• Article dans une revue

Elaboration, activity and stability of silica-based nitroaromatic sensors

D. Mercier, Franck Pereira, Christophe Méthivier, Pierre Montméat, Lionel Hairault, Claire-Marie Pradier

Functionalized silica-based thin films, modified with hydrophobic groups, were synthesized and used as sensors for nitroaromatic compound (NAC) specific detection. Their performance and behavior, in terms of stability, ageing and regeneration, have been fully characterized by combining chemical…

Physical Chemistry Chemical Physics, 2013, 15, pp.12911--12919. ⟨10.1039/C3CP43406K⟩. ⟨hal-00918578⟩

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Control of particle size via chemical composition: Structural and magnetic characterization of Ni–Co alloy nanoparticles encapsulated in lamellar mixed oxides

K.A. Tarasov, V.P. Isupov, B.B. Bokhonov, Yu.A. Gaponov, B.P. Tolochko, M.M. Yulikov, V.F. Yudanov, A. Davidson, P. Beaunier, E. Marceau, M. Che

Microporous and Mesoporous Materials, 2008, 107 (1-2), pp.202-211. ⟨10.1016/j.micromeso.2007.05.026⟩. ⟨hal-03032180⟩

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Adsorption and thermal condensation mechanisms of amino acids on oxide supports : I. Glycine on silica

Ming Meng, Lorenzo Stievano, Jean-François Lambert

Glycine was adsorbed on the surface of a well-defined silica from aqueous solutions of variable concentrations and pHs. The adsorbed molecules were characterized using middle-IR and UV-vis-NIR spectroscopies. Except at the lowestpH(2.0), they were predominantly present on the surface as zwitterions…

Langmuir, 2004, 20, pp.914-923. ⟨hal-00022081⟩

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Improved activity and stability in CO oxidation of bimetallic Au-Cu/TiO2 catalysts prepared by deposition-precipitation with urea

A. Sandoval, Catherine Louis, Rodolfo Zanello

Au-Cu bimetallic catalysts supported on TiO2 were prepared for the first time by sequential deposition-precipitation with the urea method, copper first then gold. Au-Cu catalysts with four different Au:Cu atomic ratios were synthesized (1:0.4 to 1:1.2). This method allowed quantitative deposition…

Applied Catalysis B: Environmental, 2013, 140-141, pp.363-377. ⟨10.1016/j.apcatb.2013.04.039⟩. ⟨hal-00911705⟩

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On the origin of the optimum loading of Ag on Al2O3 in the C3H6-SCR of NOx

Tesnim Chaieb, Laurent Delannoy, Catherine Louis, Cyril Thomas

Ag/Al2O3 catalysts synthesized by the common impregnation technique with various Ag loadings were characterized by the NOx-Temperature-Programmed Desorption (TPD) method and their catalytic performances were evaluated in the selective catalytic reduction of NOx by propene (C3H6-SCR). It was found…

Applied Catalysis B: Environmental, 2013, 142-143, pp.780-784. ⟨10.1016/j.apcatb.2013.06.010⟩. ⟨hal-00907584⟩

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Surface Segregation of Pd from TiO2-Supported AuPd Nanoalloys under CO Oxidation Conditions Observed In situ by ETEM and DRIFTS

Laurent Delannoy, Suzanne Giorgio, Jean-Gabriel Mattei, Claude R. Henry, Nadia El Kolli, Christophe M Éthivier, Catherine Louis

A TiO2-supported AuPd bimetallic catalyst with an Au/Pd atomic ratio of 8 was prepared by deposition-precipitation with urea, and its activity in CO oxidation at room temperature was compared to the one of a monometallic Au/TiO2 catalyst. X-ray photoelectron spectroscopy (XPS) and diffuse…

ChemCatChem, 2013, pp.1-11. ⟨10.1002/cctc.201200618⟩. ⟨hal-00836230⟩

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Origins of the deactivation process in the conversion of methylbutynol on zinc oxide monitored by operando DRIFTS

C. Drouilly, J.M. Krafft, F. Averseng, H. Lauron-Pernot, Delphine Bazer-Bachi, Céline Chizallet, V. Lecocq, G. Costentin

conversion reaction. The formation of acetone and acetylene is indicative of the basic properties of the zinc oxide surface. This basic catalyst, whose conversion level depends on the nature of the pre-treatment, was found to deactivate versus time on stream. Poisoning the basic sites by CO2 pre-…

Catalysis Today, 2012, 205, pp.67-75. ⟨10.1016/j.cattod.2012.08.011⟩. ⟨hal-00809404⟩

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Discrimination of infrared fingerprints of bulk and surface POH and OH of hydroxyapatites

Sarah Diallo-Garcia, Manel Ben Osman, Jean-Marc Krafft, Souhir Boujday, Guylene Costentin

The identification of the nature of the surface acid base pairs present on hydroxyapatites surface is a key point to rationalize their catalytic properties. To investigate the possible involvement of acidic protonated phosphate (POH) and/or of basic OH emerging from the channels, the spectroscopic…

Catalysis Today, 2014, 226, pp.81-88. ⟨10.1016/j.cattod.2013.11.041⟩. ⟨hal-00982290⟩

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Interaction of ZnII porphyrin with TiO2 nanoparticles: from mechanism to synthesis of hybrid nanomaterials.

Jolanda Spadavecchia, Christophe Méthivier, Jessem Landoulsi, Claire-Marie Pradier

The mechanism of interaction of Zn porphyrin (ZnPP) with TiO2 surfaces is investigated with a view to optimizing the synthesis of hybrid nanomaterials. The strategy consists of studying the adsorption of ZnPP on TiO2 flat surfaces by taking advantage of complementary surface characterization…

ChemPhysChem, 2013, 14, pp.2462-2469. ⟨10.1002/cphc.201300193⟩. ⟨hal-00983739⟩

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EPR Characterization and Reactivity of Surface-Localized Inorganic Radicals and Radical Ions

Mario Chiesa, Elio Giamello, Michel Che

A review. The role of surface inorg. radicals and radical ions formed at the interface between a solid and a gas phase was discussed. The formation of such species is relevant to field such as electrochem., heterogeneous catalysts, photocatalysis and corrosion. The characterization of these…

Chemical Reviews, 2010, 110 (3), pp.1320-1347. ⟨10.1021/cr800366v⟩. ⟨hal-00604710⟩