• Article dans une revue

Surface Science Approach to the Solid-Liquid Interface: Surface-Dependent Precipitation of Ni(OH)2 on a-Al2O3 Surfaces

Asma Tougerti, Isabelle Llorens, Francesco d'Acapito, Emiliano Fonda, Jean-Louis Hazemann, Yves Joly, Dominique Thiaudi Ère, Michel Che, Xavier Carrier

A molecular-scale understanding of the adsorption of metal ions on oxide surfaces is of fundamental importance for various scientific areas where the oxide/water interface plays a central role, such as corrosion science, preparation of heterogeneous catalysts, transport of contaminants in the…

Angewandte Chemie International Edition, 2012, 51, pp.7697-7701. ⟨10.1002/anie.201201349⟩. ⟨hal-00749941⟩

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Influence of the state of iron on CO oxidation on FeSiBEA zeolite catalysts

Izabela Hnat, Ireneusz Kocemba, Jacek Rynkowski, Thomas Onfroy, Stanislaw Dzwigaj

The influence of the state of iron on the catalytic properties of FexSiBEA zeolite in the oxidation of CO was investigated. Various FexSiBEA zeolites (x = 0.6, 1.0, 4.0 and 10 wt%) were prepared by a two-step post synthesis method. The presence of Fe(III) in tetrahedral coordination for low Fe…

Catalysis Today, 2011, 176, pp.229-233. ⟨10.1016/j.cattod.2010.12.052⟩. ⟨hal-00664469⟩

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A Time-Resolved In Situ Quick-XAS Investigation of Thermal Activation of Fischer-Tropsch Silica-Supported Cobalt Catalysts

Hong Jingping, Eric Marceau, Andrei Y. Khodakov, Anne Griboval-Constant, Fontaine C. La, V. Briois

Chemistry - A European Journal, 2012, 18, pp.2802-2805. ⟨10.1002/chem.201103509⟩. ⟨hal-00687092⟩

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Origins of the deactivation process in the conversion of methylbutynol on zinc oxide monitored by operando DRIFTS

C. Drouilly, J.M. Krafft, F. Averseng, H. Lauron-Pernot, Delphine Bazer-Bachi, Céline Chizallet, V. Lecocq, G. Costentin

conversion reaction. The formation of acetone and acetylene is indicative of the basic properties of the zinc oxide surface. This basic catalyst, whose conversion level depends on the nature of the pre-treatment, was found to deactivate versus time on stream. Poisoning the basic sites by CO2 pre-…

Catalysis Today, 2012, 205, pp.67-75. ⟨10.1016/j.cattod.2012.08.011⟩. ⟨hal-00809404⟩

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Surface Segregation of Pd from TiO2-Supported AuPd Nanoalloys under CO Oxidation Conditions Observed In situ by ETEM and DRIFTS

Laurent Delannoy, Suzanne Giorgio, Jean-Gabriel Mattei, Claude R. Henry, Nadia El Kolli, Christophe M Éthivier, Catherine Louis

A TiO2-supported AuPd bimetallic catalyst with an Au/Pd atomic ratio of 8 was prepared by deposition-precipitation with urea, and its activity in CO oxidation at room temperature was compared to the one of a monometallic Au/TiO2 catalyst. X-ray photoelectron spectroscopy (XPS) and diffuse…

ChemCatChem, 2013, pp.1-11. ⟨10.1002/cctc.201200618⟩. ⟨hal-00836230⟩

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Improved activity and stability in CO oxidation of bimetallic Au-Cu/TiO2 catalysts prepared by deposition-precipitation with urea

A. Sandoval, Catherine Louis, Rodolfo Zanello

Au-Cu bimetallic catalysts supported on TiO2 were prepared for the first time by sequential deposition-precipitation with the urea method, copper first then gold. Au-Cu catalysts with four different Au:Cu atomic ratios were synthesized (1:0.4 to 1:1.2). This method allowed quantitative deposition…

Applied Catalysis B: Environmental, 2013, 140-141, pp.363-377. ⟨10.1016/j.apcatb.2013.04.039⟩. ⟨hal-00911705⟩

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On the origin of the optimum loading of Ag on Al2O3 in the C3H6-SCR of NOx

Tesnim Chaieb, Laurent Delannoy, Catherine Louis, Cyril Thomas

Ag/Al2O3 catalysts synthesized by the common impregnation technique with various Ag loadings were characterized by the NOx-Temperature-Programmed Desorption (TPD) method and their catalytic performances were evaluated in the selective catalytic reduction of NOx by propene (C3H6-SCR). It was found…

Applied Catalysis B: Environmental, 2013, 142-143, pp.780-784. ⟨10.1016/j.apcatb.2013.06.010⟩. ⟨hal-00907584⟩

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Interaction of ZnII porphyrin with TiO2 nanoparticles: from mechanism to synthesis of hybrid nanomaterials.

Jolanda Spadavecchia, Christophe Méthivier, Jessem Landoulsi, Claire-Marie Pradier

The mechanism of interaction of Zn porphyrin (ZnPP) with TiO2 surfaces is investigated with a view to optimizing the synthesis of hybrid nanomaterials. The strategy consists of studying the adsorption of ZnPP on TiO2 flat surfaces by taking advantage of complementary surface characterization…

ChemPhysChem, 2013, 14, pp.2462-2469. ⟨10.1002/cphc.201300193⟩. ⟨hal-00983739⟩

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A simple thermodynamic approach to predict responses from polymer-coated quartz crystal microbalance sensors exposed to organic vapors.

P. Palmas, J. Klingenfus, A. Vedeau, E. Girard, P. Montméat, L. Hairault, C.M. Pradier, C. Methivier

As of lately, the demand for developing artificial sensors with improved capabilities for the detection of explosives, toxics or drugs has increased. Ideally, sensor devices should provide high sensitivity and give a response that is specific to a given target molecule without being influenced by…

Talanta, 2013, 115, pp.616-623. ⟨10.1016/j.talanta.2013.06.017⟩. ⟨hal-00958092⟩