• Article dans une revue

Skeletal Au prepared from Au-Zr amorphous alloys with controlled atomic compositions and arrangement for active oxidation of benzyl alcohol

Ai Nozaki, Yasutomo Tanihara, Yasutaka Kuwahara, Tetsutaro Ohmichi, Kohsuke Mori, Takeshi Nagase, Hiroyuki Y. Yasuda, Christophe Calers, Catherine Louis, Hiromi Yamashita

Skeletal (nanoporous) gold catalysts were prepared from Au–Zr amorphous alloys by immersion in HF solution to extract Zr moieties. The catalytic performance of the skeletal Au catalyst for the oxidation of benzyl alcohol to benzaldehyde was examined using O2 as an oxidant. The amount of…

Journal of Materials Chemistry A, 2016, 4 (21), pp.8458 - 8465. ⟨10.1039/C6TA01963C⟩. ⟨hal-01548324⟩

• Thèse

Towards a new concept of a proton battery, Vers un nouveau concept de batterie protonique

Ekaterina Kurchavova

Ni-MH battery is widely used energy storage systems, which are recognized for their good cyclability, competitive energy density, low memory effect, wide range of operating temperatures, low cost, and environmental friendliness. Despite these notable advantages, their widespread adoption is still…, Les batteries Ni-MH sont des systèmes de stockage d'énergie largement utilisés qui sont reconnues pour leur bonne cyclabilité, une densité énergétique compétitive, un faible effet mémoire, une large gamme de températures de fonctionnement, un faible coût et leur respect de l'environnement…

Analytical chemistry. Sorbonne Université, 2023. English. ⟨NNT : 2023SORUS448⟩. ⟨tel-05313648⟩

• Article dans une revue

Giant Exchange-Bias in Polyol-Made CoFe2O4-CoO Core-Shell Like Nanoparticles

Nancy Flores-Martinez, Giulia Franceschin, Thomas Gaudisson, Patricia Beaunier, Nader Yaacoub, Jean-Marc Greneche, Raul Valenzuela, Souad Ammar

Cobalt ferrite ferrimagnetic nanoparticles (NPs) are prepared and used in this work as seeds to grow a thin antiferromagnetic poly- and nanocrystalline CoO shell. The major purpose is to study systematically the characteristics of the as-produced powders, making emphasis on their internal…

Particle & Particle Systems Characterization, 2018, 35 (11), pp.1800290. ⟨10.1002/ppsc.201800290⟩. ⟨hal-02114586⟩

• Article dans une revue

Hierarchical collagen-hydroxyapatite nanostructures designed through layer-by-layer assembly of crystal-decorated fibrils

Elodie Colaço, Dalil Brouri, Nesrine Aissaoui, Pauline Cornette, Vincent Dupres, Rute F Domingos, Jean-François Lambert, Emmanuel Maisonhaute, Karim El Kirat, Jessem Landoulsi

A comprehensive understanding of the mechanism by which type I collagen (Col) interacts with hydroxyapatite nanoparticles (Hap NPs) in aqueous solutions is a pivotal step for guiding the design of biologically relevant nanocomposites with controlled hierarchical structure. In this paper we use a…

Biomacromolecules, 2019, 20, pp.4522-4534. ⟨10.1021/acs.biomac.9b01299⟩. ⟨hal-02361539⟩

• Article dans une revue

Operando X‐ray Absorption Study of TiO₂‐supported Au, Cu, and Au–Cu Catalysts for Butadiene Selective Hydrogenation

Abdallah Nassereddine, Laurent Delannoy, Xavier Carrier, Catherine Louis, Camille La Fontaine, Anthony Beauvois, Jaysen Nelayah, Axel Wilson

The selective hydrogenation of unsaturated hydrocarbons is essential for the production of alkenes used in polymerization processes. Au‐based catalysts offer greater selectivity than Pd but are limited by poor hydrogen activation. Alloying Au with Cu offers a promising approach to enhance catalytic…

• Article dans une revue

UV irradiation study of a tripeptide isolated in an argon matrix: A tautomerism process evidenced by infrared and X-ray photoemission spectroscopies.

Eva Mateo-Marti, Claire-Marie Pradier

Matrix isolation is a powerful tool for studying photochemical processes occurring in isolated molecules. In this way, we characterized the chemical modifications occurring within a tri peptide molecule, IGF, when exposed to the influence of Ultraviolet (UV) irradiation. This paper first describes…

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy [1994-..], 2013, 109, pp.247-252. ⟨10.1016/j.saa.2013.02.034⟩. ⟨hal-00915960⟩

• Article dans une revue

Improvements in photostability and sensing properties of EuVO₄ nanoparticles by microwave-assisted sol–gel route for detection of H₂ O₂ vapors

Chrystel Ambard, Natacha Duée, Franck Pereira, David Portehault, Christophe Méthivier, Claire-Marie Pradier, Clément Sanchez

The inorganic thin-film fluorescence probe, with the advantages of long life span and high sensitivity, has attracted much attention in explosive detection. The poor ultraviolet absorption and lack of an aromatic ring make peroxide-based explosives very hard to detect. As the signature compound of…

• Article dans une revue

Mesoporous silica supported amine and amine-copper complex for CO2 adsorption: Detailed reaction mechanism of hydrophilic character and CO2 retention

Bouhadjar Boukoussa, Aboubakr Hakiki, Nabil Bouazizi, Ana-Paola Beltrao-Nunes, Franck Launay, Alain Pailleret, Françoise Pillier, Abdelkader Bengueddach, Rachida Hamacha, Abdelkrim Azzouz

Mesoporous silica SBA-15 was functionalized with various amines and then doped with copper II cation (Cu2+). The modified materials were tested for the retention of CO2 at room temperature using temperature-programmed desorption (CO2-TPD). Several parameters affecting the CO2 retention capacity (…

Journal of Molecular Structure, 2019, 1191, pp.175-182. ⟨10.1016/j.molstruc.2019.04.035⟩. ⟨hal-02164445⟩

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One-Pot Radiolytic Synthesis of Gold Nanorods and Their Optical Properties

Wafa Abidi, P. R. Selvakannan, Yanick Guillet, Isabelle Lampre, Patricia Beaunier, Brigitte Pansu, Bruno Palpant, Hynd Remita

A novel one-pot synthesis method to prepare gold nanorods of different aspect ratios using radiolysis is presented. The gold nanorods are synthesized by radiolytic reduction of Au-III complexes in a micellar solution formed by a mixture of cationic surfactants (cetyltrimethylammonium bromide and…

Journal of Physical Chemistry C, 2010, 114 (35), pp.4794-14803. ⟨10.1021/jp104819c⟩. ⟨hal-00833023⟩

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ZSM-5/SBA-15 microporous/mesoporous composites prepared by a microwave-assisted zeolitisation of Al-SBA-15 mesoporous solids

Sami Habib, Franck Launay, Henri El Zakhem, Matjaž Mazaj, Flavien Guenneau, Patricia Beaunier, Dalil Brouri, Nataša Novak Tušar, Venčeslav Kaučič, Antoine Gedeon

ZSM-5/SBA-15 composites with high textural properties were synthesised by a microwave-assisted zeolitisation of Al-SBA-15 in the presence of tetrapropylammonium bromide. The effect of the hydrothermal treatment temperature and of ammonium fluoride, often used as a catalyst, was studied. Resulting…

Materials Research Bulletin, 2013, 48, pp.1288-1295. ⟨10.1016/j.materresbull.2012.12.030⟩. ⟨hal-00912818⟩