Laboratoire de réactivité de surface

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  • Article dans une revue

Enhanced selectivity of 3-D ordered macroporous Pt/Al2O3 catalysts in nitrites removal from water

A.C. Sunil Sekhar, A. Zaki, S. Troncea, S. Casale, C.P. Vinod, J.P. Dacquin, P. Granger

Tailored macroporous mesoporous alumina supports have been successfully prepared using a single hard templating approach. Pt nanoparticles, showing similar physico-chemical properties, were homogeneously dispersed throughout the different alumina frameworks as catalytic active phase for drinking…

Applied Catalysis A : General, 2018, 564, pp.26-32. ⟨10.1016/j.apcata.2018.07.014⟩. ⟨hal-03984216⟩

  • Article dans une revue

Stability of Binary SAMs Formed by omega-Acid and Alcohol Functionalized Thiol Mixtures

Frederik Tielens, Vincent Humblot, Claire-Marie Pradier, Monica Calatayud, Francesc Illas

A simple model is presented to describe the mixing process of acid- and alcohol-terminated thiol self-assembled monolayers (SAMs) on Au(111). It was found that the low-concentration acid-terminated SAMs are enriched in acid thiol compared with the original solution from which the SAM is made. Due…

Langmuir, 2009, 25 (17), pp.9980-9985. ⟨10.1021/la901127g⟩. ⟨hal-01361365⟩

  • Article dans une revue

Ethanol Conversion into 1,3-Butadiene by Lebedev Method over MTaSiBEA Zeolites (M= Ag, Cu, Zn)

Pavlo I. Kyriienko, Olga V. Larina, Sergiy O. Soloviev, Svitlana M. Orlyk, Christophe Calers, Stanislaw Dzwigaj

Tantalum-containing SiBEA zeolite with isolated framework mononuclear Ta(V) doped with Ag, Cu and Zn were prepared and characterized by XRD, XPS, DR UV-VIS and FTIR (with pyridine, 2,6-di-tert-butylpyridine, pyrrole and deuterated chloroform). The conversion of ethanol as renewable raw material…

ACS Sustainable Chemistry & Engineering, 2017, ⟨10.1021/acssuschemeng.6b01728⟩. ⟨hal-01437547⟩

  • Article dans une revue

Design of TiO2/Au nanoparticle films with controlled crack formation and different architectures using a centrifugal strategy

Abdelhafed Taleb, Frederic Mesguich, Thomas Onfroy, Xue Yanpeng

Here we present an approach to design hybrid nanocomposite films based on TiO2/Au nanoparticles using centrifugation processes. The prepared nanocomposite films have been characterized by different techniques such as FEGSEM, TEM, BET and XRD. Furthermore it is demonstrated that centrifugal force…

RSC Advances, 2015, 5 (10), pp.7007-7017. ⟨10.1039/C4RA13829E⟩. ⟨hal-01121614⟩

  • Article dans une revue

Synthesis of Well-Defined Dawson-Type Poly(N,N-diethylacrylamide) Organopolyoxometalates

Jennifer Lesage de la haye, Patricia Beaunier, Laurent Ruhlmann, Bernold Hasenknopf, Emmanuel Lacôte, Jutta Rieger

An organotin-substituted Dawson-type phosphotungstate was covalently linked to a trithiocarbonate group by postfunctionalization methods. This organopolyoxometalate led to a series of polyoxometalate (POM)–poly(N,N-diethylacrylamide) hybrids in a controlled way through reversible addition–…

ChemPlusChem, 2014, 79 (2), pp.250-256. ⟨10.1002/cplu.201300346⟩. ⟨hal-01121569⟩

  • Article dans une revue

Building of an immunosensor : how can the composition and structure of the thiol attachment layer affect the immunosensor efficiency ?

Elisabeth Briand, Michèle Salmain, Jean-Marie Herry, Hubert Perrot, Chantal Compere, Claire-Marie Pradier

Immunosensors, based on the immobilsation of model rabbit antibodies on a mixed self assembled monolyaers and Protein A as a linking agent on gold transducers, were elaborated and characterised at each step by Modulated polarisation- Infrared Spectroscopy (PM-IRRAS) and punctually by Atomic Force…

Biosensors and Bioelectronics, 2006, 22 (3), pp.440-448. ⟨10.1016/j.bios.2006.05.018⟩. ⟨hal-00111673⟩

  • Article dans une revue

Enhancing low-temperature activity and durability of Pd-based diesel oxidation catalysts using ZrO2 supports

Mi-Young Kim, Eleni A. Kyriakidou, Jae-Soon Choi, Todd J. Toops, Andrew J. Binder, Cyril Thomas, James E. Parks, Viviane Schwartz, Jihua Chen, Dale K. Hensley

We investigated the impact of ZrO2 on the performance of palladium-based oxidation catalysts with respect to low-temperature activity, hydrothermal stability, and sulfur tolerance. Pd supported on ZrO2 and SiO2 were synthesized for a comparative study. Additionally, in an attempt to maximize the…

Applied Catalysis B: Environmental, 2016, 187, pp.181-194. ⟨10.1016/j.apcatb.2016.01.023⟩. ⟨hal-01264140⟩

  • Article dans une revue

In-situ monitoring of transition metal complex adsorption on oxide surfaces during the first stages of supported metal catalyst preparation

Juliette Blanchard, Antoine Hervier, Guylène Costentin, John Regalbuto, Catherine Louis, Souhir Boujday

In the preparation of supported catalysts by deposition, in solution, of a transition metal complex (TMC) on an oxide support, the interactions occurring at the solid/liquid interface between the TMC and the oxide have a crucial impact on the properties of the final catalyst. However, these…

Catalysis Today, 2014, 235, pp.245-249. ⟨10.1016/j.cattod.2014.03.031⟩. ⟨hal-01077975⟩

  • Article dans une revue

Tuning the shape and size of hybrid gold nanoparticles by porphyrins using seed-mediated synthesis

Jolanda Spadavecchia, Sandra Casale, Jessem Landoulsi, Claire-Marie Pradier

We report the synthesis of hybrid gold nanostructures by means of seed/growth approach, using porphyrin molecules (protoporphyrin IX) in addition to cetyltetraammonium bromide (CTAB) as surfactants and/or shape-modulating agents. The combination of CTAB and porphyrin yields stable complexes that…

Chemical Physics Letters, 2014, 609, pp.134-141. ⟨10.1016/j.cplett.2014.06.008⟩. ⟨hal-01078002⟩

  • Article dans une revue

Production of Laccase by Recombinant Yarrowia lipolytica from Molasses: Bioprocess Development Using Statistical Modeling and Increase Productivity in Shake-Flask and Bioreactor Cultures

Farshad Darvishi, Marzieh Moradi, Catherine Madzak, Claude Jolivalt

Laccases are used in numerous applications, from green degradation of various xenobiotic compounds, waste detoxification, textile dye bleaching, and delignification of lignocellulose materials to biofuel production. In this study, the recombinant Yarrowia lipolytica YL4 strain carrying the white-…

Applied Biochemistry and Biotechnology, 2017, 181 (3), ⟨10.1007/s12010-016-2280-8⟩. ⟨hal-01531721⟩