• Article dans une revue

Electrospray ionization: an efficient approach to deposit polymetallic molecular switches onto gold surfaces

Amina Benchohra, Christophe Méthivier, Jessem Landoulsi, David Kreher, Rodrigue Lescouëzec

Electrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule's integrity is monitored by PM-IRRAS and XPS. This approach broadens the perspective of molecular magnetic switches' deposition,…

Chemical Communications, 2020, 56 (48), pp.6587-6589. ⟨10.1039/D0CC01906B⟩. ⟨hal-02879959⟩

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Polyol Process Coupled to Cold Plasma as a New and Efficient Nanohydride Processing Method: Nano-Ni 2 H as a Case Study

Sonia Haj-Khlifa, Sophie Nowak, Patricia Beaunier, Patricia de Rango, Michaël Redolfi, Souad Ammar-Merah

An alternative route for metal hydrogenation has been investigated: cold plasma hydrogen implantation on polyol-made transition metal nanoparticles. This treatment applied to a challenging system, Ni-H, induces a reordering of the metal lattice, and superstructure lines have been observed by both…

Nanomaterials, 2020, 10 (1), pp.136. ⟨10.3390/nano10010136⟩. ⟨hal-02552297⟩

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Development of acidic sites in WOx/ZrO2

Thomas Onfroy, Guillaume Clet, Marwan Houalla

Evidence is shown of the appearance of Brønsted acidic sites in WOx/ZrO2 at a given W loading and of a direct correlation between the abundance of ‘strong’ Brønsted acidic sites in these catalysts and propan-2-ol decomposition activity.

Chemical Communications, 2001, 15, pp.1378-1379. ⟨10.1039/b102867g⟩. ⟨hal-02399977⟩

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Origins of Life and Molecular Information: Selectivity in Mineral Surface-Induced Prebiotic Amino Acid Polymerization

Lise Bedoin, Sandra Alves, Jean-François Lambert

ACS Earth and Space Chemistry, 2020, acsearthspacechem.0c00183. ⟨10.1021/acsearthspacechem.0c00183⟩. ⟨hal-03133031⟩

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Fischer-Tropsch reaction on Co-containing microporous and mesoporous Beta zeolite catalysts: the effect of porous size and acidity

Renata Sadek, Karolina Chalupka, Pawel Mierczynski, Jacek Rynkowski, Yannick Millot, Laetitia Valentin, Sandra Casale, Stanislaw Dzwigaj

This work deals with the investigation of the influence of the preparation procedure on the activity of microporous and mesoporous CoBeta zeolite in Fischer – Tropsch synthesis (FTS). The series of CoSiBeta, CoAlSiBeta and CoAlBeta zeolites were prepared by: i) two-step postsynthesis procedure (…

Catalysis Today, 2020, 354, pp.109-122. ⟨10.1016/j.cattod.2019.05.004⟩. ⟨hal-03987070⟩

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Accessibility of Co3O4 nanoparticles patterned in SBA-15

Irène Lopes, Nissrine El Hassan, Gilles Wallez, Cyril Thomas, Anne Davidson

Calibrated crystalline Co3O4 nanoparticles with a narrow size distribution were synthesized inside the pores of SBA-15 silicas and studied by HR-TEM, XRD and Raman spectroscopy. Preferential orientation and size-related structural modifications are revealed. The reactivity for CO oxidation and the…

Studies in Surface Science and Catalysis, 2007, 170B, pp.1213-1221. ⟨hal-00181050⟩

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Current state of electrochemical techniques and corrosion rate analysis for next-generation materials

Junsoo Han, Oumaïma Gharbi

Current theoretical models and electrochemical techniques used to investigate corrosion mechanisms, including corrosion rates, have been tailored for conventional alloy systems. However, the application of conventional theories and techniques toward next-generation alloys such as multi-principal…

Current Opinion in Electrochemistry, 2022, 36, pp.101131. ⟨10.1016/j.coelec.2022.101131⟩. ⟨hal-03776989⟩

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EIS investigation of zinc dissolution in aerated sulfate medium. Part I: bulk zinc

Chantal Cachet, F. Ganne, Georges Maurin, J. Petitjean, Vincent Vivier, Robert Wiart

The kinetics of anodic dissolution and corrosion of zinc are investigated by electrochemical impedance spectroscopy in sulfate medium for various surface preparation conditions and different experimental procedures. A new version of the reaction model, which was established previously, accounts…

Electrochimica Acta, 2001, 47 (3), pp.509-518. ⟨10.1016/S0013-4686(01)00740-X⟩. ⟨hal-04257763⟩

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Immobilization of Orange Carotenoid Protein on mesoporous silica SBA-15 for the development of photoactivable nanodevices

Silvia Leccese, Thomas Onfroy, Adjélé Wilson, Diana Kirilovsky, Sandra Casale, Saremblé Guira, Mohamed Selmane, Claude Jolivalt, Alberto Mezzetti

The photoactive Orange Carotenoid Protein (OCP) is a protein involved in photo-protective responses in cyanobacteria. It induces the thermal dissipation of excess solar energy counteracting oxidative stress and photodamage. OCP consists of two structural domains sharing a non-covalently linked…

Microporous and Mesoporous Materials, 2022, 340, pp.112007. ⟨10.1016/j.micromeso.2022.112007⟩. ⟨hal-03987135⟩

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Bifunctional Polyoxometalates for Planar Gold Surface Nanostructuration and Protein Immobilization

Dimitri Mercier, Souhir Boujday, Cyrine Annabi, Richard Villanneau, Claire-Marie Pradier, Anna Proust

Surface nanostructuration was successfully achieved by binding the polyoxometalate (POM) (NBu4)3[PW11O39{(SiC6H4NH2)2O}] covalently onto planar gold surfaces. To do so, POMs functionalized with two terminal amino groups were synthesized and reacted with a mercaptoundecanoic acid self-assembled…

Journal of Physical Chemistry C, 2012, 116 (24), pp.13217-13224. ⟨10.1021/jp3031623⟩. ⟨hal-04564848⟩