• Article dans une revue

Metallomics in deep time and the influence of ocean chemistry on the metabolic landscapes of Earth's earliest ecosystems

Keyron Hickman-Lewis, Barbara Cavalazzi, Stéphanie Sorieul, Pascale Gautret, Frédéric Foucher, Martin Whitehouse, Heejin Jeon, Thomas Georgelin, Charles Cockell, Frances Westall

Modern biological dependency on trace elements is proposed to be a consequence of their enrichment in the habitats of early life together with Earth's evolving physicochemical conditions; the resulting metallic biological complement is termed the metallome. Herein, we detail a protocol for…

Scientific Reports, 2020, ⟨10.1038/s41598-020-61774-w⟩. ⟨insu-02511006⟩

• Article dans une revue

Influence of Coadsorbed Water and Alcohol Molecules on Isopropyl Alcohol Dehydration on γ-Alumina: Multiscale Modeling of Experimental Kinetic Profiles

Kim Larmier, Andre Nicolle, Céline Chizallet, Nicolas Cadran, Sylvie Maury, Anne-Félicie Lamic-Humblot, Eric Marceau, Hélène Lauron-Pernot

Successfully modeling the behavior of catalytic systems at different scales is a matter of importance not only for a fundamental understanding but also for a more rational design of catalysts and a more precise definition of the kinetic laws used as inputs in chemical engineering. We have developed…

ACS Catalysis, 2016, 6 (3), ⟨10.1021/acscatal.6b0008⟩. ⟨hal-01564196⟩

• Communication dans un congrès

Intérêt des revêtements N-halamines dans la lutte contre le développement des bactéries et du biofilm

Catherine Debiemme-Chouvy, Shan Gao, Hubert Cachet, Nadia Nazi, Vincent Humblot

L’enrayement du développement des biofilms ou de la prolifération de bactéries pathogènes est indispensable aussi bien pour des raisons de santé publique que pour des raisons économiques. Pour les milieux hydriques, à ces fins, des biocides oxydants sont fréquemment employés. Ils sont alors ajoutés…

Matériaux 2018, FFM; Société Chimique de France (SCF), Nov 2018, Strasbourg (67), France. ⟨hal-03978791⟩

• Article dans une revue

Ga(Nb,Ta)SiBEA zeolites prepared by two-step postsynthesis method: acid–base characteristics and catalytic performance in the dehydrogenation of propane to propylene with CO2

S. Orlyk, M. Kantserova, V. Chedryk, P. Kyriienko, D. Balakin, Y. Millot, S. Dzwigaj

Ga(Ta,Nb)SiBEA zeolites with Ta(V), Nb(V) and Ga(III)-single sites were prepared by two-step post-synthesis preparation procedure as evidenced by X-ray Diffraction, Fourier Transform Infrared Spectroscopy (FT–IR), 71Ga Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy and X-ray…

Journal of Porous Materials, 2021, 28 (5), pp.1511-1522. ⟨10.1007/s10934-021-01099-9⟩. ⟨hal-03995330⟩

• Article dans une revue

Supported Cu Nanoparticles as Selective and Stable Catalysts for the Gas Phase Hydrogenation of 1,3-Butadiene in Alkene-Rich Feeds

Giorgio Totarella, Rolf Beerthuis, Nazila Masoud, Catherine Louis, Laurent Delannoy, Petra de Jongh

Supported copper nanoparticles are a promising alternative to supported noble metal catalysts, in particular for the selective gas phase hydrogenation of polyunsaturated molecules. In this article, the catalytic performance of copper nanoparticles (3 and 7 nm) supported on either silica gel or…

Journal of Physical Chemistry C, 2021, 125 (1), pp.366-375. ⟨10.1021/acs.jpcc.0c08077⟩. ⟨hal-03995579⟩

• Communication dans un congrès

APPIMIL Project: photonic and particle irradiation experiments at the CNRS Orléans and their relevance to BIOMEX and ExoMars

F. Foucher, T. Georgelin, T. Sauvage, A. Canizares, P. de Vera J.-P., M. Baqué, V. Lago, R. Joussot, Sunil Simon, R. Gay, P. Koumba-Ibala, N. Gouillon, K. Hickman-Lewis, A. Bellamy, F. Westall

BIOMEX Closing Ceremony Meeting at DLR, Mar 2019, Berlin, Germany. ⟨hal-03089550⟩

• Thèse

Conception raisonnée de catalyseurs bifonctionnels : élaboration de catalyseurs Pt0/zéolithe-Alumine, Rational design of bifunctional catalysts : development of Pt0/zeolithe-alumina catalysts

Olfa Ben Moussa

Les catalyseurs bifonctionnels pour l’hydrocraquage nécessitent à la fois des sites acides de Brønsted et des sites métalliques. L’intimité entre sites acides et sites métalliques peut donc influer sur l’activité et la sélectivité de la réaction. Nous nous sommes proposés d’explorer l’effet de la…, Bifunctional hydrocracking catalysts require both Brønsted acid sites and metal sites. Hence, the intimacy between acid sites and metal sites can influence the activity and selectivity of the reaction. We intended to explore the effect of metal sites-acid sites distance on the conversion of n-…

Chimie-Physique [physics.chem-ph]. Université Pierre et Marie Curie - Paris VI, 2016. Français. ⟨NNT : 2016PA066700⟩. ⟨tel-01629059⟩

• Thèse

Preparation of amorphous silica-aluminas with enhanced acidic properties and spectroscopic identification of their acid sites, Préparation de silice-alumines amorphes avec des propriétés acides améliorées et identification spectroscopique de leurs sites acides

Xiaojing Jin

ASAs with enhanced acidity and a higher fraction of acidic Al were prepared by two experimental strategies. Their textures have been investigated by N2 adsorption–desorption and their acidic properties by FTIR of adsorbed probe molecule (pyridine or CO). Besides, isomerization of 33DMB1 was…, Des silice-alumines (SA) avec des propriétés acides améliorées et une fraction plus élevée d’aluminium acides ont été préparées en utilisant deux stratégies de synthèse. Leurs propriétés texturales ont été étudiées par physisorption de N2 et leurs propriétés acides par suivi FTIR de l’adsorption de…

Catalysis. Université Pierre et Marie Curie - Paris VI, 2017. English. ⟨NNT : 2017PA066355⟩. ⟨tel-02334604⟩

• Article dans une revue

Effect of postsynthesis preparation procedure on the state of copper in CuBEA zeolites and its catalytic properties in SCR of NO with NH3

Rafal Baran, Frederic Averseng, Dominik Wierzbicki, Karolina Chalupka, Jean-Marc Krafft, Teresa Grzybek, Stanislaw Dzwigaj

Copper-containing BEA zeolites, Cu2.0SiBEA and Cu2.0HAlBEA, with 2 wt % of Cu were prepared by a two-step postsynthesis method and a conventional wet impregnation, respectively. These zeolites were characterized by XRD, DR UV–vis, EPR, FTIR and TPR physicochemical techniques. The incorporation of…

Applied Catalysis A : General, 2016, 523 pp.332-342. ⟨10.1016/j.apcata.2016.06.008⟩. ⟨hal-01329581⟩

• Article dans une revue

Cation redistribution upon dehydration of Na 58 Y faujasite zeolite: a joint neutron diffraction and molecular simulation study

Wilfried Louisfrema, Benjamin Rotenberg, Florence Porcher, Jean-Louis Paillaud, Pascale Massiani, Anne Boutin

Using neutron scattering and Monte Carlo simulation, we investigate the distribution of cations in Na58Y faujasite upon (de)hydration. We introduce a new method for the assignment of cations to specific sites in molecular simulations from their local environment. This allows us to bypass the need…

Molecular Simulation, 2015, 41 (16-17), pp.1371-1378. ⟨10.1080/08927022.2015.1027889⟩. ⟨hal-01284815⟩