenot, P. David, C. Methivier, X. Carrier, G. Cabailh, V. Humblot

Tartaric acid (TA) is one of the most known chiral modifier used in heterogeneous enantioselective catalysis and understanding how it interacts with oxide supports is of significant importance for the design of efficient supported metal catalysts. This work presents a detailed surface science…

Applied Surface Science, 2019, 493, pp.1134-1141. ⟨10.1016/j.apsusc.2019.07.143⟩. ⟨hal-02340234⟩

  • Article dans une revue

Synthesis of supported ZSM-5 nanoparticles

Olfa Ben Moussa, Ilef Borghol, David Hu, Sandra Casale, Yannick Millot, Celine Sayag, Juliette Blanchard, Olivier Durupthy

The influence of the support on the nucleation of ZSM-5 nanoparticles has been studied for three supports: γ-alumina, zirconia and carbon nanotubes (CNT). While zeolite nucleation was suppressed in presence of alumina and strongly delayed in presence of zirconia, it occurred without delay in…

Microporous and Mesoporous Materials, 2019, 287, pp.177-182. ⟨10.1016/j.micromeso.2019.05.063⟩. ⟨hal-02340122⟩