• Article dans une revue

Improvements in photostability and sensing properties of EuVO₄ nanoparticles by microwave-assisted sol–gel route for detection of H₂ O₂ vapors

Chrystel Ambard, Natacha Duée, Franck Pereira, David Portehault, Christophe Méthivier, Claire-Marie Pradier, Clément Sanchez

The inorganic thin-film fluorescence probe, with the advantages of long life span and high sensitivity, has attracted much attention in explosive detection. The poor ultraviolet absorption and lack of an aromatic ring make peroxide-based explosives very hard to detect. As the signature compound of…

• Article dans une revue

Converting silicon nanoparticles into nickel iron silicide nanocrystals within molten salts for water oxidation electrocatalysis

Yang Song, Sandra Casale, Antoine Miche, David Montero, Christel Laberty-Robert, David Portehault

We synthesize metal silicide electrocatalysts for water oxidation, by using the high reactivity of silicon nanoparticles and the unique stability and low vapor pressure of molten salt solvents. We can then perform liquid-phase synthesis under vacuum at 300-400 C. This strategy yields FeSi, Ni 2 Si…

Journal of Materials Chemistry A, 2022, 10 (3), pp.1350-1358. ⟨10.1039/D1TA08097K⟩. ⟨hal-03537470⟩

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Insights into the influence of the Ag loading on Al2O3 in the H2-assisted C3H6-SCR of NOx

Tesnim Chaieb, Laurent Delannoy, Guylène Costentin, Catherine Louis, Sandra Casale, Ruth L. Chantry, Z.Y. Li, Cyril Thomas

The addition of H2 has been reported to promote drastically the selective catalytic reduction of NOx by hydrocarbons (HC-SCR). Yet, the influence of the Ag loading on the H2-promoted HC-SCR has been the subject of a very limited number of investigations. The H2-HC-SCR earlier studies reported…

Applied Catalysis B: Environmental, 2014, 156-157, pp.192-201. ⟨10.1016/j.apcatb.2014.03.025⟩. ⟨hal-00979536⟩

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Influence of Coadsorbed Water and Alcohol Molecules on Isopropyl Alcohol Dehydration on γ-Alumina: Multiscale Modeling of Experimental Kinetic Profiles

Kim Larmier, Andre Nicolle, Céline Chizallet, Nicolas Cadran, Sylvie Maury, Anne-Félicie Lamic-Humblot, Eric Marceau, Hélène Lauron-Pernot

Successfully modeling the behavior of catalytic systems at different scales is a matter of importance not only for a fundamental understanding but also for a more rational design of catalysts and a more precise definition of the kinetic laws used as inputs in chemical engineering. We have developed…

ACS Catalysis, 2016, 6 (3), ⟨10.1021/acscatal.6b0008⟩. ⟨hal-01564196⟩

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Effect of postsynthesis preparation procedure on the state of copper in CuBEA zeolites and its catalytic properties in SCR of NO with NH3

Rafal Baran, Frederic Averseng, Dominik Wierzbicki, Karolina Chalupka, Jean-Marc Krafft, Teresa Grzybek, Stanislaw Dzwigaj

Copper-containing BEA zeolites, Cu2.0SiBEA and Cu2.0HAlBEA, with 2 wt % of Cu were prepared by a two-step postsynthesis method and a conventional wet impregnation, respectively. These zeolites were characterized by XRD, DR UV–vis, EPR, FTIR and TPR physicochemical techniques. The incorporation of…

Applied Catalysis A : General, 2016, 523 pp.332-342. ⟨10.1016/j.apcata.2016.06.008⟩. ⟨hal-01329581⟩

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Cation redistribution upon dehydration of Na 58 Y faujasite zeolite: a joint neutron diffraction and molecular simulation study

Wilfried Louisfrema, Benjamin Rotenberg, Florence Porcher, Jean-Louis Paillaud, Pascale Massiani, Anne Boutin

Using neutron scattering and Monte Carlo simulation, we investigate the distribution of cations in Na58Y faujasite upon (de)hydration. We introduce a new method for the assignment of cations to specific sites in molecular simulations from their local environment. This allows us to bypass the need…

Molecular Simulation, 2015, 41 (16-17), pp.1371-1378. ⟨10.1080/08927022.2015.1027889⟩. ⟨hal-01284815⟩

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Optimization and Antibacterial Response of N-Halamine Coatings Based on Polydopamine

Nadia Nazi, Adeline Marguier, Catherine Debiemme-Chouvy, Vincent Humblot

RessouDue to the ability of microorganisms to first adhere to a material surface and then to lead to the formation of a biofilm, it is essential to develop surfaces that have antimicrobial properties. It is well known that N-halamine coatings allow us to prevent or minimize such phenomena. In the…

Colloids and Interfaces, 2022, 6 (1), pp.9 (20). ⟨10.3390/colloids6010009⟩. ⟨hal-03693047⟩

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Direct Observation of the Surface Topography at High Temperature with SEM

Renaud Podor, X. F Le Goff, Joseph Lautru, H.P. Brau, Mathias Barreau, Xavier Carrier, Jerôme Mendonça, Dorian Nogues, Antoine Candeias

High-temperature scanning electron microscopy allows the direct study of the temperature behavior of materials. Using a newly developed heating stage, tilted images series were recorded at high temperature and 3D images of the sample surface were reconstructed. By combining 3D images recorded at…

Microscopy and Microanalysis, 2020, 26 (3), pp.397-402. ⟨10.1017/S1431927620001348⟩. ⟨hal-03003458⟩

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Preparation of niobium-based oxygen carriers by polyol-mediated process and application to chemical-looping reforming

Pedro Henrique Lopes Nunes Abreu dos Santos, Sophie Nowak, Stéphanie Lau-Truong, Juliette Blanchard, Patricia Beaunier, José Augusto Jorge Rodrigues, Roberta Brayner

New niobium-based oxygen carriers were prepared adopting polyol-mediated process. Four different polyols were used (diethylene glycol, triethylene glycol, tetraethylene glycol, and 1,2-propanediol) and four different quantities of water (0 mL, 1 mL, 10 mL, 30 mL, with a total volume of 80 mL of…

Journal of Nanoparticle Research, 2019, 21 (5), ⟨10.1007/s11051-019-4528-z⟩. ⟨hal-02375304⟩

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One Step up the Ladder of Prebiotic Complexity: Formation of Nonrandom Linear Polypeptides from Binary Systems of Amino Acids on Silica

Yuriy Sakhno, Alice Battistella, Alberto Mezzetti, Maguy Jaber, Thomas Georgelin, Laurent Michot, Jean-François Lambert

Evidence for the formation of linear oligopeptides with nonrandom sequences from mixtures of amino acids coadsorbed on silica and submitted to a simple thermal activation is presented. The amino acid couples (glutamic acid+leucine) and (aspartic acid+valine) were deposited on a fumed silica and…

Chemistry - A European Journal, 2019, 25 (5), pp.1275-1285. ⟨10.1002/chem.201803845⟩. ⟨hal-02067461⟩