Laboratoire de réactivité de surface

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  • Article dans une revue

Elaboration, activity and stability of silica-based nitroaromatic sensors

D. Mercier, Franck Pereira, Christophe Méthivier, Pierre Montméat, Lionel Hairault, Claire-Marie Pradier

Functionalized silica-based thin films, modified with hydrophobic groups, were synthesized and used as sensors for nitroaromatic compound (NAC) specific detection. Their performance and behavior, in terms of stability, ageing and regeneration, have been fully characterized by combining chemical…

Physical Chemistry Chemical Physics, 2013, 15, pp.12911--12919. ⟨10.1039/C3CP43406K⟩. ⟨hal-00918578⟩

  • Article dans une revue

Bimetallic Au-Ag/TiO2 catalyst prepared by deposition-precipitation: High activity and stability in CO oxidation

A. Sandoval, A. Aguilar, C. Louis, Agnes Traverse, Rodolfo Zanella

Au-Ag bimetallic catalysts supported on TiO2 were prepared by sequential deposition-precipitation method, silver first and then gold. Au-Ag catalysts with different Au/Ag atomic ratios were synthesized. XANES and H2 TPR results show that gold is more easily reduced in bimetallic catalysts than in…

Journal of Catalysis, 2011, 281, pp.40-49. ⟨10.1016/j.cat.2011.04.003⟩. ⟨hal-00666778⟩

  • Article dans une revue

The antibacterial activity of Magainin I immobilized onto mixed thiols Self-Assembled Monolayers

Vincent Humblot, Jean-Fabrice Yala, Pascal Thebault, Kada Boukerma, Arnaud Héquet, Jean-Marc Berjeaud, Claire-Marie Pradier

An antibacterial peptide, Magainin I, was covalently bound to a mixed 11-mercaptoundecanoïc acid (MUA) and 6-mercaptohexanol (C6OH) (ratio 1:3) Self-Assembled Monolayer (SAM) on gold surfaces. Each step of the surface functionalization was characterized by Polarization Modulation Reflection…

Biomaterials, 2009, 30 (21), pp.3503-3512. ⟨10.1016/j.biomaterials.2009.03.025⟩. ⟨hal-04435299⟩

  • Article dans une revue

A New Antibacterial N -Halamine Coating Based on Polydopamine

Nadia Nazi, Vincent Humblot, Catherine Debiemme

To prevent the formation of biofilms on material surfaces, the latter must have antibacterial properties. The aim of this study is to investigate the synthesis and the antibacterial effect of a new N-halamine coating based on polydopamine (PDA). The benefits of this coating are multiple, notably…

Langmuir, 2020, 36 (37), pp.11005-11014. ⟨10.1021/acs.Langmuir.0c01856⟩. ⟨hal-02981544⟩

  • Article dans une revue

Effect of Coverage and Defects on the Adsorption of Propanethiol on Au(111) Surface: A Theoretical Study

Noelia B. Luque, Elizabeth Santos, Juan Andres, Frederik Tielens

Periodic density functional calculations have been carried out to investigate both the thiol adsorption on Au(111) surface and the reaction mechanism for the formation of the self-assembled monolayers, taking propanethiol as a representative example. The effect of coverage and surface defects (…

Langmuir, 2011, 27, pp.14514-14521. ⟨10.1021/la202861s⟩. ⟨hal-00670100⟩

  • Thèse

Approche expérimentale et théorique de l'inhibition de corrosion de surfaces métalliques, Experimental and theoretical approach of corrosion inhibition of metallic surfaces

Pauline Cornette

La corrosion des surfaces d’aluminium et d’alliages aluminium/cuivre, et notamment la corrosion localisée, est un problème majeur dans l’industrie, et l’utilisation d’inhibiteur de corrosion est bien souvent indispensable. Les chromates remplissent parfaitement leurs rôles d’inhibition mais seront…, Corrosion of aluminum and aluminum/copper alloy surfaces, including localized corrosion, is a major problem in the industry, and the use of a corrosion inhibitor is often essential. Chromates perfectly fulfill their role of inhibition but will soon be prohibited because of their toxicities for…

Matériaux. Université de recherche Paris-Sciences-et-Lettres, 2018. Français. ⟨NNT : ⟩. ⟨tel-01903566⟩

  • Article dans une revue

Prebiotic chemistry

J.F. Lambert, M. Sodupe, P. Ugliengo

Without doubt, one of the most fascinating questions ever asked is ''What is life?'', immediately followed by ''How and where did life arise?''. Both questions are by no means exclusively related to chemistry and biology. Indeed, it was soon realized that…

Chemical Society Reviews, 2012, 41, pp.5373-5374. ⟨10.1039/c2cs90061k⟩. ⟨hal-00809265⟩

  • HDR

Petit Voyage vers la surface : Structure et réactivité de solides inorganiques, A small trip to the surface: structure and reactivity of inorganic solids

Lorenzo Stievano

Dans ma carrière, j'ai eu la chance et le privilège de m'attaquer à des problématiques scientifiques très variées, qui peuvent être ressemblées par le concept fédérateur de l'application de méthodes d'analyses physico-chimiques pour la compréhension de la structure et de la…

Catalyse. Université Pierre et Marie Curie - Paris VI, 2005. ⟨tel-00092493⟩

  • Article dans une revue

Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si / Al lower limit

Marcelo Maciel Pereira, Elisa Gomes, Alessandra Vieira Silva, Ana Belen Pinar, Marc-Georg Willinger, Sangaraju Shanmugam, Céline Chizallet, Guillaume Laugel, Pit Losch, Benoit Louis

A family of Al-rich ZSM-5 zeolites with Si / Al = 8 ± 0.5 was prepared according to a biomass-mediated supramolecular approach. A combination of advanced characterisation techniques and periodic density functional theory (DFT) calculations unraveled the purity and stability of unexpected Al-…

Chemical Science, 2018, 9 (31), pp.6532 - 6539. ⟨10.1039/C8SC01675E⟩. ⟨hal-01882119v2⟩

  • Article dans une revue

Insights into bacteriophage T5 structure from analysis of its morphogenesis genes and protein components.

Yvan Zivanovic, Fabrice Confalonieri, Luc Ponchon, Rudi Lurz, Mohamed Chami, Ali Flayhan, Madalena Renouard, Alexis Huet, Paulette Decottignies, Alan R Davidson, Cécile Breyton, Pascale Boulanger

Bacteriophage T5 represents a large family of lytic Siphoviridae infecting Gram-negative bacteria. The low-resolution structure of T5 showed the T=13 geometry of the capsid and the unusual trimeric organization of the tail tube, and the assembly pathway of the capsid was established. Although major…

Journal of Virology, 2014, 88 (2), pp.1162-74. ⟨10.1128/JVI.02262-13⟩. ⟨hal-01130612⟩