• Article dans une revue

Factors impacting the aggregation/agglomeration and photocatalytic activity of highly crystalline spheroid- and rod-shaped TiO 2 nanoparticles in aqueous solutions

Thomas Degabriel, Elodie Colaço, Rute F Domingos, Karim El Kirat, Dalil Brouri, Sandra Casale, Jessem Landoulsi, Jolanda Spadavecchia

We investigate the characteristics, fate and photocatalytic activity of spheroid- and rod-shaped TiO2 nano-crystals in aqueous solutions to better understand their behaviour in media of biological and environmental interest. For this purpose, the potential of a solvothermal method in synthesizing…

Physical Chemistry Chemical Physics, 2018, 20 (18), pp.12898 - 12907. ⟨10.1039/C7CP08054A⟩. ⟨hal-01803715⟩

• Thèse

Influence de l'incorporation du vanadium dans l'hydroxyapatite sur la réaction d'oxydation déshydrogénante du propane, Influence of the incorporation of vanadium in hydroxyapatite on the oxidative dehydrogenation of propane reaction

Sarah Petit

Dans l'objectif de combler le gap entre l'offre et la demande en propène, la réaction d'oxydation déshydrogénante du propane (ODHP) est une solution alternative à la réaction de déshydrogénation directe. Les hydroxyapatites (HAp) modifiées au vanadium sont des matériaux bi-…, In order to fill the gap between propene supply and demand, the oxidative dehydrogenation of propane (ODHP) is an alternative solution to the direct dehydrogenation process. Vanadium-modified hydroxyapatites (HAp) are bifunctional catalysts combining acid-base and redox properties which were shown…

Matériaux. Université Pierre et Marie Curie - Paris VI, 2017. Français. ⟨NNT : 2017PA066620⟩. ⟨tel-02354902⟩

• Article dans une revue

A Molecular Picture of the Adsorption of Glycine in Mesoporous Silica through NMR Experiments Combined with DFT‑D Calculations

Nicolas Folliet, Christel Gervais, Dominique Costa, Guillaume Laurent, Florence Babonneau, Lorenzo Stievano, Jean-François Lambert, Frederik Tielens

The adsorption behavior of the amino acid glycine in mesoporous silica has been investigated using a combination of quantum chemical calculations and NMR spectroscopy experiments. Glycine adsorption on two representative sites of an amorphous silica surface, vicinal silanols and a silanol nest, was…

Journal of Physical Chemistry C, 2013, 117, pp.4104-4114. ⟨10.1021/jp312195a⟩. ⟨hal-00797997⟩

• Article dans une revue

Control of calcium accessibility over hydroxyapatite by post-precipitation steps: influence on the catalytic reactivity toward alcohols

Manel Ben Osman, Sarah Diallo Garcia, Jean-Marc Krafft, Christophe Methivier, Juliette Blanchard, Tetsuya Yoshioka, Jun Kubo, Guylène Costentin

Hydroxyapatites are increasingly used as heterogeneous catalysts since they present atypical behaviours for many acid base reactions. The aim of this study was to discuss the possible involvement of Ca2+ Lewis and/or PO–H Brønsted acid sites belonging to the hydroxyapatite system in the conversion…

Physical Chemistry Chemical Physics, 2016, ⟨10.1039/C6CP05294K⟩. ⟨hal-01378475⟩

• Article dans une revue

Influence of the swelling agents of siliceous mesocellular foams on the performances of Ni-based methane dry reforming catalysts

Oscar Daoura, Sarah Daher, Marie-Nour Kaydouh, Nissrine El Hassan, Pascale Massiani, Franck Launay, Maya Boutros

International Journal of Hydrogen Energy, 2018, 43 (36), pp.17205-17215. ⟨10.1016/j.ijhydene.2018.07.123⟩. ⟨hal-02414800⟩

• Article dans une revue

Surface plasmon resonance: signal amplification using colloidal gold nanoparticles for enhanced sensitivity

Sabine Szunerits, Jolanda Spadavecchia, Rabah Boukherroub

Among all the detection methods developed for bioassays, optical-based approaches are the most popular techniques. A widely used and accepted bioanalytical technique for routine characterization of molecular recognition events at a solid interface is surface plasmon resonance (SPR) spectroscopy.…

Critical Reviews in Analytical Chemistry, 2014, 33, pp.153-164. ⟨10.1515/revac-2014-0011⟩. ⟨hal-01071317⟩

• Article dans une revue

Adsorption of a chiral modifier on an oxide surface: Chemical nature of tartaric acid on rutile TiO2 (110)

E. Meriggio, R. Lazzari, S. Chenot, P. David, C. Methivier, X. Carrier, G. Cabailh, V. Humblot

Tartaric acid (TA) is one of the most known chiral modifier used in heterogeneous enantioselective catalysis and understanding how it interacts with oxide supports is of significant importance for the design of efficient supported metal catalysts. This work presents a detailed surface science…

Applied Surface Science, 2019, 493, pp.1134-1141. ⟨10.1016/j.apsusc.2019.07.143⟩. ⟨hal-02340234⟩

• Article dans une revue

Characterization and catalytic activity of Mn (salen) immobilized on silica by various strategies

Khalil Tesnime Abou, Chaaben Semy Ben, Boujday Souhir, Bergaoui Latifa

Different strategies were applied to prepare supported Mn(salen) on fumed silica and to explore the effect of the interaction nature between the active sites and the surface on the catalytic activity. Direct and multistep grafting methods were used: the silica surface was silylated and the metal…

IOSR Journal of Applied Chemistry, 2015, 8, pp.36-45. ⟨10.9790/5736-08113645⟩. ⟨hal-01133157⟩

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To be born is not enough: the key role of innovative start-ups

Alessandra Colombelli, Jackie Krafft, Marco Vivarelli

This paper investigates the reasons why entry per se is not necessarily good and the evidence showing that innovative start-ups survive longer than their non-innovative counterparts. In this framework, our own empirical analysis shows that greater survival is achieved when start-ups engage…

Small Business Economics, 2016, 47 (2), pp.1-15. ⟨10.1007/s11187-016-9716-y⟩. ⟨halshs-01248721⟩

• Article dans une revue

Investigation of ion-selective electrodes with neutral ionophores and ionic sites by EIS. II. Application to K+ detection

Claude Gabrielli, Patrick Hemery, Pierre Letellier, Michele Masure, Hubert Perrot, Marie-Isabelle Rahmi, Mireille Turmine

The impedance of an ion-selective electrode (ISE) to potassium with valinomycin as the ionophore and KBΦ4 as the ionic sites was measured. The membrane was made of PVC with DNP as a plasticizer. The influence of the content of the plasticizer and the membrane thickness was investigated. The…

Journal of Electroanalytical Chemistry, 2004, 570 (2), pp.291-304. ⟨10.1016/j.jelechem.2004.04.007⟩. ⟨hal-04197746⟩