Laboratoire de réactivité de surface

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  • Article dans une revue

Approach for Plasmonic Based DNA Sensing: Amplification of the Wavelength Shift and Simultaneous Detection of the Plasmon Modes of Gold Nanostructures

Jolanda Spadavecchia, Alexandre Barras, Joël Lyskawa, Patrice Woisel, William Laure, Claire-Marie Pradier, Rabah Boukherroub, Sabine Szunerits

In this article, the detection of DNA hybridization taking advantage of the plasmonic properties of gold nanostructures is described. The approach is based on the amplification of the wavelength shift of a multilayered localized surface plasmon resonance (LSPR) sensor interface upon hybridization…

Analytical Chemistry, 2013, 85, pp.3288-3296. ⟨10.1021/ac3036316⟩. ⟨hal-00836615⟩

  • Article dans une revue

Recent advances in aptasensors based on graphene and graphene-like nanomaterials

Jianfeng Ping, Yubin Zhou, Yuanyuan Wu, Vladislav Papper, Souhir Boujday, Robert S. Marks, Terry W.J. Steele

Graphene and graphene-like two-dimensional nanomaterials have aroused tremendous research interest in recent years due to their unique electronic, optical, and mechanical properties associated with their planar structure. Aptamers have exhibited many advantages as molecular recognition elements for…

Biosensors and Bioelectronics, 2015, 64, pp.373-385. ⟨10.1016/j.bios.2014.08.090⟩. ⟨hal-01132984⟩

  • Article dans une revue

Unlocking synergy in bimetallic catalysts by core–shell design

Jessi van der Hoeven, Jelena Jelic, Liselotte Olthof, Giorgio Totarella, Relinde van Dijk-Moes, Jean-Marc Krafft, Catherine Louis, Felix Studt, Alfons van Blaaderen, Petra de Jongh

Extending the toolbox from mono- to bimetallic catalysts is key in realizing efficient chemical processes1. Traditionally, the performance of bimetallic catalysts featuring one active and one selective metal is optimized by varying the metal composition1,2,3, often resulting in a compromise between…

Nature Materials, 2021, 20 (9), pp.1216-1220. ⟨10.1038/s41563-021-00996-3⟩. ⟨hal-03995585⟩

  • Article dans une revue

DFT Study of Halide-Free Mechanism of the CO2 Cycloaddition onto Epoxide by [PW11O39{Zn(H2O)}]5−: Evidences for the Formation of Hydrogencarbonate Intermediates

Jingjing Ren, Franck Launay, Richard Villanneau, Hélène Gérard

The intertwined experimental and theoretical study of the reaction of CO 2 with styrene oxide in the presence of the tetraoctylammonium salt of [PW 11 O 39 Zn II (H 2 O)] 5− evidences the carbonic anhydrase‐like role of the polyoxometalate center in catalyzing the reaction. We computationally…

ChemCatChem, 2025, Women in Chemistry in France, 17 (15), pp.e00312. ⟨10.1002/cctc.202500312⟩. ⟨hal-05789436⟩

  • Article dans une revue

Polypyrrole nanostructures modified with mono- and bimetallic nanoparticles for photocatalytic H2 generation

Xiaojiao Yuan, Diana Dragoe, Patricia Beaunier, Daniel Bahena Uribe, Laurence Ramos, Maria Guadalupe Méndez-Medrano, Hynd Remita

Conjugated polymer polypyrrole nanostructures modified with bimetallic (Pt–Ni) nanoparticles are very active for hydrogen generation and a synergetic effect is obtained by alloying Pt with Ni.

Journal of Materials Chemistry A, 2020, 8 (1), pp.268-277. ⟨10.1039/C9TA11088G⟩. ⟨hal-03437340⟩

  • Article dans une revue

A comparative study of alanine adsorption and condensation to peptides in two clay minerals

Fabrícia de Castro Silva, Luciano Clécio Brandão Lima, Edson Silva-Filho, Maria Gardennia Fonseca, Jean-François Lambert, Maguy Jaber

The polycondensation of amino acids to oligopeptides is an important step in the origins of life, and known to be effective on several mineral surfaces. The data available on clay mineral surfaces are heterogeneous and sometimes contradictory, however. The objective of the present work is to…

Applied Clay Science, 2020, 192, pp.105617. ⟨10.1016/j.clay.2020.105617⟩. ⟨hal-02887409⟩

  • Article dans une revue

On the origin of the changes in color of Ag/Al2O3 catalysts during storage

Tesnim Chaieb, Dalil Brouri, Sandra Casale, Jean-Marc Krafft, Tiago da Silva, Cyril Thomas, Laurent Delannoy, Catherine Louis

Despite the large number of catalytic studies involving Ag/Al2O3 catalysts, especially in deNOx reactions, the phenomenon of ageing observed during catalysts storage after preparation by impregnation followed by a calcination treatment, has not been reported earlier and rises questions. The present…

Research on Chemical Intermediates, 2019, 45 (12), pp.5877 - 5905. ⟨10.1007/s11164-019-04007-8⟩. ⟨hal-02407541⟩

  • Article dans une revue

Synthesis and characterization of Ag-Protoporphyrin nano structures using mixed co-polymer method

Ramesh Perumal, Sandra Casale, Luca de Stefano, Jolanda Spadavecchia

In this paper, we report the synthesis of hybrid silver nanostructures (AgNPs) based on an effective mixing of polyols with Polyvinylpyrrolidone (PVP) and Porphyrin molecules, in particular Protoporphyrin IX (PP). The combination of PVP and PP, which act as co-directing agents and favour the…

Frontiers in Laboratory Medicine, 2017, ⟨10.1016/j.flm.2017.05.002⟩. ⟨hal-01526696⟩

  • Article dans une revue

Revealing the Interplay between Adsorbed Molecular Layers and Gold Nanoparticles by Linear and Nonlinear Optical Properties

Laetitia Dalstein, Maroua Ben Haddada, Grégory Barbillon, Christophe Humbert, Abderrahmane Tadjeddine, Souhir Boujday, Bertrand Busson

Gold nanoparticles (AuNPs) chemically grafted on substrates are widely used as sensors due to their plasmonic properties. The efficiency and robustness of such sensors strongly depend on the molecular sublayer structure, which influences the distribution of AuNPs, and therefore the plasmonic…

Journal of Physical Chemistry C, 2015, 119 (30), pp.17146-17155. ⟨10.1021/acs.jpcc.5b03601⟩. ⟨hal-02111041⟩

  • Article dans une revue

Ordered Nanostructures on a Hydroxylated Aluminum Surface through the Self-Assembly of Fatty Acids.

Irma Liascukiene, Nesrine Aissaoui, Svajus J. Asadauskas, Jessem Landoulsi, Jean-François Lambert

We investigate the mechanism of self-assembly of fatty acids (FA) and methyl oleate on an Al oxy-hydroxide surface with a view to deciphering the role and nature of interfacial processes (adsorption, chemical binding, molecular organization, etc.). For this purpose, we focus on parameters related…

Langmuir, 2012, 28, pp.5116-5124. ⟨10.1021/la2051542⟩. ⟨hal-00688636⟩