Laboratoire de réactivité de surface

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  • Article dans une revue

Bimetallic Ni-Zn/TiO2 catalysts for selective hydrogenation of alkyne and alkadiene impurities from alkenes stream

Zhao Wang, Guillaume Wang, Catherine Louis, Laurent Delannoy

This study investigates the alternative of replacing noble metals by base metals as catalysts for selective hydrogenation of polyunsaturated hydrocarbons. Nickel catalysts are active for this type of reaction, but poorly selective. However, former calculations anticipated that Ni-Zn alloys could…

Research on Chemical Intermediates, 2021, 47 (1), pp.91-116. ⟨10.1007/s11164-020-04327-0⟩. ⟨hal-03146611⟩

  • Article dans une revue

Design of Effective Catalysts Based on ZnLaZrSi Oxide Systems for Obtaining 1,3-Butadiene from Aqueous Ethanol

Olga V Larina, Nataliya D Shcherban, Pavlo Kyriienko, Ivan M Remezovskyi, Pavlo S Yaremov, Ivan Khalakhan, Gregor Mali, Sergiy Soloviev, Svitlana Orlyk, Stanislaw Dzwigaj

ZnLaZrSi oxide systems prepared with a silica component of the different nature have been studied in 1,3-butadiene production from aqueous ethanol. The following silica materials were used: KSKG, A-175, A-380, SBA-15, MCM-41, MCM-48, MCF, and dealuminated BEA zeolites. The characteristics of the…

ACS Sustainable Chemistry & Engineering, 2020, 8 (44), pp.16600-16611. ⟨10.1021/acssuschemeng.0c05925⟩. ⟨hal-03146639⟩

  • Article dans une revue

Effect of dealumination on the catalytic performance of Cr-containing Beta zeolite in carbon dioxide assisted propane dehydrogenation

Piotr Michorczyk, Kamila Zeńczak-Tomera, Barbara Michorczyk, Adam Węgrzyniak, Marcelina Basta, Yannick Millot, Laetitia Valentin, Stanislaw Dzwigaj

New active and selective catalysts for propane to propene dehydrogenation in assistance of CO 2 (CO 2-PDH) were prepared by chromium incorporation in siliceous SiBeta. The Cr-containing SiBeta zeolite catalysts were obtained by two-step postsynthesis preparation procedure which consist, in the…

Journal of CO2 Utilization, 2020, 36, pp.54-63. ⟨10.1016/j.jcou.2019.09.018⟩. ⟨hal-02473183⟩

  • Article dans une revue

Chemically and Physically Pretreated Straw in Moderate Conditions: Poor Correlation between Biogas Production and Commonly Used Biomass Characterization

Shruthi Meenakshisundaram, Vincenzo Calcagno, Claire Ceballos, Antoine Fayeulle, Estelle Léonard, Virginie Herledan, Jean-Marc Krafft, Yannick Millot, Xiaojun Liu, Claude Jolivalt, André Pauss

Straw is a substantial agricultural by-product for biogas production. Hydrolysis of straw is found to be a rate-limiting step during its anaerobic digestion and could be enhanced by pretreatment. In this paper, the effect of various combinations of particle size reduction, autoclaving, and low-…

Energies, 2023, 16 (3), pp.1146. ⟨10.3390/en16031146⟩. ⟨hal-03952139⟩

  • Article dans une revue

Silk foams with metallic nanoparticles as scaffolds for soft tissue regeneration

Claire de Lartigue, Cristina Belda Marín, Vincent Fitzpatrick, Antonella Esposito, Sandra Casale, Jessem Landoulsi, Erwan Guénin, Christophe Egles

Tissue regeneration can be achieved by providing endogenous cells with a biomaterial scaffold that supports their adhesion and proliferation, as well as the synthesis and deposition of an extracellular matrix (ECM). In this work, silk fibroin protein foams were formed by lyophilization to generate…

International Journal of Molecular Sciences, 2024, 25 (22), pp.12377. ⟨10.3390/ijms252212377⟩. ⟨hal-04798722⟩

  • Article dans une revue

A High-Pressure, High-Temperature Flow Reactor Simulating the Hadean Earth Environment, with Application to the Pressure Dependence of the Cleavage of Avocado Viroid Hammerhead Ribozyme

Kunio Kawamura, Mari Ogawa, Noriko Konagaya, Yoshimi Maruoka, Jean-François Lambert, Louis M. P. Ter-Ovanessian, Jacques Vergne, Guy Hervé, Marie-Christine Maurel

The RNA world hypothesis suggests that chemical networks consisting of functional RNA molecules could have constructed a primitive life-like system leading a first living system. The chemical evolution scenario of RNA molecules should be consistent with the Hadean Earth environment. We have…

Life, 2022, 12 (8), ⟨10.3390/life12081224⟩. ⟨hal-03896279⟩

  • Pré-publication, Document de travail

A common precursor to both prebiotic and biological pathways to RNA nucleotides

Andrea Pérez-Villa, Thomas Georgelin, Jean-François Lambert, Marie-Christine Maurel, François Guyot, A. Marco Saitta, Fabio Pietrucci

Understanding the mechanism of spontaneous formation of ribonucleotides under realistic prebiotic conditions is a key open issue of origins-of-life research. In cells, de novo and salvage nucleotide enzymatic synthesis combines 5-phospho-α-D-ribose-1-diphosphate (α-PRPP) and nucleobases.…

2023. ⟨hal-04015892⟩

  • Article dans une revue

Factors impacting the aggregation/agglomeration and photocatalytic activity of highly crystalline spheroid- and rod-shaped TiO 2 nanoparticles in aqueous solutions

Thomas Degabriel, Elodie Colaço, Rute F Domingos, Karim El Kirat, Dalil Brouri, Sandra Casale, Jessem Landoulsi, Jolanda Spadavecchia

We investigate the characteristics, fate and photocatalytic activity of spheroid- and rod-shaped TiO2 nano-crystals in aqueous solutions to better understand their behaviour in media of biological and environmental interest. For this purpose, the potential of a solvothermal method in synthesizing…

Physical Chemistry Chemical Physics, 2018, 20 (18), pp.12898 - 12907. ⟨10.1039/C7CP08054A⟩. ⟨hal-01803715⟩

  • Article dans une revue

Adsorption of a chiral modifier on an oxide surface: Chemical nature of tartaric acid on rutile TiO2 (110)

E. Meriggio, R. Lazzari, S. Chenot, P. David, C. Methivier, X. Carrier, G. Cabailh, V. Humblot

Tartaric acid (TA) is one of the most known chiral modifier used in heterogeneous enantioselective catalysis and understanding how it interacts with oxide supports is of significant importance for the design of efficient supported metal catalysts. This work presents a detailed surface science…

Applied Surface Science, 2019, 493, pp.1134-1141. ⟨10.1016/j.apsusc.2019.07.143⟩. ⟨hal-02340234⟩

  • Article dans une revue

Influence of Cu on the catalytic activity of FeBEA zeolites in SCR of NO with NH 3

Paweł Boroń, Lucjan Chmielarz, Stanislaw Dzwigaj

Two series of Fe and/or Cu containing BEA zeolites were prepared by different procedures: two-step postsynthesis method (FexSiBEA, CuxSiBEA and FexCuxSiBEA) and conventional wet impregnation (FexHAlBEA, CuxHAlBEA and FexCuxHAlBEA) (x = 1.0 Fe or Cu wt%). Modification of BEA zeolite resulted in the…

Applied Catalysis B: Environmental, 2015, 168-169, pp.377-384. ⟨10.1016/j.apcatb.2014.12.052⟩. ⟨hal-01110190⟩