Laboratoire de réactivité de surface

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  • Article dans une revue

Fluorescent core-shell nanoparticles and nanocapsules using comb-like macromolecular RAFT agents: synthesis and functionalization thereof

Chloé Grazon, Jutta Rieger, Patricia Beaunier, Rachel Méallet-Renault, Gilles Clavier

Fluorescent nanoparticles and nanocapsules (FNPs) were synthesized via a one-pot RAFT miniemulsion process copolymerizing BODIPY-methacrylate and styrene in water. Ultra-bright sub-100 nm core–shell nanoparticles could be obtained with BODIPY covalently linked in the core, and possessing various…

Polymer Chemistry, 2016, 7 (25), pp.4272 - 4283. ⟨10.1039/C6PY00646A⟩. ⟨hal-01547927⟩

  • Article dans une revue

Boosting CO2 reforming of methane via the metal-support interaction in mesostructured SBA-16-derived Ni nanoparticles

Chao Sun, Paulina Summa, Ye Wang, Katarzyna Świrk, Albert Miró I Rovira, Sandra Casale, Konrad Świerczek, Changwei Hu, Magnus Rønning, Patrick da Costa

High surface area and porosity SBA-16 was synthesized and used as support for Ni nanoparticles using three methods including wet impregnation, citric acid-assisted impregnation, and ammonia evaporation. All the studied samples showed high activity in the CO2 reforming of methane reaction, however,…

Applied Materials Today, 2022, 26, pp.101354. ⟨10.1016/j.apmt.2021.101354⟩. ⟨hal-04030144⟩

  • Article dans une revue

A new route for preparing nanoporous Cu–Zn–Ni–Co alloy by electrodeposition and dealloying: Application as electrocatalysts for water reduction

Yuelin Xie, Antoine Miche, Vincent Vivier, Mireille Turmine

<div><p>Nanoporous Cu-Zn-Ni-Co alloys have been prepared on Cu foils by a two-step electrodeposition mechanism in ethylammonium nitrate (EAN), a protic ionic liquid, and ethaline, a deep eutectic solvent (DES). A porous alloy was then produced using a dealloying step. The…

International Journal of Hydrogen Energy, 2025, 127, pp.95 - 106. ⟨10.1016/j.ijhydene.2025.04.067⟩. ⟨hal-05041651⟩

  • Article dans une revue

The genesis of a heterogeneous catalyst: in situ observation of a transition metal complex adsorbing onto an oxide surface in solution

Antoine Hervier, Juliette Blanchard, Guylène Costentin, John R. Regalbuto, Catherine Louis, Souhir Boujday

Understanding the interactions between metal complexes and oxide surfaces is crucial to the synthesis of supported metal catalysts. Recently developed in situ techniques have made it possible to closely characterize the solid/liquid interface. For the first time, the adsorption of platinum…

Chemical Communications, 2014, 50, pp.2379-2548. ⟨10.1039/C3CC48838A⟩. ⟨hal-00982311⟩

  • Article dans une revue

Tuning Model Drug Release and Soft-Tissue Bioadhesion of Polyester Films by Plasma Post-Treatment

Vishal T. Mogal, Chaw Su Yin, Richard O’rorke, Souhir Boujday, Christophe Méthivier, Subbu S. Venkatraman, Terry W. J. Steele

lasma treatments are investigated as a post-production method of tuning drug release and bioadhesion of poly(lactic-co-glycolic acid) (PLGA) thin films. PLGA films were treated under varying conditions by controlling gas flow rate, composition, treatment time, and radio frequency (RF) power. In…

ACS Applied Materials & Interfaces, 2014, 6 (8), pp.5749-58. ⟨10.1021/am500454b⟩. ⟨hal-01132700⟩

  • Article dans une revue

Probing the Orientation of β-Lactoglobulin on Gold Surfaces Modified by Alkyl Thiol Self-Assembled Monolayers

Victor Lebec, Jessem Landoulsi, Souhir Boujday, C. Poleunis, Claire-Marie Pradier, A. Delcorte

The adsorption of a globular protein on chemically well controlled surfaces was investigated in order to correlate its orientation to the surface properties. To this end, three different alkyl thiols, differing by their end group (−COOH, −CH3, and −NH2), were used to build up self-assembled…

Journal of Physical Chemistry C, 2013, 117, pp.11569-11577. ⟨10.1021/jp311964g⟩. ⟨hal-00918524⟩

  • Article dans une revue

Photoelectrochemical properties of nanocrystalline ZnS discrete versus continuous coating of ZnO nanorods prepared by electrodeposition

A. Brayek, S. Chaguetmi, M. Ghoul, I. Ben Assaker, A. Souissi, L. Mouton, P. Beaunier, S. Nowak, F. Mammeri, R. Chtourou, S. Ammar

We developed nanostructured photoanodes for photoelectrochemical (PEC) water splitting and hydrogen generation. They are based on ZnO nanorods electrodeposited on conductive ITO glass on which ZnO@ZnS heterojunctions were formed using two different approaches. In the first case, the ZnO nanorods…

RSC Advances, 2016, 6 (37), pp.30919 - 30927. ⟨10.1039/C5RA22951K⟩. ⟨hal-01547856⟩

  • Article dans une revue

Alternative ball-milling synthesis of vanadium-substituted polyoxometalates as catalysts for the aerobic cleavage of C–C and C–O bonds

Louay Al-Hussaini, Sabine Valange, Maria Elena Gálvez, Franck Launay

Ball-milling-based synthesis of vanadium-substituted phosphomolybdic acid enables energy saving while improving the yield and providing active catalysts for aerobic oxidative cleavage.

Dalton Transactions, 2021, 50 (37), pp.12850-12859. ⟨10.1039/D1DT01585K⟩. ⟨hal-04025223⟩

  • Communication dans un congrès

Ionic liquids as environmentally friendly corrosion inhibitors : the inhibition of mechanism of butylammonium nitrate for Al AA2024-T6

Oumaïma Gharbi, Abdelmoheiman Zakaria Benbouzid, Mai T.T. Tran, Mireille Turmine, Vincent Vivier

Ionic liquids are a promising class of solvent exhibiting a large panel of attractive physico-chemical properties, which can be of interest for energy, electrocatalysis or corrosion protection applications. Therefore, in the context of European restriction REACH regulation towards chromate-based…

72rd ISE Meeting, ISE, Aug 2021, Jeju Island, South Korea. ⟨hal-04013568⟩

  • Article dans une revue

Co-grafting of amino-poly(ethylene glycol) and Magainin I on a TiO2 surface: tests of antifouling and antibacterial activities.

Jessie Peyre, V. Humblot, C. Méthivier, J.M. Berjeaud, C.-M. Pradier

An antimicrobial peptide, Magainin I (Mag), was grafted to a titanium oxide surface, via an antiadhesive poly(ethylene glycol) (PEG) cross-linker. The latter plays a 2-fold part, being antiadhesive, and enabling the covalent immobilization of the peptide. The functionalization was characterized at…

Journal of Physical Chemistry B, 2012, 116, pp.13839-47. ⟨10.1021/jp305597y⟩. ⟨hal-00808576⟩