Laboratoire de réactivité de surface

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  • Article dans une revue

Chiral Ammonium-Capped Rhodium(0) Nanocatalysts: Synthesis, Characterization, and Advances in Asymmetric Hydrogenation in Neat Water

Elodie Guyonnet Bil É, Elodie Cortelazzo-Polisini, Audrey Denicourt-Nowicki, Rita Sassine, Franck Launay, Alain Roucoux

Optically active amphiphilic compounds derived from N-methylephedrine, N-methylprolinol, or cinchona derivatives possessing bromide or chiral lactate counterions were efficiently used as protective agents for rhodium(0) nanoparticles. The full characterization of these surfactants and the obtained…

ChemSusChem, 2012, 5, pp.91-101. ⟨10.1002/cssc.201100364⟩. ⟨hal-00750000⟩

  • Article dans une revue

Synthesis, characterization and catalytic activity of meso-niobium phosphate in the oxidation of benzyl alcohols

Michèle C. Reis, Suellen D.T. Barros, Elizabeth R. Lachter, Rosane A.S. San Gil, Jhonny H. Flores, Maria I. Pais da Silva, Thomas Onfroy

In this work mesoporous niobium phosphate was synthesized hydrothermally by using SDS as the structure directing agent. The catalysts were characterized by N2 adsorption, DRX, 31P MAS NMR and FTIR. The activity of commercial and synthesized niobium phosphate catalysts were evaluated through the…

Catalysis Today, 2012, 192, pp.117-122. ⟨10.1016/j.cattod.2012.05.025⟩. ⟨hal-00751901⟩

  • Article dans une revue

Structural studies of adsorbed protein (betalactoglobulin) on natural clay (montmorillonite)

Ali Assifaoui, Lucie Huault, Cyrielle Maissiat, Chloé Roullier-Gall, Philippe Jeandet, Jerôme Hirschinger, Jesus Raya, Maguy Jaber, Jean-François Lambert, Philippe Cayot, Régis Gougeon, Camille Loupiac

In this work, the adsorption of a small globular protein (betalactoglobulin, BLG), on a natural montmorillonite clay (Mt) was investigated in acidic buffer (pH = 3). The combination of different characterization techniques such as zetametry, X-ray diffraction, transmission electronic microscopy,…

RSC Advances, 2014, 4 (105), pp.61096-61103. ⟨10.1039/C4RA11607K⟩. ⟨hal-02358967⟩

  • Poster de conférence

Chemical evolution of organic molecules under Mars-like UV radiation conditions simulated in the laboratory with the MOMIE setup

O. Poch, Patrice Coll, Cyril Szopa, F. Stalport, T. Georgelin, M. Jaber, J.F. Lambert

The search for organic carbon at the surface of Mars, as clues of past habitability or remnants of life, is a major science goal of Mars' exploration. Understanding the chemical evolution of organic molecules under current Martian environmental conditions is essential to support the past,…

Eighth International Conference on Mars, Jul 2014, Pasadena, United States. pp.abstract 1228, 2014. ⟨hal-01139973⟩

  • Article dans une revue

Cysteine-montmorillonite composites for heavy metal cation complexation: A combined experimental and theoretical study

Khaled El Adraa, Thomas Georgelin, Jean-François Lambert, Farouk Jaber, Frederik Tielens, Maguy Jaber

Green composites based on montmorillonite (Mt) and cysteine, were prepared for heavy metal removal. A comparison between the adsorption properties of the resulting hybrid inorganic-organic materials and the pure montmorillonite was carried out for the following heavy metal cations Cd2+, Hg2+, Pb2…

Chemical Engineering Journal, 2017, 314, pp.406 - 417. ⟨10.1016/j.cej.2016.11.160⟩. ⟨hal-01490419⟩

  • Article dans une revue

Triple structuration and enhanced corrosion performance of 316L in Laser-Powder Bed Fusion

Alexis Fouchereau, Hicham Maskrot, Fernando Lomello, Sophie Bosonnet, Oumaïma Gharbi, Benoit Gwinner, Pierre Laghoutaris, Frédéric Schuster, Vincent Vivier, Beatriz Puga

This work focuses on the influence of the feedstock powders on the microstructural properties and corrosion behavior of 316L stainless steel (SS) produced by laser powder bed fusion (L-PBF) from two different suppliers. Microstructural investigations conducted after additive manufacturing reveal…

Corrosion Science, 2024, 228, pp.111830. ⟨10.1016/j.corsci.2024.111830⟩. ⟨cea-04602059⟩

  • Article dans une revue

Preparation of niobium-based oxygen carriers by polyol-mediated process and application to chemical-looping reforming

Pedro Henrique Lopes Nunes Abreu dos Santos, Sophie Nowak, Stéphanie Lau-Truong, Juliette Blanchard, Patricia Beaunier, José Augusto Jorge Rodrigues, Roberta Brayner

New niobium-based oxygen carriers were prepared adopting polyol-mediated process. Four different polyols were used (diethylene glycol, triethylene glycol, tetraethylene glycol, and 1,2-propanediol) and four different quantities of water (0 mL, 1 mL, 10 mL, 30 mL, with a total volume of 80 mL of…

Journal of Nanoparticle Research, 2019, 21 (5), ⟨10.1007/s11051-019-4528-z⟩. ⟨hal-02375304⟩

  • Thèse

Etude du front de minéralisation du tissu osseux et des modèles biomimétiques associés, Study of the mineralization front in bone tissue and in biomimetic models

Marc Robin

Les travaux réalisés ont pour but de répondre à deux questions : comment le collagène s'organise-t-il dans l'os mature ? Comment la phase minérale de l'os se forme-t-elle et quel est l'effet de son environnement sur sa formation ? Nous avons étudié d'un point de vue…, This work aims to understand: How is reached the plywood architecture in bone? How is bone apatite formed and what is the effect of the environment on apatite formation? Thus, histological bone thin sections were investigated focusing on the interface between the osteoid and mature bone tissues.…

Chimie thérapeutique. Université Pierre et Marie Curie - Paris VI, 2016. Français. ⟨NNT : 2016PA066635⟩. ⟨tel-01907278v2⟩

  • Article dans une revue

Should W Surface Density of WOx-ZrO2 Catalysts Be Calculated With Respect To the Specific Surface Area of the Sample or That of ZrO2 Only?

Cyril Thomas

On the basis of the critical analysis of the NOx-TPD data obtained on WOx-ZrO2 samples [Law, H. Y.; Blanchard, J.; Carrier, X.; Thomas, C. J. Phys. Chem. C 2010, 114, 9731], this work provides convincing arguments for the first time upon which calculation of W surface density should be done by…

Journal of Physical Chemistry C, 2011, 115 (5), pp.2253-2256. ⟨10.1021/jp110497e⟩. ⟨hal-00602957⟩

  • Article dans une revue

Electrospray ionization: an efficient approach to deposit polymetallic molecular switches onto gold surfaces

Amina Benchohra, Christophe Méthivier, Jessem Landoulsi, David Kreher, Rodrigue Lescouëzec

Electrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule's integrity is monitored by PM-IRRAS and XPS. This approach broadens the perspective of molecular magnetic switches' deposition,…

Chemical Communications, 2020, 56 (48), pp.6587-6589. ⟨10.1039/D0CC01906B⟩. ⟨hal-02879959⟩