• Article dans une revue

Metallomics in deep time and the influence of ocean chemistry on the metabolic landscapes of Earth's earliest ecosystems

Keyron Hickman-Lewis, Barbara Cavalazzi, Stéphanie Sorieul, Pascale Gautret, Frédéric Foucher, Martin Whitehouse, Heejin Jeon, Thomas Georgelin, Charles Cockell, Frances Westall

Modern biological dependency on trace elements is proposed to be a consequence of their enrichment in the habitats of early life together with Earth's evolving physicochemical conditions; the resulting metallic biological complement is termed the metallome. Herein, we detail a protocol for…

Scientific Reports, 2020, ⟨10.1038/s41598-020-61774-w⟩. ⟨insu-02511006⟩

• Chapitre d'ouvrage

Structure and Surface Study of Hydroxyapatite-Based Materials: Experimental and Computational Approaches

Guylène Costentin, Christophe Drouet, Fabrice Salles, Stéphanie Sarda

In addition to designing catalytic materials ever more active and selective, the emergence of new classes of greener catalysts remains very challenging. The apatite family system with hydroxyapatite (HA) structure appears as a good candidate for catalysis due to its eco-compatibility properties,…

Design and Applications of Hydroxyapatite-Based Catalysts, 2022, ⟨10.1002/9783527830190.ch3⟩. ⟨hal-03727861⟩

• Article dans une revue

Long-Lived Charge-Separated States in ZnS/Na-MOR Zeolite upon <i>trans</i>-Stilbene Adsorption

Pedro Henrique Morais Andrade, Matthieu Hureau, Anne-Sophie Mamede, Pascale Massiani, Alexandre Legrand, Alain Moissette

Electron transfer (ET) processes are of fundamental importance in many photochemical processes in biological and chemical systems. Here, semiconductor nanoparticles of ZnS (as electron relay) and trans-stilbene molecules (t-St) (as electron donor), both confined within the porous volume of…

• Article dans une revue

Current state of electrochemical techniques and corrosion rate analysis for next-generation materials

Junsoo Han, Oumaïma Gharbi

Current theoretical models and electrochemical techniques used to investigate corrosion mechanisms, including corrosion rates, have been tailored for conventional alloy systems. However, the application of conventional theories and techniques toward next-generation alloys such as multi-principal…

Current Opinion in Electrochemistry, 2022, 36, pp.101131. ⟨10.1016/j.coelec.2022.101131⟩. ⟨hal-03776989⟩

• Article dans une revue

Phenylamine-functionalized mesoporous silica supported PdAg nanoparticles: a dual heterogeneous catalyst for formic acid/CO 2 -mediated chemical hydrogen delivery/storage

Kohsuke Mori, Shinya Masuda, Hiromasa Tanaka, Kazunari Yoshizawa, Michel Che, Hiromi Yamashita

PdAg nanoparticles supported on phenylamine-grafted mesoporous silica acted as a dual heterogeneous catalyst for the interconversion of H 2 and CO 2 .

Chemical Communications, 2017, 53 (34), pp.4677-4680. ⟨10.1039/C7CC00864C⟩. ⟨hal-04015748⟩

• Article dans une revue

Lipase-embedded Silica Nanoparticles with Oil-filled Core-Shell Structure: Stable and Recyclable Platforms for Biocatalysts

Yasutaka Kuwahara, Takato Yamanishi, Takashi Kamegawa, Kohsuke Mori, Michel Che, Hiromi Yamashita

Lipase enzyme was embedded within silica nanoparticles with oil-filled core-shell structure. The enzyme embedded within such architecture retained all of its activity and showed high catalytic performance both in water and in organic media with optimal stability and recyclability.

Chemical Communications, 2012, 48, pp.2882-4. ⟨10.1039/c2cc17896f⟩. ⟨hal-00744697⟩

• Article dans une revue

Coordination chemistry approach for the end-to-end assembly of gold nanorods

P.R. Selvakannan, Eddy Dumas, Frédéric Dumur, Christine Péchoux, Patricia Beaunier, Arnaud Etcheberry, Francis Secheresse, Hynd Remita, Cédric Mayer

Gold nanorods synthesized by radiolysis were selectively end-functionalized by a fully conjugated thiol bearing a pendant terpyridine group; addition of ferrous ions led to the end-to-end 1D self-assembly of the nanorods. Similar results have been obtained when the preformed [(HStpy)Fe(tpySH)](2+)…

Journal of Colloid and Interface Science, 2010, 349, pp.93-97. ⟨10.1016/j.jcis.2010.05.050⟩. ⟨hal-02665342⟩

• Communication dans un congrès

Combined fungal and chemical pretreatment of lignocellulosic biomass for biogas production: Effect of pretreatment order and fungal strains

Shruthi Meenakshisundaram, Vincenzo Calcagno, Claire Ceballos, Antoine Fayeulle, Estelle Léonard, Virginie Herledan, Jean-Marc Krafft, Yannick Millot, Xiaojun Liu, Claude Jolivalt, André Pauss

The recalcitrance of lignocellulosic poses a challenge for conversion to biogas and therefore, pretreatment is an essential step in addressing this. Combining fungal pretreatment with a biomimetic system, a mild Fenton reaction, was studied to improve the methane production from straw. The…

18th IWA World Conference on Anaerobic Digestion, Istanbul Technical University, Jun 2024, Istanbul, Turkey. ⟨hal-04618500⟩

• Article dans une revue

Semiconductor quantum dots reveal dipolar coupling from exciton to ligand vibration

T. Noblet, L. Dreesen, S. Boujday, C. Methivier, Bertrand Busson, A. Tadjeddine, Christophe Humbert

Within semiconductor quantum dots (QDs), exciton recombination processes are noteworthy for depending on the nature of surface coordination and nanocrystal/ligand bonding. The influence of the molecular surroundings on QDs optoelectronic properties is therefore intensively studied. Here, from the…

Communications Chemistry, 2018, 1, pp.76. ⟨10.1038/s42004-018-0079-y⟩. ⟨hal-02111047v2⟩

• Article dans une revue

Hydroxyapatite: A Matrix for Metal Exsolution Leading to Highly Dispersed Catalytically Active Species

Josefine Schnee, Ferdaous Ben Romdhane, François Devred, Antoine Miche, Alixandre Magerat, Diane Reja, Eric Gaigneaux, Marco Daturi, Cyril Thomas, Guylène Costentin

Hydroxyapatite (Ca10(PO4)6(OH)2, or HAp) -the main mineral component of bones and teeth -is a material of great interest not only in biomedical applications but also in heterogeneous catalysis. Its framework Ca 2+ cations can be substituted by a wide variety of catalytically active metals (Cu 2+ ,…

Chemistry of Materials, 2024, 36 (3), pp.1188-1196. ⟨10.1021/acs.chemmater.3c01749⟩. ⟨hal-04747806⟩