• Article dans une revue

Cu-modified hydroxy-apatite as catalyst for Glaser–Hay CC homo- coupling reaction of terminal alkynes

Birgit Maaten, Jamal Moussa, Christophe Desmarets, Patrick Gredin, Patricia Beaunier, Tõnis Kanger, Kaia Tõnsuaadu, Didier Villemin, Michel Gruselle

The oxidative Glaser–Hay coupling reaction of terminal alkynes is a very important reaction in organic chemistry to achieve the synthesis of diyne compounds. In general the reaction is performed under homogeneous conditions using Cu(I) or Cu(II) salts in the presence of a reagent such as…

Journal of Molecular Catalysis A: Chemical, 2014, 393, pp.112-116. ⟨10.1016/j.molcata.2014.06.011⟩. ⟨hal-01121587⟩

• Article dans une revue

Surface-generated copper ions induce multilayer growth of small peptides

Jessem Landoulsi, Vincent Dupres, Christophe Méthivier, Ivan Leteyi Mfiban, Pauline Cornette, Elodie Colaço, Claire-Marie Pradier

Herein, we investigate the adsorption behavior of a small peptide, Glu-Cys-Gly, in aqueous solution onto copper surface and unravel a mechanism of growth of a hybrid peptide-copper multilayer the thickness of which may exceed a hundred of nanometers. Thanks to a combined set of surface…

Applied Surface Science, 2020, 507, pp.145105. ⟨10.1016/j.apsusc.2019.145105⟩. ⟨hal-03489696⟩

• Article dans une revue

Development of acidic sites in WOx/ZrO2

Thomas Onfroy, Guillaume Clet, Marwan Houalla

Evidence is shown of the appearance of Brønsted acidic sites in WOx/ZrO2 at a given W loading and of a direct correlation between the abundance of ‘strong’ Brønsted acidic sites in these catalysts and propan-2-ol decomposition activity.

Chemical Communications, 2001, 15, pp.1378-1379. ⟨10.1039/b102867g⟩. ⟨hal-02399977⟩

• Article dans une revue

Immobilisation of protein A on SAM's for the elaboration of immunosensors

Elisabeth Briand, Michèle Salmain, Chantal Compere, Claire-Marie Pradier

Binary mixtures of 11-mercaptoundecanoic acid (MUA) and other thiols of various lengths and terminal functions were chemisorbed on gold-coated surfaces via S-Au bonds to form mixed self-assembled monolayers (SAMs). Several values of the mole fraction of MUA in the thiol mixtures were tested and the…

Colloids and Surfaces, 2006, 53, pp.222-231. ⟨10.1016/j.colsurfb.2006.09.010⟩. ⟨hal-00111187⟩

• Communication dans un congrès

Intérêt des revêtements N-halamines dans la lutte contre le développement des bactéries et du biofilm

Catherine Debiemme-Chouvy, Shan Gao, Hubert Cachet, Nadia Nazi, Vincent Humblot

L’enrayement du développement des biofilms ou de la prolifération de bactéries pathogènes est indispensable aussi bien pour des raisons de santé publique que pour des raisons économiques. Pour les milieux hydriques, à ces fins, des biocides oxydants sont fréquemment employés. Ils sont alors ajoutés…

Matériaux 2018, FFM; Société Chimique de France (SCF), Nov 2018, Strasbourg (67), France. ⟨hal-03978791⟩

• Article dans une revue

Building the uracil skeleton in primitive ponds at the origins of life: carbamoylation of aspartic acid

Louis Ter-Ovanessian, Jean-François Lambert, Marie-Christine Maurel

Abstract A large set of nucleobases and amino acids is found in meteorites, implying that several chemical reservoirs are present in the solar system. The “geochemical continuity” hypothesis explores how protometabolic paths developed from so-called “bricks” in an enzyme-free prebiotic world and…

Scientific Reports, 2022, 12 (1), pp.19178. ⟨10.1038/s41598-022-21272-7⟩. ⟨hal-03848150⟩

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Hydrodenitrogenation of indole over Mo2C catalyst: Insights into mechanistic events through DFT modeling

Witold Piskorz, Grzegorz Adamski, Andrzej Kotarba, Zbigniew Sojka, Céline Sayag, G. Djéga-Mariadassou

The molecular reaction mechanism of hydrodenitrogenation of indole was studied using density-functional theory calculations of the adsorbed o-ethylaniline surrounded by mobile hydrogen atoms. It was found that the hydrogenation of o-ethylaniline occurs through two steps: consisting in…

Catalysis Today, 2006, 119, pp.39-43. ⟨10.1016/j.cattod.2006.08.050⟩. ⟨hal-00128043⟩

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Dynamics of Hydration in Vanadia-Titania Catalysts at Low Loading: A Theoretical and Experimental Study

Anna E. Lewandowska, Monica Catalayud, Frederik Tielens, Miguel A. Banares

The hydration process of dehydrated vanadia-titania catalysts at low loading is investigated using periodic DFT calculations. We focus on the early stages of the hydration process of the vanadia-titania in order to shed light onto the structural and dynamical changes occurring at the molecular…

Journal of Physical Chemistry C, 2011, 115, pp.24133-24142. ⟨10.1021/jp204726b⟩. ⟨hal-00669737⟩

• Communication dans un congrès

APPIMIL Project: photonic and particle irradiation experiments at the CNRS Orléans and their relevance to BIOMEX and ExoMars

F. Foucher, T. Georgelin, T. Sauvage, A. Canizares, P. de Vera J.-P., M. Baqué, V. Lago, R. Joussot, Sunil Simon, R. Gay, P. Koumba-Ibala, N. Gouillon, K. Hickman-Lewis, A. Bellamy, F. Westall

BIOMEX Closing Ceremony Meeting at DLR, Mar 2019, Berlin, Germany. ⟨hal-03089550⟩

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General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis

Sabine Valange, Jacques C. Védrine

In this review paper, we have assembled the main characteristics of partial oxidation reactions (oxidative dehydrogenation and selective oxidation to olefins or oxygenates, as aldehydes and carboxylic acids and nitriles), as well as total oxidation, particularly for depollution, environmental…

Catalysts, 2018, 8 (10), pp.483. ⟨10.3390/catal8100483⟩. ⟨hal-01926781⟩