Laboratoire de réactivité de surface

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  • Article dans une revue

Copper nanoparticles supported on ZIF-8: comparison of Cu(II) reduction processes and application as benzyl alcohol oxidation catalysts

Yifan Zan, Ferdaous Ben Romdhane, Antoine Miche, Christophe Méthivier, Jean-Marc Krafft, Claude Jolivalt, Julien Reboul

We report the synthesis of a stable heterogeneous catalyst based on copper metal nanoparticles with oxidized surface supported on ZIF-8 for the oxidation of benzyl alcohol under mild temperature and using air as a sustainable oxygen source as well as for the implementation of the tandem “one-pot”…

ACS Applied Materials & Interfaces, 2023, 15 (32), pp.38716-38728. ⟨10.1021/acsami.3c08906⟩. ⟨hal-04192093⟩

  • Article dans une revue

Selective Oxidation of Methane to Formaldehyde Catalyzed by Phosphates: Kinetic Description by Bond Strengths and Specific Total Acidities

Vasilij Gomonaj, Hervé Toulhoat

A kinetic model predicts the experimental activity and selectivity patterns obtained in oxidation of methane for divided unsupported orthophosphates (M II 3(PO4)2, M III PO4,) and pyrophosphates (M II 2P2O7, M IV P2O7) catalysts spanning extended ranges of M-O bond strength (calculated from first…

ACS Catalysis, 2018, 8 (9), pp.8263-8272. ⟨10.1021/acscatal.8b02629⟩. ⟨hal-01955648⟩

  • Article dans une revue

Vibrating single probe and stationary bi-probes to measure local electrochemical impedance spectroscopy.

Hisasi Takenouti, G. Galicia, Michel Keddam, Vincent Vivier

The electrochemical impedance spectroscopy is widely used to investigate the electrode kinetics. This method is recognized as a powerful method to discriminate one reaction model to another and also to evaluate the reaction rate of elementary steps. However, when the electrode kinetics is markedly…

Bulgarian Chemical Communications, 2006, 38 (3), pp.165-175. ⟨hal-04172938⟩

  • Article dans une revue

Nanostructured and spiky gold in biomolecule detection: improving binding efficiencies and enhancing optical signals

E. E. Bedford, S. Boujday, C.-M. Pradier, F. X. Gu

Nanostructured gold can improve the ability to detect biomolecules. Whether planar nanostructured surfaces or nanostructured particles are used, similar principles governing the enhancement apply. The two main benefits of nanostructured gold are improved geometry and enhancement of optical…

RSC Advances, 2015, 5 (21), pp.16461-16475. ⟨10.1039/c4ra13544j⟩. ⟨hal-01133167⟩

  • Article dans une revue

Effect of Coverage and Defects on the Adsorption of Propanethiol on Au(111) Surface: A Theoretical Study

Noelia B. Luque, Elizabeth Santos, Juan Andres, Frederik Tielens

Periodic density functional calculations have been carried out to investigate both the thiol adsorption on Au(111) surface and the reaction mechanism for the formation of the self-assembled monolayers, taking propanethiol as a representative example. The effect of coverage and surface defects (…

Langmuir, 2011, 27, pp.14514-14521. ⟨10.1021/la202861s⟩. ⟨hal-00670100⟩

  • Article dans une revue

Corrosion and protection of high leaded tin bronze covered with patina in NaHCO3 + Na2SO4 solution simulating acid rain in urban environment

Kamal Rahmouni, Suzanne Joiret, Luc Robbiola, A. Srhiri, Hisasi Takenouti, Vincent Vivier

An experimental procedure for obtaining reproducible patina on high leaded tin bronze, B66 (Cu-8Sn-14Pb in wt %) has been devised, followed by its isolation from the substrate and examination of the electrochemical behaviour in a solution of 0.2 g.L - 1 Na 2 SO 4 + 0.2 g.L - 1 NaHCO 3 acidified to…

Bulgarian Chemical Communications, 2005, 37 (1), pp.26-34. ⟨hal-04189329⟩

  • Article dans une revue

Versatile and robust synthesis process for the fine control of the chemical composition and core-crystallinity of spherical core-shell Au@Ag nanoparticles

Suyeon Lee, Hervé Portalès, Michael Walls, Patricia Beaunier, Nicolas Goubet, Benoit Tremblay, Jérémie Margueritat, Lucien Saviot, Alexa Courty

Au nanoparticles (NPs) characterized by distinct surface chemistry (including dodecanethiol or oleylamine as capping agent), different sizes (~5 and ~10 nm) and crystallinities (polycrystalline or single crystalline), were chosen as seeds to demonstrate the versatility and robustness of our two-…

Nanotechnology, 2021, 32, pp.095604. ⟨10.1088/1361-6528/abc450⟩. ⟨hal-02994816⟩

  • Article dans une revue

Smartphone spectrometer for colorimetric biosensing

Yi Wang, Xiaohu Liu, Peng Chen, Nhung Thi Tran, Jinling Zhang, Wei Sheng Chia, Souhir Boujday, Bo Liedberg

We report on a smartphone spectrometer for colorimetric biosensing applications. The spectrometer relies on a sample cell with an integrated grating substrate, and the smartphone's built-in light-emitting diode flash and camera. The feasibility of the smartphone spectrometer is demonstrated…

Analyst, 2016, 141 (11), pp.3233 - 3238. ⟨10.1039/C5AN02508G⟩. ⟨hal-01547878⟩

  • Article dans une revue

Catalytic Pyrolysis of Plastics over Maghemite-Impregnated Mesocellular Foam using Induction Heating

Luing Wong Syie, Sabino Armenise, B. Nyakuma Bemgba, Soon Ng Pang, Hau Lee Chia, Anna Bogush, Franck Launay, Evgeny Rebrov, Marta Munoz

Pyrolysis is a key technology that converts unrecyclable end-of-life plastics into value-added products. Nevertheless, the high energy consumption during plastic pyrolysis limits the economic feasibility of a scaled-up process. Development of an energy-efficient plastic pyrolysis process is…

Chemical Engineering Transactions, 2022, 97, pp.25. ⟨10.3303/CET2297005⟩. ⟨hal-04030193⟩

  • Article dans une revue

Sustainable production of acrolein: effects of reaction variables, modifiers doping and ZrO2 origin on the performance of WO3/ZrO2 catalyst for the gas-phase dehydration of glycerol

Song-Hai Chai, Li-Zhi Tao, Bo Yan, Jacques C. Vedrine, Bo-Qing Xu

Zirconia-supported tungsten oxide (WO3/ZrO2 or WZ) is known as an efficient catalyst for selective acrolein (AC) production from gas-phase dehydration of glycerol (GL). Two catalysts (WZ-CP and WZ-AN) were prepared herein using, respectively, a ZrO(OH)2 hydrogel (ZrO(OH)2-CP) and its derived…

RSC Advances, 2014, 4 (9), pp.4619-4630. ⟨10.1039/C3RA46511J⟩. ⟨hal-01079293⟩