Laboratoire de réactivité de surface

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  • Thèse

Emergence de biopolymères de complexite contrôlée dans les scénarios d'origine de la vie, Emergence of biopolymers with controlled complexity in an origins of life scenario

Lise Bedoin

La matière vivante se caractérise par la présence de biopolymères non aléatoires dont la fonction biologique dépend de la séquence en monomères. Pour comprendre les origines de la vie, il est essentiel d’expliquer l’émergence de polymères non aléatoires dans un monde où les cellules vivantes n’…, Living matter is characterized by the presence of non-random biopolymers whose biological function depends on the monomer sequence. Thus, a major challenge for the elucidation of the Origins of Life lies in understanding how non-random polypeptides were formed and selected among all of the possible…

Polymères. Sorbonne Université, 2021. Français. ⟨NNT : 2021SORUS229⟩. ⟨tel-03475214⟩

  • Article dans une revue

Electrochemistry of a new carbon-rich fluorine-doped tin oxide (CFTO) material as a powder electrode in chloride electrolytes

Chantal Cachet, Hubert Cachet, B Jousseaume, T Toupance, Vincent Vivier

The electrochemical behavior of a conductive carbon-rich fluorine-doped tin oxide (CFTO) powder synthesized via the sol–gel process was investigated by studying the chloride oxidation reaction in aqueous media with the help of a cavity microelectrode (CME) without any binding additive. This new…

Electrochimica Acta, 2002, 47 (9), pp.1385-1394. ⟨10.1016/S0013-4686(01)00873-8⟩. ⟨hal-04228572⟩

  • Article dans une revue

The Impact of Reduction Temperature and Nanoparticles Size on the Catalytic Activity of Cobalt-Containing BEA Zeolite in Fischer–Tropsch Synthesis

Karolina A Chalupka, Jacek Grams, Pawel Mierczynski, Malgorzata I Szynkowska, Jacek Rynkowski, Thomas Onfroy, Sandra Casale, Stanislaw Dzwigaj

A goal of this work was to investigate the influence of the preparation procedure and activation conditions (reduction temperature and reducing medium: pure hydrogen (100% H 2) or hydrogen-argon mixture (5% H 2-95% Ar)) on the activity of Co-containing BEA zeolites in Fischer-Tropsch synthesis.…

Catalysts, 2020, 10 (5), pp.553. ⟨10.3390/catal10050553⟩. ⟨hal-03987087⟩

  • Article dans une revue

Tunable hierarchical porous silica materials using hydrothermal sedimentation-aggregation technique

Abdelali Zaki, Jing Xu, Grégory Stoclet, Sandra Casale, Jean-Philippe Dacquin, Pascal Granger

Herein, a simple and efficient synthesis based on a dual templating approach allow the preparation of tunable macroporous mesoporous silica materials. Macropores incorporation has been obtained using polymer spheres of well-defined size and their subsequent removal by thermal treatment allowed the…

Microporous and Mesoporous Materials, 2015, Microporous and Mesoporous Materials, 208, pp.140-151. ⟨10.1016/j.micromeso.2015.01.041⟩. ⟨hal-03033078⟩

  • Article dans une revue

How to determine IR molar absorption coefficients of co-adsorbed species? Application to methanol adsorption for quantification of MgO basic sites

Béatrice Moulin, Laetitia Oliviero, Philippe Bazin, Marco Daturi, Guylène Costentin, Françoise Maugé

Methanol adsorption on MgO samples with different morphologies is studied by infrared (IR) spectroscopy coupled to volumetry or thermogravimetry measurements to probe qualitatively and quantitatively the acid-base paired sites. The molar absorption coefficients of [small nu](OC) vibration of non-…

Physical Chemistry Chemical Physics, 2011, 13 (22), pp.10797-10807. ⟨10.1039/C0CP02767G⟩. ⟨hal-00639308⟩

  • Article dans une revue

Total Oxidation of Methane on Oxide and Mixed Oxide Ceria-Containing Catalysts

Marius Stoian, Vincent Rogé, Liliana Lazar, Thomas Maurer, Jacques C Védrine, Ioan-Cezar Marcu, Ioana Fechete

Methane, discovered in 1766 by Alessandro Volta, is an attractive energy source because of its high heat of combustion per mole of carbon dioxide. However, methane is the most abundant hydrocarbon in the atmosphere and is an important greenhouse gas, with a 21-fold greater relative radiative…

Catalysts, 2021, 11 (4), pp.427. ⟨10.3390/catal11040427⟩. ⟨hal-03236104⟩

  • Article dans une revue

Importance, features and uses of metal oxide catalysts in heterogeneous catalysis

Jacques C. Védrine

This short review paper aims at assembling the present state of the art of the multiuses of metal oxides in heterogeneous catalysis, concerning liquid and gaseous phases of the reactant mixtures on solid catalysts. It includes the description of the main types of metal oxide catalysts, of their…

Chinese Journal of Catalysis, 2019, 40 (11), pp.1627-1636. ⟨10.1016/S1872-2067(18)63162-6⟩. ⟨hal-02405087⟩

  • Article dans une revue

Cobalt on dealuminated-Siβ as a catalyst for the oxidative dehydrogenation of propane

Stanislaw Dzwigaj, Diane Reja, Saremblé Koné-Guira, Antoine Miche, Guylène Costentin, Cyril Thomas

The present work aims at investigating the oxidative dehydrogenation of propane (ODHP) catalytic properties of Co species supported on a Siβ zeolitic support. The Co2+ species incorporated in the silanol nests created by dealumination of a HAlSiβ pristine support (Co-Siβ) appeared to be about 4…

Applied Catalysis A : General, 2023, 657, pp.119119. ⟨10.1016/j.apcata.2023.119119⟩. ⟨hal-04193203⟩

  • Thèse

Approche moléculaire de la synthèse et du mode de fonctionnement d’hydroxyapatites au cobalt : application à l’activation sélective du propane, Molecular approach to the synthesis and operation of cobalt hydroxyapatites : application to the selective activation of propane

Corentin Reynaud

L'hydroxyapatite (HAp) est un matériau bio et écocompatible dont l'attrait en catalyse hétérogène vient de la possibilité de moduler ses propriétés physico-chimiques par la synthèse. En particulier, sa modification par des métaux de transition permet de lui conférer des propriétés redox…, Hydroxyapatite (HAp) is a bio and eco-compatible material whose attractiveness in heterogeneous catalysis comes from the possibility to modulate its physicochemical properties by synthesis. In particular, its modification by transition metals allows to confer redox properties to make it a…

Chimie inorganique. Sorbonne Université, 2022. Français. ⟨NNT : 2022SORUS354⟩. ⟨tel-04268999⟩

  • Thèse

Surface characterizations to investigate osteoarticular mesenchymal tissues : new insights to monitor the extracellular matrix remodeling at the supramolecular level, Caractérisations de surface pour étudier les tissus mésenchymateux ostéoarticulaires : nouvelles perspectives pour surveiller le remodelage de la matrice extracellulaire au niveau supramoléculaire

Ilhem Lilia Jaabar

A connective tissue is a cooperative set of differentiated cells entangled in an extracellular matrix (ECM). The latter, which is particularly abundant, is composed mainly of proteins, such as collagens, and a viscous gel made up of water and negatively charged polysaccharides: proteoglycans. All…, Un tissu conjonctif est un ensemble coopératif de cellules différenciées enchevêtrées dans une matrice extracellulaire (ECM). Cette dernière, particulièrement abondante, se compose principalement de protéines, telles que les collagènes, et d'un gel visqueux constitué d'eau et de…

Rhumatology and musculoskeletal system. Sorbonne Université, 2022. English. ⟨NNT : 2022SORUS145⟩. ⟨tel-04099571⟩