Laboratoire de réactivité de surface

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  • Article dans une revue

The Mosaic Structure of Zeolite Crystals

Zhengxing Qin, Georgian Melinte, Jean-Pierre Gilson, Maguy Jaber, Krassimir Bozhilov, Philippe Boullay, Svetlana Mintova, Ovidiu Ersen, Valentin Valtchev

Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride…

Angewandte Chemie International Edition, 2016, 55 (48), pp.15049-15052. ⟨10.1002/anie.201608417⟩. ⟨hal-02410439⟩

  • Thèse

Use of unconventional activation methods for the oxidative cleavage of lignin by dioxygen, Utilisation de moyens d’activation non-conventionnels pour le clivage oxydant de la lignine par le dioxygène

Louay Al-Hussaini

Due to the depletion of fossil resources, the interest of lignin as a sustainable alternative to petroleum is growing. Thus, the main purpose of this thesis was to develop a process for oxidative cleavage of lignin by dioxygen that involves unconventional methodologies like sonochemistry and ball-…, Du fait de l'épuisement des ressources fossiles, l'intérêt de la lignine en tant qu'alternative durable est grandissant. Ainsi, le but principal de cette thèse était de mettre au point un procédé de clivage oxydant de la lignine par le dioxygène qui implique des voies non…

Other. Sorbonne Université, 2019. English. ⟨NNT : 2019SORUS448⟩. ⟨tel-03463302⟩

  • Article dans une revue

One-pot prepared mesoporous silica SBA-15-like monoliths with embedded Ni particles as selective and stable catalysts for methane dry reforming

Oscar Daoura, Giulia Fornasieri, Maya Boutros, Nissrine El Hassan, Patricia Beaunier, Cyril Thomas, Mohamed Selmane, Antoine Miche, Capucine Sassoye, Ovidiu Ersen, Walid Baaziz, Pascale Massiani, Anne Bleuzen, Franck Launay

Ni@SBA-15 monoliths with up to 5 wt.% of Ni were successfully synthetized by means of an original and easy one-pot sol-gel method. Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), Temperature-Programmed Reduction (TPR), Pair Distribution Function (PDF) and X-Ray…

Applied Catalysis B: Environmental, 2021, 280, pp.119417. ⟨10.1016/j.apcatb.2020.119417⟩. ⟨hal-02991760⟩

  • Thèse

Synthèse prébiotique de Ribonucléotides sur des surfaces minérales, Prebiotic synthesis of Ribonucleotides on mineral surfaces

Mariame Akouche

Dans le contexte prébiotique du " monde ARN ", les ribonucléotides sont considérés comme étant les premières espèces à avoir émergé sur Terre. En milieu aqueux, leur formation est défavorable thermodynamiquement. Les voies de synthèse de nucléotides décrites en phase homogène impliquent l…, In the « RNA world» prebiotic scenario, ribonucleotide polymers are considered as the first biochemical species to have emerged. However, in aqueous solution, their formation through conventional mechanisms of condensation is thermodynamically forbidden. Several synthesis pathways of nucleotides…

Chimie-Physique [physics.chem-ph]. Université Pierre et Marie Curie - Paris VI, 2016. Français. ⟨NNT : 2016PA066609⟩. ⟨tel-01547822⟩

  • Article dans une revue

Oscillatory Behavior of Pd-Au Catalysts in Toluene Total Oxidation

Tarek Barakat, Joanna Rooke, Dayan Chlala, Renaud Cousin, Jean-François Lamonier, Jean-Marc Giraudon, Sandra Casale, Pascale Massiani, Bao-Lian Su, Stéphane Siffert

In this work, the activity of bimetallic Pd-Au doped hierarchically structured titania catalysts has been investigated in the total oxidation of toluene. In earlier works, doping titania with group Vb metal oxides ensured an increased catalytic performance in the elimination of VOC molecules. A…

Catalysts, 2018, 8 (12), pp.574. ⟨10.3390/catal8120574⟩. ⟨hal-02311603⟩

  • Thèse

Catalysis assisted by plasmon, Catalyse assistée par plasmon

Iyad Sarhid

Metallic nanoparticles (NPs) have many applications in catalysis. Some of them (gold, silver, copper) have a visible absorption resulting from the excitation of the surface plasmon by an external electromagnetic field. In this project, we propose to couple the catalytic properties of gold-based…, Les nanoparticules (NPs) métalliques ont de nombreuses applications en catalyse. Certaines d’entre elles (or, argent, cuivre) présentent une absorption dans le visible résultant de l’excitation du plasmon de surface par un champ électromagnétique extérieur. Nous proposons dans ce projet de coupler…

Catalysis. Université Paris Saclay (COmUE), 2019. English. ⟨NNT : 2019SACLS227⟩. ⟨tel-02724739⟩

  • Article dans une revue

Approach for Plasmonic Based DNA Sensing: Amplification of the Wavelength Shift and Simultaneous Detection of the Plasmon Modes of Gold Nanostructures

Jolanda Spadavecchia, Alexandre Barras, Joël Lyskawa, Patrice Woisel, William Laure, Claire-Marie Pradier, Rabah Boukherroub, Sabine Szunerits

In this article, the detection of DNA hybridization taking advantage of the plasmonic properties of gold nanostructures is described. The approach is based on the amplification of the wavelength shift of a multilayered localized surface plasmon resonance (LSPR) sensor interface upon hybridization…

Analytical Chemistry, 2013, 85, pp.3288-3296. ⟨10.1021/ac3036316⟩. ⟨hal-00836615⟩

  • Article dans une revue

Impregnation of .gamma.-Alumina with Ni(II) or Co(II) Ions at Neutral pH: Hydrotalcite-Type Coprecipitate Formation and Characterization

Jean-Baptiste d'Espinose de la Caillerie, Maggy Kermarec, Olivier Clause

The adsorption of Co(II) or Ni(II) ammine complexes from aqueous solutions onto y-alumina at neutral or near neutral pH (7 < pH < 8.2) and ambient temperature is investigated as a function of the ion concentration in the impregnating solutions, the contact and aging times, and the drying…

Journal of the American Chemical Society, 1995, 117 (46), pp.11471-11481. ⟨10.1021/ja00151a010⟩. ⟨hal-03978150⟩

  • Thèse

Molecules at surfaces : formation, reactivity, assembly of (bio)molecules on external and internal surfaces of nanosized/nanostructured materials, Molécules aux surfaces : formation, réactivité, assemblage de (bio) molécules sur les surfaces externes et internes de matériaux nanométriques / nanostructurés

Ola El Samrout

This PhD thesis aims to deeply study the polymerization of Gly monomers on amorphous silica to better understand its reaction mechanism, kinetics, and parameters related to the nature of the condensation product obtained under different environmental conditions. In the first part, the behavior of…, Cette thèse vise à étudier en profondeur la polymérisation des monomères Gly sur de la silice amorphe afin de mieux comprendre son mécanisme réactionnel, sa cinétique et les paramètres liés à la nature du produit de condensation obtenu dans différentes conditions environnementales. Dans la première…

Material chemistry. Sorbonne Université; Università di Torino, 2023. English. ⟨NNT : 2023SORUS085⟩. ⟨tel-04138067⟩

  • Article dans une revue

Self-assembled multilayers based on native or denatured collagen: mechanism and synthesis of size-controlled nanotubes

Jessem Landoulsi, Sophie Demoustier-Champagne, Christine Dupont-Gillain

The mechanism of layer-by-layer (LbL) assembly using collagen, the major protein of the extracellular matrix, was investigated on flat substrates and in nanoporous templates, with a view to synthesize collagen-contg. nanotubes. The effect of parameters related to geometrical constraints (flat…

Soft Matter, 2011, 7 (7), pp.3337-3347. ⟨10.1039/C0SM00918K⟩. ⟨hal-00602942⟩