• Article dans une revue

Thermodynamic brønsted basicity of clean MgO surfaces determined by their deprotonation ability: Role of Mg2+–O2 pairs

Céline Chizallet, Marie Laurence Bailly, Guylène Costentin, Hélène Lauron-Pernot, Jean Marc Krafft, Philippe Bazin, Jacques Saussey, Michel Che

The deprotonation ability of clean (i.e., carbonate- and hydroxyl-free) MgO surfaces of various morphologies towards protic molecules, such as propyne and methanol, is evaluated by following the adsorption modes and amount of dissociated species by FTIR. Photoluminescence is used to identify the…

Catalysis Today, 2006, 116, pp.196-205. ⟨10.1016/j.cattod.2006.01.030⟩. ⟨hal-00112162⟩

• Article dans une revue

Carbon black composites—supports of HDS catalysts

P. Gheek, S. Suppan, J. Trawczynski, A. Hynaux, Celine Sayag, G. Djéga-Mariadassou

HDS activity of sulfided Mo (W) catalysts supported on carbon black composites (CBC) is affected by kind of functional groups present on the CBC surface. Oxidation of CBC with (NH4)2S2O8 produce functionalities with the highest acid strength and corresponding catalyst exhibits the highest HDS…

Catalysis Today, 2006, 119, pp.19-22. ⟨10.1016/j.cattod.2006.08.026⟩. ⟨hal-00128078⟩

• Article dans une revue

Hydrodesulfurization of dibenzothiophene on MoS2/MCM-41 and MoS2/SBA 15 catalysts prepared by thermal spreading of MoO3.

A. Sampieri-Croda, Stéphane Pronier, Joël Blanchard, Michèle Breysse, Sylvette Brunet, Katia Fajerwerg, C. Louis, Guy Perot

Catalysis Today, 2005, 107-108, pp.537-544. ⟨10.1016/j.cattod.2005.07.069⟩. ⟨hal-00288833⟩

• Article dans une revue

1H MAS NMR study of the coordination of hydroxyl groups generated upon adsorption of H2O and CD3OH on clean MgO surfaces

Céline Chizallet, Guylène Costentin, Hélène Lauron-Pernot, Jocelyne Maquet, Michel Che

The coordination of OH groups on MgO has been characterized by 1H MAS NMR after appropriate pre-treatment conditions to obtain surfaces free from carbonates and with a controlled degree of hydroxylation. On MgO-sol–gel sample treated at 1023 K under flowing nitrogen, hydroxylated with water and…

Applied Catalysis A : General, 2006, 307, pp.239-244. ⟨10.1016/j.apcata.2006.03.056⟩. ⟨hal-00112138⟩

• Communication dans un congrès

Mechanochemical preparation of nanostructured mixed oxide catalysts for selective oxidation reactions

Sabine Valange, Ronan Behling, Gregory Chatel, Franck Launay

4th International Conference on Advanced Complex Inorganic Nanomaterials, Jul 2018, Namur, Belgium. ⟨hal-02002188⟩

• Article dans une revue

Ionic liquid redox flow membraneless battery in microfluidic system

Nesrine Chaabene, Kieu Ngo, Mireille Turmine, Vincent Vivier

Redox flow batteries (RFBs) often require the presence of a physical membrane to separate the two compartments of the battery. The objective of this work is to develop a membraneless microfluidic redox flow battery (RFB) by using 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (…

Journal of Energy Storage, 2023, 57, pp.106270. ⟨10.1016/j.est.2022.106270⟩. ⟨hal-04775517⟩

• Article dans une revue

Evidence of Pd segregation and stabilization at edges of AuPd nano-clusters in the presence of CO: A combined DFT and DRIFTS study

Beien Zhu, Gode Thrimurthulu, Laurent Delannoy, Catherine Louis, Christine Mottet, Jerome Creuze, Bernard Legrand, Hazar Guesmi

Combined Density Functional Theory (DFT) calculations and Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) were performed to study the distribution of Pd atoms in bimetallic AuPd nanoparticles in the presence of adsorbed CO. Compared to vacuum condition, the results showed…

Journal of Catalysis, 2013, 308, pp.272-281. ⟨10.1016/j.jcat.2013.08.022⟩. ⟨hal-03184658⟩

• Article dans une revue

Integrated stopped-flow device for the study of porous materials using hyperpolarized $^{129}$Xe NMR

Jing Li, Estelle Léonce, Corentin Coutellier, Céline Boutin, Kévin Chighine, Charles Rivron, Anne Davidson, Patrick Berthault

A simple, low-cost, and efficient device is proposed for the study of porous materials via NMR using small gas probes. Mainly built through additive manufacturing and being equipped with a radiofrequency solenoid microcoil, it only requires tiny quantities of sample and/or gas and is particularly…

Analytical Chemistry, 2024, ⟨10.1021/acs.analchem.4c00490⟩. ⟨cea-04596570⟩

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Halide Ligands to Release Strain in Cadmium Chalcogenide Nanoplatelets and Achieve High Brightness

Marion Dufour, Junling Qu, Charlie Gréboval, Christophe Méthivier, Emmanuel Lhuillier, Sandrine Ithurria

Zinc blende II-VI semiconductor nanoplatelets (NPLs) are defined at the atomic scale along the thickness of the nanoparticle and are initially capped with carboxylates on the top and bottom [001] facets. These ligands are exchanged on CdSe NPLs with halides that act as X-L-type ligands. These CdSe…

ACS Nano, 2019, ⟨10.1021/acsnano.8b09794⟩. ⟨hal-02099454⟩

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When RNA meets montmorillonite: Influence of the pH and divalent cations

Luís de Oliveira, Pollyana Trigueiro, Baptiste Rigaud, Edson da Silva-Filho, Josy Osajima, Maria Fonseca, Jean-François Lambert, Thomas Georgelin, Maguy Jaber

Applied Clay Science, 2021, 214, pp.106234. ⟨10.1016/j.clay.2021.106234⟩. ⟨hal-03990019⟩