• Article dans une revue

Synthesis of small Ni-core–Au-shell catalytic nanoparticles on TiO2 by galvanic replacement reaction

Julien Reboul, Z. y Li, Jun Yuan, Kazuki Nakatsuka, Masakazu Saito, Kohsuke Mori, Hiromi Yamashita, Yu Xia, Catherine Louis

We report the first preparation of small gold–nickel (AuNi) bimetallic nanoparticles (<5 nm) supported on titania by the method of galvanic replacement reaction (GRR), evidenced by the replacement of Ni atoms by Au atoms according to the stoichiometry of the reaction. We showed that this…

Nanoscale Advances, 2021, ⟨10.1039/d0na00617c⟩. ⟨hal-03113238⟩

• Poster de conférence

Bimetallic Fe-Ni/SiO2 catalysts for furfural hydrogenation: respective roles of Fe and Ni

Dichao Shi, Jean-Sébastien Girardon, Anne Constant, Anne-Sophie Mamede, Robert Wojcieszak, Paul Sébastien, E. Marceau, Anne-Félicie Lamic-Humblot, Maya Marinova, Valérie Briois, Lorenzo Stievano

ISGC 2019, International Symposium on Green Chemistry, May 2019, La Rochelle, France. ⟨hal-03515379⟩

• Chapitre d'ouvrage

Preparation of Pt°/MCM-41: effect of drying on MCM-41 structure and Pt° dispersion

Baichun Zhu, Franck Letellier, Juliette Blanchard, Katia Fajerwerg, Catherine Louis, Denis Guillaume, Denis Uzio, Miehèle Breysse

Pt°/MCM-41 catalysts were prepared by electrostatic adsorption of Pt(NH3)42+ at pH=8, followed by calcination under O2 and reduction. This procedure allows to prepare highly dispersed Pt° nanoparticles (D>76%), but has the drawback to modify significantly the structure of the ordered mesoporous…

E.M. Gaigneaux; M. Devillers; D.E. De Vos; S. Hermans; P.A. Jacobs; J.A. Martens; P. Ruiz. Scientific Bases for the Preparation of Heterogeneous Catalysts, 162, Elsevier, pp.449-456, 2006, Studies in Surface Science and Catalysis, 978-0-444-52827-8. ⟨10.1016/S0167-2991(06)80939-0⟩. ⟨hal-03663614⟩

• Communication dans un congrès

Physicochemical characterizations of ionic liquid-molecular solvents mixtures

Nesrine Chaabene, Kieu Ngo, Mireille Turmine

ISSP 2018, Jul 2018, Tours, France. ⟨hal-03977348⟩

• Article dans une revue

On-line inductively coupled plasma-atomic emission spectroelectrochemistry: Real-time element-resolved electrochemistry

Borhan Bin Mohamad Sultan, Oumaïma Gharbi, Kevin Ogle, Junsoo Han

Electrochemical techniques are coupled with inductively coupled plasma (ICP) atomic emission spectrometry for in-line electrolyte analyses. In this way, direct measurement of the elemental dissolution rates in real-time or element-resolved electrochemistry can be carried out, complementary to…

Current Opinion in Electrochemistry, 2023, 41, pp.101350. ⟨10.1016/j.coelec.2023.101350⟩. ⟨hal-04211090⟩

• Article dans une revue

Static and dynamic electronic characterization of organic monolayers grafted on a silicon surface

Olivier Pluchery, Y. Zhang, R. Benbalagh, L. Caillard, J. J. Gallet, F. Bournel, A.-F. Lamic-Humblot, M. Salmeron, Y. J. Chabal, F. Rochet

Organic layers chemically grafted on silicon offer excellent interfaces that may open up the way for new organic–inorganic hybrid nanoelectronic devices. However, technological achievements rely on the precise electronic characterization of such organic layers. We have prepared ordered grafted…

Physical Chemistry Chemical Physics, 2016, 18 (5), pp.3675-3684. ⟨10.1039/C5CP05943G⟩. ⟨hal-01262800⟩

• Article dans une revue

Cellulose fibers modification through metal-free click chemistry for the elaboration of versatile functional surfaces

Alex Meye Biyogo, Louise Hespel, Vincent Humblot, Laurent Lebrun, François Estour

European Polymer Journal, 2020, 135, pp.109866. ⟨10.1016/j.eurpolymj.2020.109866⟩. ⟨hal-02907151⟩

• Article dans une revue

Scanning Electrochemical Microscopy for Investigating Gas Bubble/Liquid Interfaces

Claude Gabrielli, François Huet, Michel Keddam, Philippe Rousseau, Vincent Vivier

Scanning electrochemical microscopy was used to characterize air bubble/electrolyte interfaces for bubbles of diameter in the millimeter range. Contrary to rigid insulated substrate/liquid interfaces, the approach of the tip of the microelectrode was shown to lead to a deformation of the bubble…

Electrochemical and Solid-State Letters, 2003, 6 (10), pp.E23. ⟨10.1149/1.1604971⟩. ⟨hal-04219330⟩

• Article dans une revue

Unraveling the Direct Decomposition of NO x over Keggin Heteropolyacids and Their Deactivation Using a Combination of Gas-IR/MS and In Situ DRIFT Spectroscopy

Josefine Schnee, Laurent Delannoy, Guylène Costentin, Cyril Thomas

Keggin heteropolyacids (HPAs) have been known to be efficient NOx absorbers for many years, and to decompose a significant fraction of the NOx species pre-absorbed at 100-150 °C into harmless N2 and O2 upon rapid heating to 450 °C. However, this capability of Keggin HPAs to directly decompose NOx…

Journal of Physical Chemistry C, In press, ⟨10.1021/acs.jpcc.0c05945⟩. ⟨hal-02960399⟩

• Article dans une revue

Stability of Binary SAMs Formed by omega-Acid and Alcohol Functionalized Thiol Mixtures

Frederik Tielens, Vincent Humblot, Claire-Marie Pradier, Monica Calatayud, Francesc Illas

A simple model is presented to describe the mixing process of acid- and alcohol-terminated thiol self-assembled monolayers (SAMs) on Au(111). It was found that the low-concentration acid-terminated SAMs are enriched in acid thiol compared with the original solution from which the SAM is made. Due…

Langmuir, 2009, 25 (17), pp.9980-9985. ⟨10.1021/la901127g⟩. ⟨hal-01361365⟩