Laboratoire de réactivité de surface

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  • Article dans une revue

Should W Surface Density of WOx-ZrO2 Catalysts Be Calculated With Respect To the Specific Surface Area of the Sample or That of ZrO2 Only?

Cyril Thomas

On the basis of the critical analysis of the NOx-TPD data obtained on WOx-ZrO2 samples [Law, H. Y.; Blanchard, J.; Carrier, X.; Thomas, C. J. Phys. Chem. C 2010, 114, 9731], this work provides convincing arguments for the first time upon which calculation of W surface density should be done by…

Journal of Physical Chemistry C, 2011, 115 (5), pp.2253-2256. ⟨10.1021/jp110497e⟩. ⟨hal-00602957⟩

  • Article dans une revue

In Vitro Cytotoxicity and Transforming Potential of Industrial Carbon Dust (Fibers and Particles) in Syrian Hamster Embryo (SHE) Cells

C. Darne, F. Terzetti, C. Coulais, Jeanine Fournier, Y. Guichard, L. Gate, S. Binet

Carbon fibers have many applications, mainly in high-tech industries such as the aviation industry. Eleven carbon samples (fibers and particles) coming from an aeronautic group were tested for their cytotoxicity and carcinogenic potential using in vitro short-term assays in Syrian hamster embryo…

Annals of Occupational Hygiene, 2010, 54 (5), pp.532-544. ⟨10.1093/annhyg/meq012⟩. ⟨hal-00604711⟩

  • Article dans une revue

Accessibility of Co3O4 nanoparticles patterned in SBA-15

Irène Lopes, Nissrine El Hassan, Gilles Wallez, Cyril Thomas, Anne Davidson

Calibrated crystalline Co3O4 nanoparticles with a narrow size distribution were synthesized inside the pores of SBA-15 silicas and studied by HR-TEM, XRD and Raman spectroscopy. Preferential orientation and size-related structural modifications are revealed. The reactivity for CO oxidation and the…

Studies in Surface Science and Catalysis, 2007, 170B, pp.1213-1221. ⟨hal-00181050⟩

  • Article dans une revue

Immobilization of polyoxometalate hybrid catalysts onto mesoporous silica supports using phenylene diisothiocyanate as a cross-linking agent

Ourania Makrygenni, Dalil Brouri, Anna Proust, Franck Launay, Richard Villanneau

The hybrid derivative of heteropolytungstate bearing two aniline groups, namely (nBu4N)3[NaHPW9O34{As(O)C6H4NH2}2], was post-functionalized in the presence of 1,4-phenylene diisothiocyanate (PDITC). The resulting molecular moiety was characterized by IR, 1H and 31P NMR spectroscopy. In a second…

Microporous and Mesoporous Materials, 2018, 278, pp.314-321. ⟨10.1016/j.micromeso.2018.11.036⟩. ⟨hal-02143825⟩

  • Article dans une revue

One-Pot Radiolytic Synthesis of Gold Nanorods and Their Optical Properties

Wafa Abidi, P. R. Selvakannan, Yanick Guillet, Isabelle Lampre, Patricia Beaunier, Brigitte Pansu, Bruno Palpant, Hynd Remita

A novel one-pot synthesis method to prepare gold nanorods of different aspect ratios using radiolysis is presented. The gold nanorods are synthesized by radiolytic reduction of Au-III complexes in a micellar solution formed by a mixture of cationic surfactants (cetyltrimethylammonium bromide and…

Journal of Physical Chemistry C, 2010, 114 (35), pp.4794-14803. ⟨10.1021/jp104819c⟩. ⟨hal-00833023⟩

  • Article dans une revue

Palladium loaded BEA zeolites as efficient catalysts for aqueous-phase diclofenac hydrodechlorination

Bartosz Zawadzki, Emil Kowalewski, Monika Asztemborska, Krzysztof Matus, Sandra Casale, Stanislaw Dzwigaj, Anna Śrębowata

Herein the catalytic performance of two 1 wt% Pd loaded BEA zeolites with Si/Al ratio of 19 and 1300 were investigated for the aqueous phase hydrodechlorination (HDC) of diclofenac, the latter compound a prevalent nonsteroidal anti-inflammatory drug. 1 wt%Pd/SiO2 and 1 wt%Pd/Al2O3 being commonly…

Catalysis Communications, 2020, 145, pp.106113. ⟨10.1016/j.catcom.2020.106113⟩. ⟨hal-03014314⟩

  • Article dans une revue

CO2-assisted Dehydrogenation of Propane to Propene over Zn-BEA Zeolites: Impact of Acid-Base Characteristics on Catalytic Performance

Svitlana Orlyk, Pavlo Kyriienko, Andriy Kapran, Valeriy Chedryk, Dmytro Balakin, Jacek Gurgul, Yannick Millot, Stanislaw Dzwigaj

The research results about the influence of BEA zeolite preliminary dealumination on the acid-base characteristics and catalytic performance of 1%Zn-BEA compositions in propane dehydrogenation with CO2 are presented. The catalyst samples, prepared by a two-step post-synthesis procedure, involving…

Catalysts, 2023, 13 (4), pp.681. ⟨10.3390/catal13040681⟩. ⟨hal-04201435⟩

  • Article dans une revue

Silver-Based Plasmonic Nanoparticles for and Their Use in Biosensing

Alexis Loiseau, Victoire Asila, Gabriel Boitel-Aullen, Mylan Lam, Michèle Salmain, Souhir Boujday

The localized surface plasmon resonance (LSPR) property of metallic nanoparticles is widely exploited for chemical and biological sensing. Selective biosensing of molecules using functionalized nanoparticles has become a major research interdisciplinary area between chemistry, biology and material…

Biosensors, 2019, 9 (2), pp.78. ⟨10.3390/bios9020078⟩. ⟨hal-02379984⟩

  • Article dans une revue

Enzyme-assisted mineralization of calcium phosphate: exploring confinement for the design of highly crystalline nano-objects

E. Colaço, D. Lefèvre, E. Maisonhaute, D. Brouri, C. Guibert, C. Dupont-Gillain, Karim El Kirat, S. Demoustier-Champagne, J. Landoulsi

In hard tissues of vertebrates, calcium phosphate (CaP) biomineralization is a fascinating process that combines specific physicochemical and biochemical reactions, resulting in the formation of extracellular matrices with elegant nanoarchitectures. Although several “biomimetic” strategies have…

Nanoscale, 2020, 12 (18), pp.10051-10064. ⟨10.1039/d0nr01638a⟩. ⟨hal-03266105⟩

  • Article dans une revue

Bimetallic Ni-Zn/TiO2 catalysts for selective hydrogenation of alkyne and alkadiene impurities from alkenes stream

Zhao Wang, Guillaume Wang, Catherine Louis, Laurent Delannoy

This study investigates the alternative of replacing noble metals by base metals as catalysts for selective hydrogenation of polyunsaturated hydrocarbons. Nickel catalysts are active for this type of reaction, but poorly selective. However, former calculations anticipated that Ni-Zn alloys could…

Research on Chemical Intermediates, 2021, 47 (1), pp.91-116. ⟨10.1007/s11164-020-04327-0⟩. ⟨hal-03146611⟩