Laboratoire de réactivité de surface

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  • Article dans une revue

Bioconjugated gold nanorods to enhance the sensitivity of FT-SPR-based biosensors

Jolanda Spadavecchia, Sandra Casale, Souhir Boujday, Claire-Marie Pradier

n this paper, we report a feasible solvent-free approach for the synthesis and self-assembling of gold nanorods after bioconjugation to antibodies; scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images revealed a remarkable shape and size narrow distribution, as well…

Colloids and Surfaces B: Biointerfaces, 2012, 100, pp.1-8. ⟨10.1016/j.colsurfb.2012.03.035⟩. ⟨hal-00744490⟩

  • Article dans une revue

Effect of vanadium dispersion and support properties on the catalytic activity of V-SBA-15 and V-MCF mesoporous materials prepared by direct synthesis

Marco Piumetti, Barbara Bonelli, Pascale Massiani, Stanislaw Dzwigaj, Llenia Rossetti, Sandra Casale, Lucia Gaberova, Marco Armandi, Edorado Garrone

Direct synthesis route was developed to support TiO2-ZrO2 binary metal oxide onto the carbon templated mesoporous silicalite-1 (CS-1). Metal hydroxide modified carbon particles could play a role as hard template and simultaneously support metal components on the mesopores during the crystallization…

Catalysis Today, 2011, 176, pp.458-464. ⟨10.1016/j.cattod.2010.10.066⟩. ⟨hal-00667426⟩

  • Article dans une revue

Methanol oxidation on VSiBEA zeolites: Influence of V content on the catalytic properties

Marciej Tredja, Maria Ziolek, Yannick Millot, Karolina Chalupka, Michel Che, Stanislaw Dziwag

This study deals with the influence of V content on the catalytic properties of VxSiBEA zeolites in the oxidation of methanol. The samples are prepared following a postsynthesis method reported earlier (S. Dzwigaj, M.J. Peltre, P. Massiani, A. Davidson, M. Che, T. Sen, S. Sivasanker, Chem. Commun…

Journal of Catalysis, 2011, 281 (1), pp.169-176. ⟨10.1016/j.jcat.2011.04.013⟩. ⟨hal-00663368⟩

  • Article dans une revue

Study of the use of fluidized bed plasma reactors for the treatment of alumina supported palladium catalyst: Application for SCR NOx by CH4 in stationary sources

Marjorie Foix, Cedric Guyon, Michael Tatoulian, Patrick da Costa

Calcination is an important step in catalyst synthesis. This work examd. plasma treatment as an alternative to calcination, since it is a more energy efficient process. A radio frequency, fluidized bed plasma reactor was used for the pretreatment process with different gas mixts. (Ar and Ar/O2…

Catalysis Communications, 2010, 12 (1), pp.20-24. ⟨10.1016/j.catcom.2010.05.022⟩. ⟨hal-00604716⟩

  • Article dans une revue

Bioengineering of stainless steel surface by covalent immobilization of enzymes. Physical characterization and interfacial enzymatic activity

Anne Caro, Vincent Humblot, Christophe Methivier, Michel Minier, Lucica Barbes, Joachim Li, Michele Salmain, Claire-Marie Pradier

Two hydrolytic enzymes, namely lysozyme and trypsin, were covalently immobilized onto stainless steel surfaces using wet chemistry processes. The immobilization strategy took advantage of the spontaneous physisorption of the polymer poly(ethylene imine) (PEI) onto stainless steel to yield a firmly…

Journal of Colloid and Interface Science, 2010, 349 (1), pp.13-18. ⟨10.1016/j.jcis.2009.12.001⟩. ⟨hal-00604709⟩

  • Article dans une revue

Exhaust gas recirculation for on-board hydrogen production by isooctane reforming: Comparison of performances of metal/ceria-zirconia based catalysts prepared through pseudo sol-gel or impregnation methods are described

Emmanuelle Ambroise, Claire Courson, Anne-Cecile Roger, Alain Kiennemann, Gilbert Blanchard, Severine Rousseau, Xavier Carrier, Eric Marceau, Camille La Fontaine, Francoise Villain

Isooctane reforming under conditions which are set by exhaust gas can be used to generate H on-board. Isooctane reforming reactivity tests have been performed with bimetallic catalysts Co-noble metal/ceria-zirconia, prepd. either by insertion of transition metal in a ceria-zirconia matrix, either…

Catalysis Today, 2010, 154 (1-2), pp.133-141. ⟨10.1016/j.cattod.2009.12.010⟩. ⟨hal-00604698⟩

  • Article dans une revue

Highly porous and monodisperse magnetic silica beads prepared by a green templating method

Sebastien Abramson, Clementine Meiller, Patricia Beaunier, Vincent Dupuis, Laurent Perrigaud, Agnes Bee, Valerie Cabuil

We describe the prepn. of magnetic silica nanocomposite millimetric beads using alginate as a green biopolymer template. The simple and soft method which is used here is particularly suitable since the alginate template allows a multiscale control of the structure of the material, both its morphol…

Journal of Materials Chemistry, 2010, 20 (23), pp.4916-4924. ⟨10.1039/C000525H⟩. ⟨hal-00604697⟩

  • Article dans une revue

Insight into the structure and localization of the titania overlayer in TiO2-coated SBA-15 materials

Fu-Xiang Zhang, Xavier Carrier, Jean-Marc Krafft, Yu-Ji Yoshimura, Juliette Blanchard

Titania-coated SBA-15 materials (Ti-SBA-n with n = 1-4) were synthesized by successive grafting of titanium isopropoxide in iso-propanol. The investigation of the nature and localization of the TiO2 overlayer allowed us to conclude that there was formation of very small (UV-visible, EXAFS, XANES),…

New Journal of Chemistry, 2010, 34 (3), pp.508-516. ⟨10.1039/B9NJ00439D⟩. ⟨hal-00604815⟩

  • Article dans une revue

Polyol synthesis and magnetic study of Mn3O4 nanocrystals of tunable size

Lorette Sicard, Jean-Marc Le Meins, Christophe Methivier, Frederic Herbst, Souad Ammar

Nanosized manganese oxide particles were prepd. by the so-called polyol process. The av. diam. of the particles was controlled by the growth time. XRD, TEM and x-ray photon spectroscopy (XPS) show that the particles are well crystd., pure, stoichiometric Mn3O4 single crystals of uniform size…

Journal of Magnetism and Magnetic Materials, 2010, 322 (18), pp.2634-2640. ⟨10.1016/j.jmmm.2010.03.016⟩. ⟨hal-00604799⟩

  • Article dans une revue

Detailed crystal chemistry and iron topochemistry of asbestos occurring in its natural setting: A first step to understanding its chemical reactivity

A. Pacella, G. B. Andreozzi, Jeanine Fournier

Five samples of tremolite asbestos from Italy and USA were fully characterized by ICP-MS, SEM, EMPA, FT-IR, MS, XRPD, to correlate crystal chemistry with chemical reactivity. Iron topochemistry was investigated in detail, due to the role of Fe in the aetiology of respiratory inflammatory diseases.…

Chemical Geology, 2010, 277 (3-4), pp.197-206. ⟨10.1016/j.chemgeo.2010.07.018⟩. ⟨hal-00604789⟩