Laboratoire de réactivité de surface

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  • Article dans une revue

Conversion of xylene over mordenites: an operando infrared spectroscopy study of the effect of Na+

Pascale Massiani, Olivier Marie, Frédéric Thibault-Starzyk

A series of progressively proton-exchanged sodium mordenite samples was studied by operando infrared spectroscopy during xylene conversion. This unique, powerful tool allowed us to characterize the species adsorbed to the surface during catalysis and to follow the evolution of the active sites as…

Journal of Catalysis, 2004, 230, pp.28-37. ⟨hal-00126974⟩

  • Article dans une revue

Structural studies of adsorbed protein (betalactoglobulin) on natural clay (montmorillonite)

Ali Assifaoui, Lucie Huault, Cyrielle Maissiat, Chloé Roullier-Gall, Philippe Jeandet, Jerôme Hirschinger, Jesus Raya, Maguy Jaber, Jean-François Lambert, Philippe Cayot, Régis Gougeon, Camille Loupiac

In this work, the adsorption of a small globular protein (betalactoglobulin, BLG), on a natural montmorillonite clay (Mt) was investigated in acidic buffer (pH = 3). The combination of different characterization techniques such as zetametry, X-ray diffraction, transmission electronic microscopy,…

RSC Advances, 2014, 4 (105), pp.61096-61103. ⟨10.1039/C4RA11607K⟩. ⟨hal-02358967⟩

  • Article dans une revue

Mechanistic Study of Cast and 3D-Printed Stainless Steel Electropolishing in Acid Media and Deep Eutectic Solvents

Chloé Rotty, Marie-Laure Doche, Audrey Mandroyan, Vincent Vivier, Jean-Yves Hihn

The mechanistic analysis of the electropolishing procedure of stainless steel (SS) was revisited using electrochemical impedance spectroscopy. Firstly, the control of the dissolution reaction by diffusion was confirmed with the linear dependence of the limiting current density as a function of the…

Journal of The Electrochemical Society, 2022, 169 (7), pp.071504. ⟨10.1149/1945-7111/ac7bb3⟩. ⟨hal-04294211⟩

  • Article dans une revue

Controlling the Nanocontact Nature and the Mechanical Properties of a Silica Nanoparticle Assembly

J. Avice, C. Boscher, G. Vaudel, G. Brotons, V. Juvé, M. Edely, C. Methivier, Vitali Goussev, P. Belleville, H. Piombini, P. Ruello

Elaborating advanced nanomaterials based on the assembly of nanoparticles (NPs) is a versatile route for targeting and tuning a wide variety of properties like optical, magnetic, and electrical properties or sensing. This route usually employs a so-called soft chemistry which has the advantage of…

Journal of Physical Chemistry C, 2017, 121 (42), pp.23769-23776. ⟨10.1021/acs.jpcc.7b08404⟩. ⟨hal-02536813⟩

  • Thèse

Elaboration de catalyseurs hétérogènes en milieu liquide ionique : nanoparticules métalliques (Au et Au-Pd) supportées sur dioxyde de titane, Heterogeneous catalysts preparation in ionic liquid media : titania-supported metallic nanoparticles (Au and Au-Pd)

Camella Oumahi

Ces travaux portent sur l'élaboration de catalyseurs hétérogènes en milieu liquide ionique (LI). Ces sels liquides à température ambiante permettent d'ajuster les propriétés du solvant suivant la composition chimique du LI mis en jeu (sels d'imidazolium ou Deep Eutectic Solvent à…, This work deals with the elaboration of heterogeneous catalysts in ionic liquids (ILs). These salts, liquid at room temperature, were chosen because they permit to adjust the solvent properties depending on their chemical composition (imidazolium salts or Deep Eutectic Solvent based on choline…

Chimie-Physique [physics.chem-ph]. Université Pierre et Marie Curie - Paris VI, 2014. Français. ⟨NNT : 2014PA066503⟩. ⟨tel-01144886⟩

  • Article dans une revue

Effect of pH on the incorporation of acrylic acid units in the core of polymer nanoparticles prepared by PISA and on their morphology

Clément Debrie, Noémie Coudert, Jean-Michel Guigner, Fanny Coumes, Clément Guibert, Simon Harrisson, François Stoffelbach, Olivier Colombani, Jutta Rieger

Polymerization-induced self-assembly (PISA) is a polymerization process in which amphiphilic block copolymers are simultaneously synthesized and self-assembled in a selective solvent, leading to nanoparticles of different morphologies. Copolymerization has been reported as a means to tune…

Polymer Chemistry, 2024, 15 (24), pp.2462-2475. ⟨10.1039/D4PY00373J⟩. ⟨hal-04649351⟩

  • Article dans une revue

Enhancing the magnetic anisotropy of maghemite nanoparticles via the surface coordination of molecular complexes

Yoann Prado, Niéli Daffé, Aude Michel, Thomas Georgelin, Nader Yaacoub, Jean-Marc Greneche, Fadi Choueikani, Edwige Otero, Philippe Ohresser, Marie-Anne Arrio, C. Cartier Dit Moulin, Ph. Sainctavit, Benoit Fleury, Vincent Dupuis, Laurent Lisnard, Jérôme Fresnais

Superparamagnetic nanoparticles are promising objects for data storage or medical applications. In the smallest—and more attractive—systems, the properties are governed by the magnetic anisotropy. Here we report a molecule-based synthetic strategy to enhance this anisotropy in sub-10-nm…

Nature Communications, 2015, 6, pp.10139. ⟨10.1038/ncomms10139⟩. ⟨hal-01390543⟩

  • Article dans une revue

Fully controlled precipitation of photomagnetic CoFe Prussian blue analogue nanoparticles within the ordered mesoporosity of silica monoliths

Giulia Fornasieri, Merwen Aouadi, Pierrick Durand, Patricia Beaunier, Eric Rivière, Anne Bleuzen

The porosity of ordered mesoporous silica monoliths has been successfully used as nanoreactor for the elaboration of CoFe Prussian blue analogue nanoparticles. The nanocomposite exhibits a reversible photomagnetic effect different from that of typical powdered compounds due to particle size…

Chemical Communications, 2010, 46 (42), pp.8061. ⟨10.1039/c0cc02439b⟩. ⟨hal-05469294⟩

  • Thèse

Nanoparticules d’oxydes de fer et de ferrites obtenues par nano-réplication : réactivité chimique et application en dépollution des eaux, Iron oxides and ferrites quantum-dots obtained by nano-replication, chemical reactivity and application for water depollution

Nabil Tabaja

Cette thèse a été réalisée dans le cadre d’une cotutelle de thèse (3 ans) Franco-Libanaise entre l’Université Pierre et Marie Curie de Paris et l’Université Libanaise de Beyrouth. Nabil Tabaja a été entièrement financé par le Groupe de Recherche MAPE (Nanosized Porous Materials, Preparation,…, This thesis was carried out as part of a Franco-Lebanese collaboration thesis (3 years) between the University of Pierre et Marie Curie in Paris and the Lebanese University in Beirut. Nabil Tabaja was fully funded by the Research Group MAPE (nanosized Porous Materials, Preparation, Advanced…

Chimie analytique. Université Pierre et Marie Curie - Paris VI; Université Libanaise. Faculté des Sciences (Beyrouth, Liban), 2015. Français. ⟨NNT : 2015PA066315⟩. ⟨tel-01255306⟩

  • Thèse

Investigation of the plate-impact method as a precursor of physical phenomena and chemical processes, L'étude de la méthode de l'impact par plaque comme précurseur des phénomènes physiques et des processus chimiques

Maya Mounir Daou

This manuscript aims at characterizing a new device based on a plate impact on a liquid surface to generate cavitation and evaluate its potential to induce chemical reactions. The device is composed of a reactor containing a liquid that a piston hits due to pressure difference. This impact…, Ce manuscrit a pour but d'étudier un nouveau dispositif générateur de cavitation dont le potentiel favorable à l'intensification de réactions chimiques est évalué. Ce dispositif est constitué d'une plaque mobile qui frappe un liquide contenu dans un réacteur. L'impact génère une…

Chemical and Process Engineering. Université Pierre et Marie Curie - Paris VI, 2017. English. ⟨NNT : 2017PA066245⟩. ⟨tel-01692697v2⟩