• Thèse

Molecules at surfaces : formation, reactivity, assembly of (bio)molecules on external and internal surfaces of nanosized/nanostructured materials, Molécules aux surfaces : formation, réactivité, assemblage de (bio) molécules sur les surfaces externes et internes de matériaux nanométriques / nanostructurés

Ola El Samrout

This PhD thesis aims to deeply study the polymerization of Gly monomers on amorphous silica to better understand its reaction mechanism, kinetics, and parameters related to the nature of the condensation product obtained under different environmental conditions. In the first part, the behavior of…, Cette thèse vise à étudier en profondeur la polymérisation des monomères Gly sur de la silice amorphe afin de mieux comprendre son mécanisme réactionnel, sa cinétique et les paramètres liés à la nature du produit de condensation obtenu dans différentes conditions environnementales. Dans la première…

Material chemistry. Sorbonne Université; Università degli studi (Turin, Italie), 2023. English. ⟨NNT : 2023SORUS085⟩. ⟨tel-04138067⟩

• Article dans une revue

A fullerene helical peptide: synthesis, characterization and formation of self-assembled monolayers on gold surfaces

Houssein Nasrallah, Jad Rabah, Van Bui-Thi-Tuyet, Krystyna Baczko, Hélène Fensterbank, Flavien Bourdreux, Anne-Marie Goncalves, Valérie Declerck, Souhir Boujday, Vincent Humblot, Karen Wright, Anne Vallée, Emmanuel Allard

The synthesis of a C60-peptide using "clickable" fullerene and peptide derivatives is described. The peptide is composed of a repeating sequence of -aminoisobutyric acid (Aib) and two L-Alanine (Ala) residues, promoting the formation of a helical conformation, which has been confirmed by…

New Journal of Chemistry, 2018, 42 (24), pp.19423-19432. ⟨10.1039/c8nj04599b⟩. ⟨hal-02348881⟩

• Article dans une revue

Hydrodechlorination of 1,2-dichloroethane on nickel loaded Beta zeolite modified by copper: Influence of nickel and copper state on product selectivity

Rafal Baran, Anna Srebowata, Sandra Casale, D. Łomot, Stanislaw Dzwigaj

Influence of copper addition to nickel containing zeolite on activity and product selectivity in the hydrodechlorination of 1,2-dichloroethane was investigated. Ni2.0SiBEA and Cu2.0Ni2.0SiBEA zeolites were prepared by a two-steps postsynthesis method which consist of (1) creation of vacant T-atom…

Catalysis Today, 2014, 226, pp.134-140. ⟨10.1016/j.cattod.2013.09.005⟩. ⟨hal-01044872⟩

• Article dans une revue

Permanently hydrophilic, piezoelectric PVDF nanofibrous scaffolds promoting unaided electromechanical stimulation on osteoblasts

Maria Kitsara, Andreu Blanquer, Gonzalo Murillo, Vincent Humblot, Sara de Bragança Vieira, Carme Nogués, Elena Ibáñez, Jaume Esteve, Leonardo Barrios

Biomimetic functional scaffolds for tissue engineering should fulfil specific requirements concerning structural, biochemical and electro-mechanical characteristics, depending on the tissue that they are designed to resemble. In bone tissue engineering, piezoelectric materials based on poly(…

Nanoscale, 2019, 11 (18), pp.8906-8917. ⟨10.1039/C8NR10384D⟩. ⟨hal-02351810⟩

• Poster de conférence

Influence des voies de préparation des oxydes mixtes NiMgAl sur leurs activités catalytiques en méthanation du CO2

Michel Obeid, Christophe Poupin, Samer Aouad, François Delattre, Madona Labaki, Josefine Schnee, Eric Gaigneaux, Edmond Abi-Aad

GECat 2024, May 2024, Hendaye, France. ⟨hal-04585096⟩

• Article dans une revue

Improvement of the Catalytic Performances of SBA‐15 in the Formylation of Aniline upon the Introduction of Template‐Free Nano‐Faujasite in Its Synthesis Gel

Karima Baghdad, Mohammed Abdelkrim Hasnaoui, Franck Launay

Faujasite nanoparticles with average size of 10–40 nm were obtained without any organic structure directing agents (Green synthesis), then used as precursors for the synthesis of NaY/SBA-15 composites. Two types of composites were obtained with meso/micro porosity (C1 and C2).The inorganic salt,…

ChemistrySelect, 2021, 6 (30), pp.7636-7643. ⟨10.1002/slct.202101782⟩. ⟨hal-04025231⟩

• Article dans une revue

Activity of molybdenum and tungsten oxycarbides in hydrodenitrogenation of carbazole leading to isomerization secondary reaction of bicyclohexyl. Results using bicyclohexyl as feedstock

Marek Lewandowski, Agnieszka Szymańska-Kolasa, Céline Sayag, Gérald Djéga-Mariadassou

The catalytic activities of bulk tungsten and molybdenum oxycarbides, (W2C and Mo2C) have been specifically studied in the isomerization occurring during the hydrodenitrogenation (HDN) of carbazole. The two catalysts have been characterized by several physico-chemical techniques such as X-Ray…

Applied Catalysis B: Environmental, 2020, 261, pp.118239. ⟨10.1016/j.apcatb.2019.118239⟩. ⟨hal-04024756⟩

• Article dans une revue

Plasma Assisted Catalyst for NOx Remediation from Lean Gas Exhaust

Ahmed Khacef, Patrick da Costa, Gérald Djéga-Mariadassou

A non-thermal plasma (NTP) reactor was coupled with a three-function catalyst in order to verify the nature of the effect of the plasma on the catalytic process. A mixture of NO/O2/hydrocarbons in N2 was used as a lean model exhaust gas composition. The plasma was found to perform two of the three…

Journal of Engineering and Technology Research, 2013, 1 (1), pp.112-122. ⟨hal-00918937⟩

• Article dans une revue

Porosity Design of Shaped Zeolites for Improved Catalyst Lifetime in the Methanol-to-Hydrocarbons Reaction

Rogéria Bingre, Renna Li, Qiang Wang, Patrick Nguyen, Thomas Onfroy, Benoit Louis

Additional porosity, such as meso-and macropores, was introduced in zeolite extrudates with the intention intuit of improving the effective diffusivity of the catalysts. The samples were characterized in depth by nitrogen adsorption-desorption, mercury intrusion porosimetry, ammonia temperature…

Catalysts, 2019, 9 (6), pp.545. ⟨10.3390/catal9060545⟩. ⟨hal-02271909⟩

• Article dans une revue

Promoting Ag/Al2O3 Performance in Low-Temperature H2-C3H6-SCR by Thermal Pretreatment of γ-Alumina in Water

Tesnim Chaieb, Laurent Delannoy, Catherine Louis, Cyril Thomas

The present work highlights for the first time that a thermal treatment of γ-Al2O3 in water at 80 °C for 24 h prior to Ag deposition (Ag/Al2O3-OH) leads to a drastic enhancement of H2-C3H6-SCR performance at low temperature. This enhancement is attributed to the higher NOx coverage on Ag/Al2O3-OH…

Catalysis Letters, 2016, pp.1-8. ⟨10.1007/s10562-016-1864-9⟩. ⟨hal-01390045⟩